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US4064304A Expired / Lapsed US ⏱️ 0.0 years remaining

Coated synthetic paper adapted for offset printing and method for production thereof

Assignee: Kanzaki Paper Manufacturing Co Ltd
•
Filing: 1976-07-14
•
Granted: 1977-12-20
•
Expires: 1996-07-14
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Abstract

Abstract A coated synthetic paper adapted for offset printing is produced from a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 square meter/g. A microporous and discontinuous coating layer is formed on at least one of the surfaces of the base paper sheet using a coating composition having an adhesive component and a pigment component, at least 5% by weight of said pigment component being an organic polymer pigment in the form of finely divided particles.

Inventors

  • 👤 Seigoro Fujita
  • 👤 Tojiro Kitahori

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 07:09
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/50; B41M5/502; B41M5/508; B41M5/52; D; D21; D21H; D21H19/00; D21H19/36; D21H19/38; D21H19/42; B41M5/5218; B41M5/5236; B41M5/5254; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24893; Y10T428/24901; Y10T428/249921; Y10T428/249953; Y10T428/249978; Y10T428/249986; Y10T428/27; Y10T428/273; Y10T428/277; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31909; Y10T428/31913; Y10T428/3192

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 151 words
A coated synthetic paper adapted for offset printing comprising a base paper sheet comprising fibrous material at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 m 2 /g., and a microporous and discontinuous coating layer formed on at least one of the surfaces of said base paper sheet, said coating layer being substantially formed of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof.
Claim 2
Dependent Claim 151 words
A coated synthetic paper adapted for offset printing comprising a base paper sheet comprising fibrous material at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 m 2 /g., and a microporous and discontinuous coating layer formed on at least one of the surfaces of said base paper sheet, said coating layer being substantially formed of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof.
Claim 3
Dependent Claim 30 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which 5 to 95% by weight of said fibrous material is formed of polyolefinic pulp fibrils.
Claim 4
Dependent Claim 44 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which said fibrous material is formed of a mixture of 5 to 95% by weight of polyolefinic pulp fibrils and 95 to 5% by weight of a natural cellulose pulp.
Claim 5
Dependent Claim 39 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which at least 10% by weight on dry basis of said pigment component is an organic polymer pigment in the form of finely divided particles.
Claim 6
Dependent Claim 38 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which said pigment component consists of a mixture of an organic polymer pigment in the form of finely divided particles and an inorganic pigment.
Claim 7
Dependent Claim 42 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which the amount of said adhesive component is 8 to 35 parts by weight with respect to 100 parts by weight on dry basis of said pigment component.
Claim 8
Dependent Claim 41 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which said organic polymer pigment comprises finely divided particles of an organic polymer having a deflection temperature higher than 30° C according to the ASTM Standard D-648.
Claim 9
Dependent Claim 41 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which said organic polymer pigment comprises finely divided particles of an organic polymer having a deflection temperature higher than 50° C according to the ASTM Standard D-648.
Claim 10
Dependent Claim 33 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which said organic polymer pigment consists of finely divided particles having an average size of 0.1 to 1.0 micron.
Claim 11
Dependent Claim 30 words
A coated synthetic paper adapted for offset printing as defined in claim 1 in which the weight of said coating layer is at least 0.5 g/square meter on dry basis.
Claim 12
Dependent Claim 30 words
A coated synthetic paper adapted for offset printing as defined in claim 1, in which the weigth of said coating layer is 3.0 to 30 g/square meter on dry basis.
Claim 13
Independent Claim 157 words
A method for the production of a coated synthetic paper adapted for offset printing, comprising: preparing a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 square meter/g., and forming a microporous and discontinuous coating layer on at least one of the surfaces of said base paper sheet with a coating composition consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof.
Claim 14
Independent Claim 157 words
A method for the production of a coated synthetic paper adapted for offset printing, comprising: preparing a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 square meter/g., and forming a microporous and discontinuous coating layer on at least one of the surfaces of said base paper sheet with a coating composition consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof.
Claim 15
Dependent Claim 184 words
A coated synthetic paper adapted for offset printing, comprising: a base paper sheet comprising fibrous material, at least 5% up to 95% by weight of which is formed of polymeric pulp fibrils and 95% to 5% by weight of cellulose pulp, said polymeric pulp fibrils being formed of a hydrophilic component and a polyolefinic polymer in a weight ratio range of 1:99 to 30:70, said polymeric pulp fibrils having a specific surface area of at least 0.7 square meter/g. and a microporous and discontinuous coating layer formed on at least one of the surfaces of the base paper sheet, the coating layer consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, from 5 to 100% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles and selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof and from 0 to 95% by weight inorganic pigment.
Claim 16
Dependent Claim 184 words
A coated synthetic paper adapted for offset printing, comprising: a base paper sheet comprising fibrous material, at least 5% up to 95% by weight of which is formed of polymeric pulp fibrils and 95% to 5% by weight of cellulose pulp, said polymeric pulp fibrils being formed of a hydrophilic component and a polyolefinic polymer in a weight ratio range of 1:99 to 30:70, said polymeric pulp fibrils having a specific surface area of at least 0.7 square meter/g. and a microporous and discontinuous coating layer formed on at least one of the surfaces of the base paper sheet, the coating layer consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, from 5 to 100% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles and selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof and from 0 to 95% by weight inorganic pigment.
Claim 17
Independent Claim 192 words
A method for preparing a coated synthetic paper adapted for offset printing comprising preparing a base paper sheet comprising fibrous material, at least 5% up to 95% by weight of which is formed of polymeric pulp fibrils, the balance being cellulose pulp, said polymeric pulp fibrils being formed of a hydrophilic component and a polyolefinic polymer in a weight ratio range of 1:99 to 30:70, said polymeric pulp fibrils having a specific surface area of at least 0.7 square meter/g., and applying to at least one surface of said base paper sheet from 015 to 30 grams per square meter of a microporous and discontinuous coating layer, the coating layer consisting essentially of: 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, from 5 to 100% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles and selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof and from 0 to 95% by weight inorganic pigment.
Claim 18
Independent Claim 192 words
A method for preparing a coated synthetic paper adapted for offset printing comprising preparing a base paper sheet comprising fibrous material, at least 5% up to 95% by weight of which is formed of polymeric pulp fibrils, the balance being cellulose pulp, said polymeric pulp fibrils being formed of a hydrophilic component and a polyolefinic polymer in a weight ratio range of 1:99 to 30:70, said polymeric pulp fibrils having a specific surface area of at least 0.7 square meter/g., and applying to at least one surface of said base paper sheet from 015 to 30 grams per square meter of a microporous and discontinuous coating layer, the coating layer consisting essentially of: 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, from 5 to 100% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles and selected from the group consisting of polystyrene, polymethyl methacrylate and vinyl copolymers thereof and from 0 to 95% by weight inorganic pigment.
Claim 19
Dependent Claim 201 words
A coated synthetic paper adapted for offset printing comprising a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 m 2 /g., and a microporous and discontinuous coating layer formed on at least one of the surfaces of said base paper sheet, said coating layer being substantially formed of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, poly(α-methylstyrene), poly(4-ethylstyrene), poly (1-vinylnaphthalene), polyvinyl chloride, poly(hexafluoropropylene), polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), polyvinylidene chloride, poly(1,2-difluoroethylene), poly (methylmethacrylate), poly(isopropyl chloroacrylate), poly (2-chloroethyl methacrylate), poly(cyclohexyl chloroacrylate), poly(methyl chloroacrylate), polyvinyl acetate, polyallyl acetate, polyvinyl propionate, poly(ethylene 1,5-naphthalate), polyethylene terephthalate, poly(hexamethylene adipamide), poly(ε-capramide), poly(decamethylene adipamide), polycarbonates, polyacetals, polyvinyl formal, polyvinyl butyral, and copolymers of the constituent monomers of the above-named polymers.
Claim 20
Dependent Claim 201 words
A coated synthetic paper adapted for offset printing comprising a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 m 2 /g., and a microporous and discontinuous coating layer formed on at least one of the surfaces of said base paper sheet, said coating layer being substantially formed of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of a pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, poly(α-methylstyrene), poly(4-ethylstyrene), poly (1-vinylnaphthalene), polyvinyl chloride, poly(hexafluoropropylene), polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), polyvinylidene chloride, poly(1,2-difluoroethylene), poly (methylmethacrylate), poly(isopropyl chloroacrylate), poly (2-chloroethyl methacrylate), poly(cyclohexyl chloroacrylate), poly(methyl chloroacrylate), polyvinyl acetate, polyallyl acetate, polyvinyl propionate, poly(ethylene 1,5-naphthalate), polyethylene terephthalate, poly(hexamethylene adipamide), poly(ε-capramide), poly(decamethylene adipamide), polycarbonates, polyacetals, polyvinyl formal, polyvinyl butyral, and copolymers of the constituent monomers of the above-named polymers.
Claim 21
Independent Claim 208 words
A method for the production of a coated synthetic paper adapted for offset printing, comprising: preparing a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils, which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 square meter/g., and forming a microporous and discontinuous coating layer on at least one of the surfaces of said base paper sheet with a coating composition consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, poly(α-methylstyrene), poly(4-ethylstyrene), poly(1-vinylnaphthalene), polyvinyl chloride, poly (hexafluoropropylene), polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), polyvinylidene chloride, poly (1,2-difluoroethylene), poly(methyl methacrylate), poly(isopropyl chloroacrylate), poly(2-chloroethyl methacrylate), poly (cyclohexyl chloroacrylate), poly(methyl chloroacrylate), polyvinyl acetate, polyallyl acetate, polyvinyl propionate, poly(ethylene 1,5-naphthalate), polyethylene terephthalate, poly (hexamethylene adipamide), poly(ε-capramide), poly(decamethylene adipamide), polycarbonates, polyacetals, polyvinyl formal, polyvinyl butyral, and copolymers of the constituent monomers of the above-named polymers.
Claim 22
Independent Claim 208 words
A method for the production of a coated synthetic paper adapted for offset printing, comprising: preparing a base paper sheet comprising fibrous material, at least 5% by weight of which is formed of polyolefinic pulp fibrils, which are formed from a polyolefinic polymer and a hydrophilic polymer, said polyolefinic pulp fibrils having a specific surface area of at least 0.7 square meter/g., and forming a microporous and discontinuous coating layer on at least one of the surfaces of said base paper sheet with a coating composition consisting essentially of 5 to 100 parts by weight on a dry weight basis of an adhesive component and 100 parts by weight on a dry weight basis of pigment component, at least 5% by weight on a dry weight basis of said pigment component being an organic polymer pigment in the form of finely divided particles selected from the group consisting of polystyrene, poly(α-methylstyrene), poly(4-ethylstyrene), poly(1-vinylnaphthalene), polyvinyl chloride, poly (hexafluoropropylene), polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), polyvinylidene chloride, poly (1,2-difluoroethylene), poly(methyl methacrylate), poly(isopropyl chloroacrylate), poly(2-chloroethyl methacrylate), poly (cyclohexyl chloroacrylate), poly(methyl chloroacrylate), polyvinyl acetate, polyallyl acetate, polyvinyl propionate, poly(ethylene 1,5-naphthalate), polyethylene terephthalate, poly (hexamethylene adipamide), poly(ε-capramide), poly(decamethylene adipamide), polycarbonates, polyacetals, polyvinyl formal, polyvinyl butyral, and copolymers of the constituent monomers of the above-named polymers.

References Cited (Backward Citations)

GB873682A Cited
US3017295A Cited
US3228790A Cited
US3081519A Cited
US3808091A Cited
US3897300A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-19 1981-06-20 1981-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-19 1985-06-20 1985-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-19 1989-06-20 1989-12-20 $7700.00 Window Closed / Lapsed

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