US4060583A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrically insulating composition
Assignee: 3M Co
•
Filing: 1976-08-06
•
Granted: 1977-11-29
•
Expires: 1996-08-06
Abstract
Abstract An electrically insulating composition especially adapted for insulating terminations or splices of oil-impregnated cables comprises an electrically insulating organic liquid and a reactive thickening agent. Initially the composition is a liquid having a low viscosity permitting it to be conveniently poured into place in a termination housing or splice casing. After reaction of the thickening agent, the composition thickens to prevent undesired drainage of the composition.
Inventors
- 👤 James D. Groves
- 👤 Stefano Loffredo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 03:28
CPC Classifications
H; H02; H02G; H02G15/00; H02G15/02; H02G15/06; H01; H01B; H01B3/00; H01B3/18; H01B3/20; H01B3/30; H01B3/302; H01B3/307; H02G15/003
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
241 words
A two-part composition disposed in a single unitary package with the parts of the composition stored in separate compartments within the package and adapted upon mixing for use in electrical insulation of oil-impregnated cables, the composition comprising (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least 0° C; and (2) at least two room-temperature-reactive ingredients separated from one another in said parts of the composition and adapted, upon mixing of the parts, to be uniformly and compatibly dispersed in said organic liquid and to chemically react with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition after mixing of said parts, but prior to reaction of said ingredients having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 2
Dependent Claim
241 words
A two-part composition disposed in a single unitary package with the parts of the composition stored in separate compartments within the package and adapted upon mixing for use in electrical insulation of oil-impregnated cables, the composition comprising (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least 0° C; and (2) at least two room-temperature-reactive ingredients separated from one another in said parts of the composition and adapted, upon mixing of the parts, to be uniformly and compatibly dispersed in said organic liquid and to chemically react with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition after mixing of said parts, but prior to reaction of said ingredients having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 3
Dependent Claim
19 words
A composition of claim 1 in which the reactive groups of one of said reactive ingredients comprise isocyanate groups.
Claim 4
Dependent Claim
20 words
A composition of claim 2 in which the reactive groups of the other of said reactive ingredients comprise hydroxyl groups.
Claim 5
Dependent Claim
20 words
A composition of claim 2 in which the reactive groups on the other of said reactive ingredients comprise amine groups.
Claim 6
Dependent Claim
19 words
A composition of claim 1 in which said reactive ingredients comprise less than about 50 weight-percent of the composition.
Claim 7
Dependent Claim
16 words
A composition of claim 1 in which at least one of said ingredients is a prepolymer.
Claim 8
Dependent Claim
272 words
A two-part composition disposed in a single unitary package with the parts of the composition stored in separate compartments within the package and adapted upon mixing for use in electrical insulation of oil-impregnated cables, the composition comprising (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter when tested at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients separated from one another in said parts of the composition, one of said ingredients having isocyanate terminal groups and the other having hydroxyl terminal groups, said ingredients comprising no more than about 35 weight-percent of said composition and being adapted, upon mixing of the parts of the composition, to be uniformly and compatibly dispersed in said organic liquid, and chemically reacting with one another to form a high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid; the isocyanate and hydroxyl coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition after mixing of said parts but prior to reaction of said ingredients, having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 9
Dependent Claim
272 words
A two-part composition disposed in a single unitary package with the parts of the composition stored in separate compartments within the package and adapted upon mixing for use in electrical insulation of oil-impregnated cables, the composition comprising (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter when tested at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients separated from one another in said parts of the composition, one of said ingredients having isocyanate terminal groups and the other having hydroxyl terminal groups, said ingredients comprising no more than about 35 weight-percent of said composition and being adapted, upon mixing of the parts of the composition, to be uniformly and compatibly dispersed in said organic liquid, and chemically reacting with one another to form a high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid; the isocyanate and hydroxyl coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition after mixing of said parts but prior to reaction of said ingredients, having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 10
Dependent Claim
16 words
A composition of claim 7 in which said organic liquid comprises one or more petroleum fractions.
Claim 11
Dependent Claim
17 words
A composition of claim 7 in which at least one of said reactive ingredients is a prepolymer.
Claim 12
Independent Claim
12 words
A method for electrically insulating a section of power transmission line comprising
Claim 13
Independent Claim
12 words
A method for electrically insulating a section of power transmission line comprising
Claim 14
Dependent Claim
22 words
A. placing a housing capable of holding a liquid electrically insulating composition around a base conductor that is to be insulated; and
Claim 15
Dependent Claim
22 words
A. placing a housing capable of holding a liquid electrically insulating composition around a base conductor that is to be insulated; and
Claim 16
Dependent Claim
188 words
B. introducing into the housing a composition that comprises (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at at least 0° C; and (2) at least two room-temperature-reactive ingredients that are uniformly and compatibly dispersed in said organic liquid and that chemically react with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients having a room-temperature viscosity of less than 5000 centipoises, and after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 17
Dependent Claim
188 words
B. introducing into the housing a composition that comprises (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at at least 0° C; and (2) at least two room-temperature-reactive ingredients that are uniformly and compatibly dispersed in said organic liquid and that chemically react with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients having a room-temperature viscosity of less than 5000 centipoises, and after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 18
Dependent Claim
19 words
A method of claim 10 in which the reactive groups on one of said reactive ingredients comprise isocyanate groups.
Claim 19
Dependent Claim
20 words
A method of claim 11 in which the reactive groups on the other of said reactive ingredients comprise hydroxyl groups.
Claim 20
Dependent Claim
19 words
A method of claim 11 in which the reactive groups on the other of said ingredients comprise amine groups.
Claim 21
Dependent Claim
19 words
A method of claim 10 in which said reactive ingredients comprise less than about 50 weight-percent of the composition.
Claim 22
Dependent Claim
17 words
A method of claim 10 in which at least one of said reactive ingredients is a prepolymer.
Claim 23
Dependent Claim
199 words
A composition adapted for use in electrical insulation of oil-impregnated cables and prepared by mixing (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients so that said ingredients are uniformly and compatibly dispersed in said organic liquid, the ingredients chemically reacting with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 24
Dependent Claim
199 words
A composition adapted for use in electrical insulation of oil-impregnated cables and prepared by mixing (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients so that said ingredients are uniformly and compatibly dispersed in said organic liquid, the ingredients chemically reacting with one another at room temperature to form a thermally stable high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid, the coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 25
Dependent Claim
19 words
A composition of claim 16 in which the reactive groups of one of said reactive ingredients comprise isocyanate groups.
Claim 26
Dependent Claim
20 words
A composition of claim 17 in which the reactive groups on the other of said reactive ingredients comprise hydroxyl groups.
Claim 27
Dependent Claim
20 words
A composition of claim 17 in which the reactive groups on the other of said reactive ingredients comprise amine groups.
Claim 28
Dependent Claim
19 words
A composition of claim 16 in which said reactive ingredients comprise less than about 50 weight-percent of the composition.
Claim 29
Dependent Claim
16 words
A composition of claim 16 in which at least one of said ingredients is a prepolymer.
Claim 30
Dependent Claim
227 words
A composition adapted for use in electrical insulation of oil-impregnated cables and prepared by mixing (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter when tested at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients so that the ingredients are uniformly and compatibly dispersed in said organic liquid and comprise no more than about 35 weight-percent of said composition; one of the ingredients having isocyanate terminal groups and the other having hydroxyl terminal groups and the ingredients chemically reacting with one another to form a high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid; the isocyanate and hydroxyl coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients, having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 31
Dependent Claim
227 words
A composition adapted for use in electrical insulation of oil-impregnated cables and prepared by mixing (1) a dry water-immiscible nonvolatile free-flowing organic liquid that has a dielectric strength of at least 6 kilovolts per millimeter when tested at a gap of 2.5 millimeters, a dielectric constant of no more than about 10, and a dissipation factor of no more than about 0.2, and that remains liquid at least at 0° C; and (2) at least two room-temperature-reactive ingredients so that the ingredients are uniformly and compatibly dispersed in said organic liquid and comprise no more than about 35 weight-percent of said composition; one of the ingredients having isocyanate terminal groups and the other having hydroxyl terminal groups and the ingredients chemically reacting with one another to form a high-viscosity thickening agent that is uniformly and compatibly dispersed in said organic liquid; the isocyanate and hydroxyl coreactive groups of said ingredients averaging between about 1.8 and 2.3 per molecule; said composition prior to reaction of said ingredients, having a room-temperature viscosity of less than about 10,000 centipoises; and said composition, after reaction of said ingredients, (a) being flowable so as to assume the shape of its container, (b) having a room-temperature viscosity of at least 50,000 centipoises, and (c) having a variation in viscosity in the temperature interval 25° C to 100° C of at least 10,000 centipoises.
Claim 32
Dependent Claim
16 words
A composition of claim 22 in which said organic liquid comprises one or more petroleum fractions.
Claim 33
Dependent Claim
17 words
A composition of claim 22 in which at least one of said reactive ingredients is a prepolymer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-11-28 | 1981-05-30 | 1981-11-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-11-28 | 1985-05-30 | 1985-11-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-11-28 | 1989-05-30 | 1989-11-29 | $7700.00 | Window Closed / Lapsed |