Antistatic dyeable polyamide composition

Claim 2

A polyamide composition prepared by admixing (A) a polyamide; (B) an antistatic agent comprising the reaction product of (1) at least one tetrol compound of the formula: ##STR2## where a, b, c, d, e, f, g, and hare each a whole number and the total of a, b, c, and d is between 8 and 1,000 and the total of e, f, g, and h is between 8 and 850, Q is an alkylene radical containing 1 to 13 carbon atoms, wherein the molecular weight of said tetrol compound is between about 1,650 and about 135,000 and said (OCH 2 CH 2 ) moieties make up from about 10 to about 90 weight percent of said tetrol compound, and (2) at least one dicarboxylic acid ester having the formula R'OOC--A--COOR' wherein A is a valence bond or a divalent hydrocarbyl radical having from 1 to 8 carbon atoms and R' is an alkyl group containing 1 to 4 carbon atoms or a hydroxyalkyl group containing 2 to 4 carbon atoms, wherein the two R' radicals may be the same or different; and (C) at least one zinc alkyl sulfinate of the formula: Zn(R"SO.sub.2).sub.2 wherein R" is an alkyl group containing from 4 to 20 carbon atoms; wherein the amount of antistatic agent is that which is sufficient to improve the antistatic characteristics of said polyamide and the amount of zinc alkyl sulfinate is such that when said polyamide composition is dyed with an acid dye, the K/S value will be greater than that which would be observed if the zinc alkyl sulfinate were not present in said polyamide composition.

Claim 3

A polyamide composition according to claim 1 wherein said zinc alkyl sulfinate is added to a melt of said antistatic agent and the resulting composition is compounded with the polyamide.

Claim 4

A polyamide composition according to claim 2 wherein said zinc alkyl sulfinate is employed in an amount in the range of about 0.02 to about 2.5 weight percent based on the weight of the polyamide plus the weight of the antistatic agent.

Claim 5

A composition according to claim 3 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 6

A composition according to claim 4 wherein the polyamide is poly(hexamethylene adipamide) and the antistatic agent is one prepared by reacting dimethyl terephthalate with a tetrol compound having an ethylene oxide moiety content of about 60 weight percent and a molecular weight of about 20,000.

Claim 7

A composition according to claim 5 wherein the amount of said antistatic agent is in the range of from about 1 to about 12 weight percent based on the weight of the polyamide and the antistatic agent.

Claim 8

A composition according to claim 6 which is a filament which has been dyed with an acid dye selected from Merpacyl Blue 2GA, Merpacyl Blue SW, and Lanasyn Brilliant Red RL.

Claim 9

A composition according to claim 4 wherein the polyamide is poly(hexamethylene adipamide) and the antistatic agent is one prepared by reacting dimethyl terephthalate with a tetrol compound having an ethylene oxide moiety content of about 40 weight percent and a molecular weight of about 12,500.

Claim 10

A composition according to claim 8 wherein the amount of antistatic agent is in the range of about 1 to about 12 weight percent based on the weight of the polyamide plus antistatic agent.

Claim 11

A composition according to claim 9 which is a filament which has been dyed with an acid dye selected from Merpacyl Blue 2GA, Merpacyl Blue SW, and Lanasyn Brilliant Red RL.

Claim 12

A composition according to claim 3 wherein there is also admixed with said polyamide, said antistatic agent and said zinc alkyl sulfinate, an antioxidant selected from the group consisting of 2,6-di-t-butyl-4-methylphenol, octadecyl[3-(3,5-di-t-butyl-4-hydroxyphenyl)] propionate, di-n-octadecyl(3,5-di-t-butyl-4-hydroxybenzyl) phosphonate, tetrakis[methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl) benzene and tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanurate, wherein said antioxidant is present in an amount of about 0.02 to about 2.0 weight percent based on the weight of the polyamide plus the antistatic agent.

Claim 13

In the forming of a polyamide composition by admixing ingredients comprising (A) a polyamide and (B) an antistatic agent comprising the reaction product of (1) at least one tetrol compound of the formula: ##STR3## where a, b, c, d, e, f, g, and h are each a whole number and the total of a, b, c, and d is between 8 and 1,000 and the total of e, f, g, and h is between 8 and 850, Q is an alkylene radical containing 1 to 13 carbon atoms, wherein the molecular weight of said tetrol compound is between about 1,650 and about 135,000 and said (OCH 2 CH 2 ) moieties make up from about 10 to about 90 weight percent of said tetrol compound, and (2) at least one dicarboxylic acid ester having the formula R'OOC--A--COOR' wherein A is a valence bond or a divalent hydrocarbyl radical having from 1 to 8 carbon atoms and R' is an alkyl group containing 1 to 4 carbon atoms or a hydroxyalkyl group containing 2 to 4 carbon atoms, wherein the two R' radicals may be the same or different; the method of obtaining a polyamide composition which when dyed with an acid dye will exhibit greater depth of dyeing than a composition consisting only of said polyamide and said antistatic agent, said method comprising employing as an ingredient in the forming of said polyamide composition at least one zinc sulfinate of the formula: Zn(R"SO.sub.2).sub.2 wherein R" is an alkyl group containing 4 to 20 carbon atoms, said zinc alkyl sulfinate being employed in such an amount that when said polyamide composition is dyed the K/S value will be greater than that of a composition consisting only of said polyamide and said antistatic agent.

Claim 14

In the forming of a polyamide composition by admixing ingredients comprising (A) a polyamide and (B) an antistatic agent comprising the reaction product of (1) at least one tetrol compound of the formula: ##STR3## where a, b, c, d, e, f, g, and h are each a whole number and the total of a, b, c, and d is between 8 and 1,000 and the total of e, f, g, and h is between 8 and 850, Q is an alkylene radical containing 1 to 13 carbon atoms, wherein the molecular weight of said tetrol compound is between about 1,650 and about 135,000 and said (OCH 2 CH 2 ) moieties make up from about 10 to about 90 weight percent of said tetrol compound, and (2) at least one dicarboxylic acid ester having the formula R'OOC--A--COOR' wherein A is a valence bond or a divalent hydrocarbyl radical having from 1 to 8 carbon atoms and R' is an alkyl group containing 1 to 4 carbon atoms or a hydroxyalkyl group containing 2 to 4 carbon atoms, wherein the two R' radicals may be the same or different; the method of obtaining a polyamide composition which when dyed with an acid dye will exhibit greater depth of dyeing than a composition consisting only of said polyamide and said antistatic agent, said method comprising employing as an ingredient in the forming of said polyamide composition at least one zinc sulfinate of the formula: Zn(R"SO.sub.2).sub.2 wherein R" is an alkyl group containing 4 to 20 carbon atoms, said zinc alkyl sulfinate being employed in such an amount that when said polyamide composition is dyed the K/S value will be greater than that of a composition consisting only of said polyamide and said antistatic agent.

Claim 15

A method according to claim 12 wherein prior to being incorporated into said polyamide said antistatic agent is melted and said zinc alkyl sulfinate is blended with the melted antistatic agent.

Claim 16

A method according to claim 13 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 17

A composition according to claim 11 wherein said antioxidant is tetrakis [methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane.

Claim 18

A composition according to claim 15 wherein the polyamide is poly(hexamethylene adipamide) and the antistatic agent is one prepared by reacting dimethyl terephthalate with a tetrol compound having an ethylene oxide moiety content of about 60 weight percent and a molecular weight of about 20,000, said antistatic agent is present in an amount in the range of about 1 to about 12 weight percent based upon the weight of the polyamide plus antistatic agent, and the composition is a filament which has been dyed with Merpacyl Blue 2GA or Lanasyn Brilliant Red RL.

Claim 19

A composition according to claim 15 wherein the polyamide is poly(hexamethylene adipamide), the antistatic agent is one prepared by reacting dimethyl terephthalate with a tetrol compound having an ethylene oxide moiety content of about 40 weight percent and a molecular weight of about 12,500, said antistatic agent being present in an amount in the range of about 1 to about 12 weight percent based upon the weight of the polyamide and the antistatic agent, and said composition is a filament which has been dyed with Merpacyl Blue 2GA or Lanasyn Brilliant Red RL.

Claim 20

A composition according to claim 3 which also contains a stabilizing amount of a hindered phenol-type antioxidant.

Claim 21

A method according to claim 14 wherein said zinc alkyl sulfinate is present in an amount in the range of about 0.02 to about 2.5 weight percent based on the weight of the polyamide plus the weight of the antistatic agent.

Claim 22

A composition according to claim 16 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 23

A composition according to claim 20 wherein said antioxidant is added to the melt of said antistatic agent.

Claim 24

A composition according to claim 17 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 25

A composition according to claim 22 wherein said antioxidant is added to the melt of said antistatic agent.

Claim 26

A composition according to claim 18 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 27

A composition according to claim 1 wherein said zinc alkyl sulfinate and said antistatic agent are each added separately to said polyamide.

Claim 28

A composition according to claim 25 wherein said antistatic agent is employed in an amount in the range of about 1 to about 12 weight percent based upon the weight of the polyamide plus antistatic agent and said zinc alkyl sulfinate is employed in an amount in the range of about 0.02 to about 2.5 weight percent based on the weight of the polyamide plus antistatic agent.

Claim 29

A composition according to claim 26 wherein the antistatic agent is one prepared by reacting dimethyl terephthalate with a tetrol compound having an ethylene oxide moiety of about 60 weight percent and a molecular weight of about 20,000, and the zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 30

A composition according to claim 27 wherein included in the ingredients is a hindered phenol-type antioxidant is an amount in the range of about 0.02 to about 2.0 weight percent based on the weight of the polyamide and the antistatic agent.

Claim 31

A composition according to claim 28 wherein said antioxidant is tetrakis[methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane.

Claim 32

A composition according to claim 1 wherein said zinc alkyl sulfinate is employed in an amount in the range of about 0.02 to about 2.5 weight percent based on the weight of the polyamide plus the weight of the antistatic agent and wherein said antistatic agent is employed in an amount in the range of about 1 to about 12 weight percent based on the weight of the polyamide plus antistatic agent.

Claim 33

A composition according to claim 30 wherein said zinc alkyl sulfinate is zinc 1-dodecanesulfinate.

Claim 34

A composition according to claim 31 wherein included in the ingredients is a hindered phenol-type antioxidant in an amount in the range of about 0.02 to about 2.0 weight percent based on the weight of the polyamide and the antistatic agent.

Claim 35

A composition according to claim 32 wherein said hindered phenoltype antioxidant is tetrakis[methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane.

Claim 36

A composition according to claim 33 wherein said composition is a filament which has been dyed with an acid dye.

Claim 37

A composition according to claim 31 wherein said composition is a filament which has been dyed with an acid dye.

Claim 38

A method according to claim 12 wherein said zinc alkyl sulfinate is added to said polyamide after said antistatic agent has been added to said polyamide.