US4065630A
Expired / Lapsed
US
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Polyoxyalkylene fluoroalkyltrimellitates
Assignee: Arkema Inc
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Filing: 1976-09-10
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Granted: 1977-12-27
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Expires: 1996-09-10
Abstract
Abstract Novel polyoxyalkylene fluoroalkyltrimellitate compounds are disclosed that are useful for improving the soil release properties of textiles. These compounds may be conveniently prepared by reacting a fluorinated alkyl thiol or amine with trimellitic anhydride monoacid chloride to form a fluorinated trimellitic anhydride intermediate product which is then reacted with a polyoxyalkylene derivative.
Inventors
- 👤 Stanley Robert Sandler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 13:07
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/322; D06M13/402; D06M13/408; C; C07; C07C; C07C327/00; C07D; C07D307/00; C07D307/77; C07D307/87; C07D307/89; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; D06M13/10; D06M13/184; D06M13/188; D06M13/192
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
259 words
A compound of the formula ##STR35## wherein: a. the ring is 1, 3, 4 tri-substituted b. Z is NR, Z 1 is O and Z 2 is selected from O, S, or NR where R is H or an alkyl of 1 to 4 carbon atoms, c. Q is selected from -- CH 2 -) 1--10 , d. R 1 and R 2 are moieties independently selected from hydrogen or an alkyl having 1 to 4 carbon atoms, e. m and p are independent integers from 0 to 30 describing repeating units of polyoxyalkylene groups that form a chain with at least one polyoxyalkylene chain of at least three repeating units being present, f. R 1 and R 2 are one or more of said moieties within the repeating units m and p, g. R f is selected from the group consisting of a linear or branched perfluoroalkyl a linear or branched monochloroperfluoroalkyl, ora linear or branched perfluoroisoalkoxyalkyl wherein each member of the group has 3 to 20 carbon atoms, h. r is an integer from 1 to 10, i. A is a linking group selected from the group consisting of the acyl segment of alkanoic or mono or dicyclic aromatic polycarboxylic acids, alkanoic or mono or dicyclic aromatic anhydrides or alkanoic or mono or dicyclic aromatic polycarbamates, linear alkylene of 2 to 12 carbon atoms or a cyclic alkylene of 5-8 carbon atoms or a branched alkylene of 3-12 carbon atoms, and j. R 3 is selected from H or an alkyl of 1 to 20 carbon atoms.
Claim 2
Dependent Claim
259 words
A compound of the formula ##STR35## wherein: a. the ring is 1, 3, 4 tri-substituted b. Z is NR, Z 1 is O and Z 2 is selected from O, S, or NR where R is H or an alkyl of 1 to 4 carbon atoms, c. Q is selected from -- CH 2 -) 1--10 , d. R 1 and R 2 are moieties independently selected from hydrogen or an alkyl having 1 to 4 carbon atoms, e. m and p are independent integers from 0 to 30 describing repeating units of polyoxyalkylene groups that form a chain with at least one polyoxyalkylene chain of at least three repeating units being present, f. R 1 and R 2 are one or more of said moieties within the repeating units m and p, g. R f is selected from the group consisting of a linear or branched perfluoroalkyl a linear or branched monochloroperfluoroalkyl, ora linear or branched perfluoroisoalkoxyalkyl wherein each member of the group has 3 to 20 carbon atoms, h. r is an integer from 1 to 10, i. A is a linking group selected from the group consisting of the acyl segment of alkanoic or mono or dicyclic aromatic polycarboxylic acids, alkanoic or mono or dicyclic aromatic anhydrides or alkanoic or mono or dicyclic aromatic polycarbamates, linear alkylene of 2 to 12 carbon atoms or a cyclic alkylene of 5-8 carbon atoms or a branched alkylene of 3-12 carbon atoms, and j. R 3 is selected from H or an alkyl of 1 to 20 carbon atoms.
Claim 3
Dependent Claim
16 words
The compound of claim 1 wherein R f is (CF 3 )CF(CF 2 ) 4-8 --.
Claim 4
Dependent Claim
16 words
The compound of claim 1 wherein R f is CF 3 (CF 2 ) 2-9 --.
Claim 5
Dependent Claim
24 words
The compound of claim 1 where R f is CF 3 CF 2 (OCF 2 CF 2 ) 1-3 OCF 2 CF 2 --.
Claim 6
Dependent Claim
18 words
The compound of claim 1 where R f is (CF 3 ) 2 CFO(CF 2 ) 4-8 --.
Claim 7
Dependent Claim
12 words
The compound of claim 1 where the polyoxyalkylene chains are polyethylene oxides.
Claim 8
Dependent Claim
17 words
The compound of claim 1 where the polyoxyalkylene chains are copolymers of ethylene oxide and propylene oxide.
Claim 9
Dependent Claim
14 words
The compound of claim 1 where the linking group A is a trimellitate derivative.
Claim 10
Dependent Claim
14 words
The compound of claim 1 wherein the linking group A is a polyoxyethylene trimellitate.
Claim 11
Dependent Claim
14 words
The compound of claim 1 where the linking group A is a polyoxyalkylene pyromellitate.
Claim 12
Dependent Claim
14 words
The compound of claim 1 wherein the linking group is a polyoxyalkylene tolaene dicarbamate.
Claim 13
Dependent Claim
11 words
The compound of the claim 1 where R 3 is H.
References Cited (Backward Citations)
US3336363A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-12-26 | 1981-06-27 | 1981-12-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-12-26 | 1985-06-27 | 1985-12-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-12-26 | 1989-06-27 | 1989-12-27 | $7700.00 | Window Closed / Lapsed |