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US4066608A Expired / Lapsed US ⏱️ 0.0 years remaining

Three component stabilizer system for propylene polymers containing grafted acrylic acid with or without glass fiber reinforcement

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-09-25
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Granted: 1978-01-03
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Expires: 1995-09-25
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Abstract

Abstract A three component LTHA stabilizer system of distearyl thiodipropionate, tris(3,5-di-t-butyl-4-hydroxybenzyl isocyanurate, sold under the trademark Goodrite 3114 and cyclic neopentanetetrayl bis(octadecylphosphite), sold under the trademark Weston 618 particularly suitable for glass fiber reinforced homopolypropylene or acrylic acid grafted propylene polymers. Key parts of the invention include well defined ratios of the thioester and phenolic components and good dispersion of the glass fiber to achieve the desired stability. The stabilizer system is good for other acrylic acid grafted polypropylene polymers which include impact modifiers. Other grafting monomers can be substituted for the acrylic acid.

Inventors

  • 👤 Robert A. Van Brederode

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 03:39
CPC Classifications
C; C08; C08K; C08K7/00; C08K7/02; C08K7/04; C08K7/14; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34924; C08K5/36; C08K5/38; C08K5/49; C08K5/51; C08K5/52; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08L51/00; C08L51/06

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 59 words
A glass reinforced polyolefin composition comprising a major proportion of polyolefin and having outstanding resistance to oxidative degradation containing a synergistic stabilizer combination of a. 0.15 to 0.25 wt. % of cyclic neopentanetetrayl bis(octadecylphosphite) and b. 0.5 to 1.3 wt. % of a combination of distearyl thiodipropionate and c. tris(3,5-di-t-butyl-4-hydroxybenzyl isocyanurate in a ratio of 3 or 4 :1.
Claim 2
Dependent Claim 59 words
A glass reinforced polyolefin composition comprising a major proportion of polyolefin and having outstanding resistance to oxidative degradation containing a synergistic stabilizer combination of a. 0.15 to 0.25 wt. % of cyclic neopentanetetrayl bis(octadecylphosphite) and b. 0.5 to 1.3 wt. % of a combination of distearyl thiodipropionate and c. tris(3,5-di-t-butyl-4-hydroxybenzyl isocyanurate in a ratio of 3 or 4 :1.

References Cited (Backward Citations)

US3437550A Cited
US3849516A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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