US4064322A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrolyte reservoir for a fuel cell
Assignee: RTX Corp
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Filing: 1976-09-01
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Granted: 1977-12-20
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Expires: 1996-09-01
Abstract
Abstract An electrolyte reservoir layer disposed behind and adjacent one of the catalyst layers of a fuel cell is porous and hydrophilic to the electrolyte. In one embodiment the reservoir layer includes impregnations of hydrophobic material on the catalyst facing surface thereof and holes leading from the other surface to the impregnations for providing reactant gas passages through the reservoir layer to the catalyst layer. The impregnations of hydrophobic material are designed to provide good distribution of the reactant gas into the catalyst layer without consuming a large volume of the reservoir. In a preferred embodiment the reservoir is also the electrode substrate whereby the catalyst layer is bonded to the surface thereof.
Inventors
- 👤 Calvin L. Bushnell
- 👤 Harold Russell Kunz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 09:01
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/02; H01M8/0289; H01M4/00; H01M4/86; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
126 words
An electrolyte reservoir layer for use adjacent the catalyst layer of a fuel cell, said reservoir layer being porous throughout and including a catalyst facing surface and a non-catalyst facing surface, said catalyst facing surface including first impregnations of hydrophobic material to a shallow depth over a major portion of its area, said catalyst facing surface also including uniformly distributed areas not impregnated with hydrophobic material, said reservoir layer also including uniformly distributed non-electrolyte retaining portions leading from said non-catalyst facing surface to said impregnations of hydrophobic material at said other surface, said non-electrolyte retaining portions comprising only a small portion of the volume of said reservoir layer, said reservoir layer being hydrophilic in all portions other than said non-electrolyte retaining portions and said first impregnations.
Claim 2
Dependent Claim
126 words
An electrolyte reservoir layer for use adjacent the catalyst layer of a fuel cell, said reservoir layer being porous throughout and including a catalyst facing surface and a non-catalyst facing surface, said catalyst facing surface including first impregnations of hydrophobic material to a shallow depth over a major portion of its area, said catalyst facing surface also including uniformly distributed areas not impregnated with hydrophobic material, said reservoir layer also including uniformly distributed non-electrolyte retaining portions leading from said non-catalyst facing surface to said impregnations of hydrophobic material at said other surface, said non-electrolyte retaining portions comprising only a small portion of the volume of said reservoir layer, said reservoir layer being hydrophilic in all portions other than said non-electrolyte retaining portions and said first impregnations.
Claim 3
Dependent Claim
24 words
The reservoir layer according to claim 1 wherein said non-electrolyte retaining portions are holes extending from the non-catalyst facing surface into said first impregnations.
Claim 4
Dependent Claim
31 words
The reservoir layer according to claim 1 wherein said non-electrolyte retaining portions are second impregnations of hydrophobic material extending from said non-catalyst facing surface to said first impregnations of hydrophobic material.
Claim 5
Dependent Claim
81 words
The reservoir layer according to claim 1 wherein the area of said catalyst facing surface not impregnated with hydrophobic material is at least 2% of the total area of said catalyst facing surface, said depth of said first impregnations is no more than 50% of the thickness of said reservoir layer and no less than 3 mils, and the minimum total cross-sectional area of said non-electrolyte retaining portions is 2% of the total cross sectional area of said non-catalyst facing surface.
Claim 6
Dependent Claim
212 words
In a fuel cell comprising an electrolyte retaining matrix, an anode catalyst layer disposed on one side of said matrix and a cathode catalyst layer disposed on the other side of said matrix, each layer including hydrophobic material substantially uniformly distributed throughout, each catalyst layer also including an active area in contact with said matrix, the improvement comprising: an electrolyte reservoir layer including an active portion in intimate contact with the non-matrix facing side of said active area of at least one of said catalyst layers, said reservoir layer being porous throughout and including a catalyst facing surface and a non-catalyst facing surface, said catalyst facing surface including first impregnations of hydrophobic material to a shallow depth over a major portion of its area, said catalyst facing surface including uniformly distributed areas not impregnated with hydrophobic material, said reservoir layer also including uniformly distributed non-electrolyte retaining portions leading from said non-catalyst facing surface to said impregnations of hydrophobic material at said other surface, said non-electrolyte retaining portions comprising only a small portion of the volume of said reservoir layer, said reservoir layer being hydrophilic in all portions other than said non-electrolyte retaining portions and said first impregnations, said hydrophilic portions having substantially no pores smaller than the largest pores of said matrix.
Claim 7
Dependent Claim
212 words
In a fuel cell comprising an electrolyte retaining matrix, an anode catalyst layer disposed on one side of said matrix and a cathode catalyst layer disposed on the other side of said matrix, each layer including hydrophobic material substantially uniformly distributed throughout, each catalyst layer also including an active area in contact with said matrix, the improvement comprising: an electrolyte reservoir layer including an active portion in intimate contact with the non-matrix facing side of said active area of at least one of said catalyst layers, said reservoir layer being porous throughout and including a catalyst facing surface and a non-catalyst facing surface, said catalyst facing surface including first impregnations of hydrophobic material to a shallow depth over a major portion of its area, said catalyst facing surface including uniformly distributed areas not impregnated with hydrophobic material, said reservoir layer also including uniformly distributed non-electrolyte retaining portions leading from said non-catalyst facing surface to said impregnations of hydrophobic material at said other surface, said non-electrolyte retaining portions comprising only a small portion of the volume of said reservoir layer, said reservoir layer being hydrophilic in all portions other than said non-electrolyte retaining portions and said first impregnations, said hydrophilic portions having substantially no pores smaller than the largest pores of said matrix.
Claim 8
Dependent Claim
16 words
The improvement according to claim 5 wherein said one catalyst layer is said anode catalyst layer.
Claim 9
Dependent Claim
23 words
The improvement according to claim 6 wherein said non-electrolyte retaining portions are holes extending from said non-catalyst facing surface into said first impregnations.
Claim 10
Dependent Claim
17 words
The improvement according to claim 6 wherein said anode catalyst layer is bonded to said reservoir layer.
Claim 11
Dependent Claim
13 words
The improvement according to claim 5 wherein said reservoir layer comprises carbon paper.
Claim 12
Dependent Claim
115 words
The improvement according to claim 6 wherein said non-electrolyte retaining portions are second impregnations of hydrophobic material extending from said non-catalyst facing surface to said first impregnations of hydrophobic material, said areas of said catalyst facing surface not impregnated with hydrophobic material being at least 2% of the total area of said catalyst facing surface, said depth of said first impregnations being no more than 50% of the thickness of said reservoir layer and no less than 3 mils, the minimum total cross sectional area of said non-electrolyte retaining portions being 2% of the total cross sectional area of said non-catalyst facing surface, and said depth of said first impregnations being at least 3 mils.
References Cited (Backward Citations)
US3905832A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-12-19 | 1981-06-20 | 1981-12-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-12-19 | 1985-06-20 | 1985-12-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-12-19 | 1989-06-20 | 1989-12-20 | $7700.00 | Window Closed / Lapsed |