US4066611A
Expired / Lapsed
US
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Stabilized polycarbonate composition
Assignee: General Electric Co
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Filing: 1976-06-23
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Granted: 1978-01-03
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Expires: 1996-06-23
Abstract
Abstract A stabilized polycarbonate composition comprising in admixture an aromatic carbonate polymer and a stabilizing amount of a cyclic diphosphite. The composition may additionally contain co-stabilizers such as epoxides or silanes.
Inventors
- 👤 Robert Jay Axelrod
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 01:43
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/15; C08K5/151; C08K5/1515; C08K5/49; C08K5/51; C08K5/52; C08K5/527; C08K5/54; C08L; C08L63/00; C08L69/00
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
55 words
A stabilized polycarbonate composition comprising in admixture, an aromatic carbonate polymer and a stabilizing amount of a cyclic diphosphite characterized by the following general formula: ##STR6## wherein X is selected from the group consisting of lower alkyl of 1 to 6 carbon atoms; aryl, alkaryl and aralkyl of 6 to 20 carbon atoms and halogen.
Claim 2
Dependent Claim
55 words
A stabilized polycarbonate composition comprising in admixture, an aromatic carbonate polymer and a stabilizing amount of a cyclic diphosphite characterized by the following general formula: ##STR6## wherein X is selected from the group consisting of lower alkyl of 1 to 6 carbon atoms; aryl, alkaryl and aralkyl of 6 to 20 carbon atoms and halogen.
Claim 3
Dependent Claim
23 words
The composition as defined in claim 1 wherein the cyclic diphosphite is used in amounts of from 0.01 to about 0.10 weight percent.
Claim 4
Dependent Claim
15 words
The composition as defined in claim 1 wherein the cyclic diphosphite is di-(2,4-di-t-butylphenyl) pentaerythrityl diphosphite.
Claim 5
Dependent Claim
62 words
The composition as defined in claim 1 which contains a stabilizing amount of a silane compound of the general formula: R.sub.a Si(OR).sub.b wherein R is independently selected from the group consisting of alkyl, alkoxy, aryl, aralkyl and alkaryl of 1 to 20 carbon atoms and wherein a + b = 4 and b is an integer equal to or less than 3.
Claim 6
Dependent Claim
30 words
The composition as defined in claim 4 wherein the silane is used in amounts of from 0.01 to about 0.10 weight percent based on the weight of the polycarbonate composition.
Claim 7
Dependent Claim
13 words
The composition as defined in claim 4 wherein the silane is triethoxy silane.
Claim 8
Dependent Claim
14 words
The composition as defined in claim 4 wherein the silane is diphenyl diethoxy silane.
Claim 9
Dependent Claim
208 words
The composition as defined in claim 1 which contains 0.01 to 0.5 weight percent based on the weight of the polymer composition of epoxy compounds selected from the following: I. derivatives of epoxy ethane represented by the following formula: ##STR7## wherein R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of hydrogen, an alkyl radical of 1-24 carbon atoms, an aryl radical of 6-24 carbon atoms, --CH 2 OR', --CH 2 OCOR', --CH 2 OCOR'X, 'COOCH 2 X, CH 2 OR"OCH 2 X wherein R' is selected from the group consisting of an alkyl radical of 1-24 carbon atoms or an aryl radical of 6 to 24 carbon atoms and wherein R" is an alkylene radical of 1-24 carbon atoms and X is an oxirane ring. Ii. derivatives of epoxy cyclohexane represented by the following formula: ##STR8## wherein R 5 through R 12 are independently selected from the group consisting of hydrogen, alkyl radicals of 1-24 carbon atoms, --COOR 13 , --OCOR 13 , --COOR 14 X, --OCOR 14 --COOX wherein R 13 is an alkyl radical of 1-24 carbon atoms and R 14 therein is an alkylene radical of 1-24 carbon atoms and X is an oxirane ring.
Claim 10
Dependent Claim
15 words
The composition as defined in claim 8 wherein the epoxy compound is 2,3-epoxycyclohexylmethyl 3,4-epoxycyclohexane carboxylate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-02 | 1981-07-04 | 1982-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-02 | 1985-07-04 | 1986-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-02 | 1989-07-04 | 1990-01-03 | $7700.00 | Window Closed / Lapsed |