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US4066453A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the preparation of printing forms

Assignee: Hoechst AG
•
Filing: 1976-06-02
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Granted: 1978-01-03
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Expires: 1996-06-02
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Abstract

Abstract This invention relates to an improvement in the process for the preparation of printing forms or metallic etchings from electrophotographic or electrographic reproduction materials composed of a support with a photoconductive or high-ohmic layer thereon, by charging and image-wise exposure, or by image-wise charging, development of the electrostatic image with a finely-divided toner, fixing, and removal of the layer in the image-free areas by means of a decoating solution, the improvement comprising developing the electrostatic image with a developer which reacts at least superficially with the image areas at room temperature, thereby simultaneously effecting development and resistance to the decoating solution, or developing the electrostatic image with a developer which reacts with the decoating solution and thereby deactivates it in the image areas.

Inventors

  • 👤 Erwin Lind
  • 👤 Franz Freimuth

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:10
CPC Classifications
G; G03; G03G; G03G13/00; G03G13/26; G03G13/28; G03G13/32; G03G9/00; G03G9/08; G03G9/09; G03G9/0926; G03G9/097; G03G9/09708; G03G9/09733; G03G9/09758; G03G9/09775; G03G9/09783; G03G9/09791

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 131 words
In the process for the preparation of printing forms or metallic etchings from electrophotographic or electrographic reproduction materials composed of a support with a photoconductive organic or high-ohmic organic layer thereon, by charging and imagewise exposure, or by imagewise charging, development of the electrostatic image with a finely divided toner, fixing, and removal of the layer in the image-free areas by means of a decoating solution, the improvement which ccomprises developing the electrostatic image with a developer which chemically reacts at least superfically with the image areas of the photoconductive organic or high-ohmic organic layer at room temperature, thereby simultaneously effecting development and resistance to the decoating solution, or developing the electrostatic image with a developer which chemically reacts with the decoating solution and thereby deactivates it in the image areas.
Claim 2
Dependent Claim 131 words
In the process for the preparation of printing forms or metallic etchings from electrophotographic or electrographic reproduction materials composed of a support with a photoconductive organic or high-ohmic organic layer thereon, by charging and imagewise exposure, or by imagewise charging, development of the electrostatic image with a finely divided toner, fixing, and removal of the layer in the image-free areas by means of a decoating solution, the improvement which ccomprises developing the electrostatic image with a developer which chemically reacts at least superfically with the image areas of the photoconductive organic or high-ohmic organic layer at room temperature, thereby simultaneously effecting development and resistance to the decoating solution, or developing the electrostatic image with a developer which chemically reacts with the decoating solution and thereby deactivates it in the image areas.
Claim 3
Dependent Claim 35 words
A process according to claim 1 in which the developer reacts at least partially with a resin binder of the photoconductive or highohmic layer to form a complex compound, a chelate compound, or a salt.
Claim 4
Dependent Claim 28 words
A process according to claim 1 in which the developer reacts at least partially with the photoconductor component of the layer to form a sparingly soluble donor-acceptor complex.
Claim 5
Dependent Claim 46 words
A process according to claim 1 in which the developer reacts at least partially with a component of the decoating solution to form a salt and thereby prevents the decoating solution from acting upon the areas of the copying layer which are covered by the developer.
Claim 6
Dependent Claim 24 words
A process according to claim 1 in which the developer is composed of a high-ohmic liquid phase with a finely-divided solid phase dispersed therein.
Claim 7
Dependent Claim 44 words
A process according to claim 1 in which the developer contains at least one salt of a multi-valent metal, said salt reacting with a polymer or a copolymer containing acid groups or anhydride groups which is present in the layer as a resin binder.
Claim 8
Dependent Claim 13 words
A process according to claim 1 in which the developer comprises magnesium sulfate.
Claim 9
Dependent Claim 14 words
A process according to claim 1 in which the developer comprises potassium aluminum sulfate.
Claim 10
Dependent Claim 13 words
A process according to claim 1 in which the developer conprises copper chloride.
Claim 11
Dependent Claim 21 words
A process according to claim 1 in which the developer comprises at least one compound of the triphenyl methane dyestuff type.
Claim 12
Dependent Claim 17 words
A process according to claim 1 in which the developer comprises at least one aromatic diazonium salt.
Claim 13
Dependent Claim 35 words
A process according to claim 1 in which the developer comprises at least one substance which serves as an electron acceptor or electron donor in molecular complexes formed with the photoconductor present in the layer.
Claim 14
Dependent Claim 40 words
A process according to claim 12 in which the developer, being an electron acceptor, comprises at least one compound selected from the group consisting of tetraphenyl cyclopentadienone, benzoquinone, dicyanochloro benzoquinone, benzoanthraquinone, tetrachloroquinone, dibromosuccinic acid, tetrachlorophthalic anhydride, dinitronaphthalic anhydride and tetranitronaphthalene.
Claim 15
Dependent Claim 13 words
A process according to claim 13 in which the developer comprises tetraphenyl cyclopentadienone.
Claim 16
Dependent Claim 13 words
A process according to claim 1 in which the developer comprises calcium oxide.
Claim 17
Dependent Claim 17 words
A process according to claim 1 in which the developer comprises boric acid or toluene sulfonic acid.
Claim 18
Dependent Claim 22 words
A process according to claim 1 in which the developer additionally contains a finely-divided solid substance which renders the image areas hydrophobic.
Claim 19
Dependent Claim 24 words
A process according to claim 17 in which the substance imparting hydrophobic properties is selected from the group consisting of bitumen, waxes, and resins.
Claim 20
Dependent Claim 26 words
A process according to claim 1 in which the photoconductive or high-ohmic layer contains a resin binder which is soluble in aqueous or alcoholic solvent systems.
Claim 21
Dependent Claim 25 words
A process according to claim 19 in which the resin binders used are composed of high molecular weight substances containing groups which render them alkali-soluble.
Claim 22
Dependent Claim 17 words
A process according to claim 19 in which the resin binder is a copolymer containing anhydride groups.
Claim 23
Dependent Claim 16 words
A process according to claim 19 in which the resin binder is a styrene/maleic anhydride copolymer.
Claim 24
Dependent Claim 16 words
A process according to claim 1 including etching of the bared image-free areas of the support.
Claim 25
Dependent Claim 69 words
A process according to claim 1 in which the developer contains at least one salt of a multi-valent metal selected from the group consisting of chromium, manganese, iron, copper, and the metals of the IInd, IIIrd, and IVth main groups of the Periodic System, said salt reacting with a polymer or a copolymer containing acid groups or anhydride groups which is present in the layer as a resin binder.

References Cited (Backward Citations)

US3287114A Cited
US3305359A Cited
US3406061A Cited
GB1182174A Cited
US3615385A Cited
US3745002A Cited
US3954467A Cited
US3839028A Cited
US3748127A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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