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US4066569A Expired / Lapsed US ⏱️ 0.0 years remaining

Dopants for dynamic scattering liquid crystals

Assignee: Raytheon Co
•
Filing: 1975-12-30
•
Granted: 1978-01-03
•
Expires: 1995-12-30
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Abstract

Abstract Metallocenes when mixed with conjugated cyano-organic compounds such as 7,7'8,8'-tetracyanoquinodimethane (TCNQ) and (2,4,7,-trinitro-9-fluorenylidene)-malononitrile (TFM) function as excellent dopants for liquid crystals.

Inventors

  • 👤 Hong Sup Lim

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 08:31
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/58; C09K19/582

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 48 words
A doped liquid crystal combination suitable for dc DSM and storage scattering applications comprised of a metallocene formed from a metal selected from the group consisting of Fe, Ru, and Os and (2,4,7-trinitro-9-fluorenylidene)-malononitrile dissolved in a nematic liquid crystal, nematic liquid crystal mixture, or cholesteric-nematic liquid crystal mixture.
Claim 2
Dependent Claim 48 words
A doped liquid crystal combination suitable for dc DSM and storage scattering applications comprised of a metallocene formed from a metal selected from the group consisting of Fe, Ru, and Os and (2,4,7-trinitro-9-fluorenylidene)-malononitrile dissolved in a nematic liquid crystal, nematic liquid crystal mixture, or cholesteric-nematic liquid crystal mixture.
Claim 3
Dependent Claim 21 words
The combination of claim 1 wherein said metallocene is taken from the group of compounds consisting of ferrocene and substituted ferrocenes.
Claim 4
Dependent Claim 10 words
The combination of claim 1 wherein said metallocene is ferrocene.
Claim 5
Dependent Claim 48 words
The combination of claim 1 wherein said metallocene is a mono-substituted ferrocene whose general structural formula is ##STR1## and R is an organic group of the formula C n H 2n+1 X where n ranges from 1 to 20 and X may be CH 2 , O, ##STR2##
Claim 6
Dependent Claim 50 words
The combination of claim 1 wherein said metallocene is a di-substituted ferrocene whose general structural formula is ##STR3## and both R' and R are organic groups of the formula C n H 2n+1 X where n ranges from 1 to 20 and X may be CH 2 , O, ##STR4##
Claim 7
Dependent Claim 10 words
The combination of claim 4 wherein said ferrocene is n-butyl-ferrocene.
Claim 8
Dependent Claim 10 words
The combination of claim 5 wherein said ferrocene is di-n-butyl-ferrocene.
Claim 9
Dependent Claim 32 words
The combination of claim 1 wherein said dopant is dissolved in a nematic liquid crystal or a mixture of liquid crystals taken from the group of compounds consisting of phenyl benzoate esters.
Claim 10
Dependent Claim 31 words
The combination of claim 1 wherein the concentration of said dopant is less than 1% of the weight of said nematic liquid crystal, nematic crystal mixture, or cholesteric-nematic liquid crystal mixture.

References Cited (Backward Citations)

US3162641A Cited
US3838059A Cited
US3923857A Cited
US3876286A Cited
US3814700A Cited
US3975285A Cited
JPS4995881A Cited
US3932298A Cited
US3990984A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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