US4064303A
Expired / Lapsed
US
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Process for decorating heat-stable polymer coating compositions
Assignee: EIDP Inc
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Filing: 1975-08-22
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Granted: 1977-12-20
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Expires: 1995-08-22
Abstract
Abstract The appearance of a heat-stable polymer coating is enhanced by a process which produces a decorative pattern within a heat-stable polymer coating. The process consists essentially of applying, in a decorative pattern, an oxidation catalyst composition which diffuses into the heat-stable polymer coating composition and renders the pattern visible, upon baking, within the baked coat produced by the coating composition.
Inventors
- 👤 Eustathios Vassiliou
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 04:41
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/08; B05D5/083; B05D3/00; B05D3/10; B05D3/102; B05D3/107; B05D5/06; B44; B44C; B44C1/00; B44C1/04; B05D2202/00; B05D2202/20; B05D2202/25; B05D3/104; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24901; Y10T428/24917; Y10T428/31504; Y10T428/31533; Y10T428/31536; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31623; Y10T428/31678; Y10T428/31681; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31757
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
197 words
A process for decorating a heat-stable polymer coating on a substrate; the process consisting essentially of applying a heat-stable polymer composition either directly under or as a subsequent coat over an oxidation catalyst composition which is arranged in a decorative pattern on a substrate, and then baking the coating; wherein the oxidation catalyst or its decomposition product diffuses into the coating and either by reacting with the components of the coating, by catalyzing reactions within the coating or by itself renders, upon baking, the decorative pattern visible within the heat-stable polymer coating; wherein the heat-stable polymer composition comprising: a. heat-stable polymer stable at temperatures above 300° C, said polymer being silicone, polysulfides, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbon, or mixtures thereof, b. a liquid carrier, and C. optionally an oxidation catalyst; D. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2) ______________________________________
(1) Metal
Cobalt Bismuth
Cerium Nickel
Manganese Lead
Iron
(2) Salts
Acetate Octoate
Caprate Oleate
Caprylate Palmitate
Isodecanoate Ricinoleate
Linoleate Stearate
Nitrate Tallate
Naphthenate Soyate.
______________________________________
Claim 2
Dependent Claim
197 words
A process for decorating a heat-stable polymer coating on a substrate; the process consisting essentially of applying a heat-stable polymer composition either directly under or as a subsequent coat over an oxidation catalyst composition which is arranged in a decorative pattern on a substrate, and then baking the coating; wherein the oxidation catalyst or its decomposition product diffuses into the coating and either by reacting with the components of the coating, by catalyzing reactions within the coating or by itself renders, upon baking, the decorative pattern visible within the heat-stable polymer coating; wherein the heat-stable polymer composition comprising: a. heat-stable polymer stable at temperatures above 300° C, said polymer being silicone, polysulfides, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbon, or mixtures thereof, b. a liquid carrier, and C. optionally an oxidation catalyst; D. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2) ______________________________________
(1) Metal
Cobalt Bismuth
Cerium Nickel
Manganese Lead
Iron
(2) Salts
Acetate Octoate
Caprate Oleate
Caprylate Palmitate
Isodecanoate Ricinoleate
Linoleate Stearate
Nitrate Tallate
Naphthenate Soyate.
______________________________________
Claim 3
Dependent Claim
34 words
The process of claim 1 wherein the oxidation catalyst composition contains one or more of the following compounds: ______________________________________
Cobalt octoate Bismuth octoate
Cerium octoate Nickel octoate
Manganese octoate Lead octoate
Iron octoate.
______________________________________
Claim 4
Dependent Claim
48 words
The process of claim 1 wherein the oxidation catalyst composition also includes color enhancers which are heat-unstable organic compounds which decompose to produce colorants, or viscosity builders or thickeners, wetting agents, pigments, decomposable resins and polymers, heat-stable resins and polymers, neutralizers, liquid carriers, or mixtures of the above.
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein the heat-stable polymer is a fluorocarbon.
Claim 6
Dependent Claim
27 words
The process of claim 1 wherein the heat-stable polymer is a hydrocarbon monomer completely substituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms.
Claim 7
Dependent Claim
21 words
The process of claim 1 wherein the heat-stable polymer is polytetrafluoroethylene, copolymer of tetrafluoroethylene and hexafluoropropylene or mixtures of the above.
Claim 8
Dependent Claim
13 words
The process of claim 1 wherein the heat-stable polymer composition contains a colorant.
Claim 9
Dependent Claim
37 words
The process of claim 7 wherein the colorant is carbon black, a carbonaceous residue, a carbonaceous residue precursor or a mixture thereof, in concentrations up to 40% based on the weight of total solids of the composition.
Claim 10
Dependent Claim
63 words
The process of claim 1 wherein the heat-stable polymer composition contains oxidation catalyst(s) selected from compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2). ______________________________________
(1) Metal
Cobalt Bismuth
Cerium Nickel
Manganese Lead
Iron
(2) Salts
Caprate Palmitate
Caprylate Acetate
Isodecanoate Ricinoleate
Linoleate Soyate
Naphthenate Stearate
Octoate Tallate
Oleate Nitrate.
______________________________________
Claim 11
Dependent Claim
35 words
The process of claim 1 wherein the heat-stable polymer composition contains one or more of the following oxidation catalysts: ______________________________________
Cobalt octoate Bismuth octoate
Cerium octoate Nickel octoate
Manganese octoate Lead octoate
Iron octoate.
______________________________________
Claim 12
Dependent Claim
13 words
An article bearing a decorative pattern produced by the process of claim 1.
Claim 13
Dependent Claim
31 words
The process of claim 1 in which the heat-stable polymer is present in the composition at a concentration of at least 25% by weight of the total solids of the composition.
Claim 14
Dependent Claim
32 words
The process of claim 1 in which the heat-stable polymer is present in the composition at a concentration in the range of 25% to 95% of the total solids of the composition.
Claim 15
Dependent Claim
32 words
The process of claim 1 in which the heat-stable polymer is present in the composition at a concentration in the range of 70% to 90% of the total solids of the composition.
Claim 16
Dependent Claim
18 words
The process of claim 1 in which the heat-stable polymer composition is applied over the oxidation catalyst composition.
Claim 17
Dependent Claim
18 words
The process of claim 1 in which the oxidation catalyst composition is applied over the heat-stable polymer composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-12-19 | 1981-06-20 | 1981-12-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-12-19 | 1985-06-20 | 1985-12-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-12-19 | 1989-06-20 | 1989-12-20 | $7700.00 | Window Closed / Lapsed |