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US4059437A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxygen-free copper product and process

Assignee: Phelps Dodge Industries Inc
•
Filing: 1975-07-02
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Granted: 1977-11-22
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Expires: 1995-07-02
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Abstract

Abstract An improved copper product and process of making it, wherein oxygen-free copper contains small amounts of manganese above normal impurity levels, and has enhanced grain size control during annealing, high electrical conductivity, and increased ductility as cast or fabricated. By adding approximately 1 to approximately 100 parts per million of manganese, the desired oxygen-free product has a minimum electrical conductivity of 100% I.A.C.S. By adding approximately 1 to approximately 50 parts per million of manganese, the desired oxygen-free product has a minimum electrical conductivity of 101% I.A.C.S. When at least approximately 30 parts per million of manganese are added to the oxygen-free copper, ductility is maximized. The manganese may be added at any convenient stage of producing the oxygen-free copper. The copper after annealing is free of or less subject to roughened surfaces or cracking.

Inventors

  • 👤 Donald John Nesslage
  • 👤 Lin Sheng Yu
  • 👤 Michael Francis Shaw

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 08:08
CPC Classifications
C; C22; C22C; C22C9/00; C22C9/05; H; H01; H01B; H01B1/00; H01B1/02; H01B1/026

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 42 words
An improved oxygen-free copper product consisting essentially of non-deoxidized oxygen-free copper containing normal impurities and manganese in addition from approximately 1 to approximately 100 parts per million by weight, further characterized by having a minimum electrical conductivity of at least 100% I.A.C.S.
Claim 2
Dependent Claim 42 words
An improved oxygen-free copper product consisting essentially of non-deoxidized oxygen-free copper containing normal impurities and manganese in addition from approximately 1 to approximately 100 parts per million by weight, further characterized by having a minimum electrical conductivity of at least 100% I.A.C.S.
Claim 3
Dependent Claim 32 words
The invention defined in claim 1, wherein the manganese in addition is no more than approximately 50 parts per million by weight, and the minimum electrical conductivity is at least 101% I.A.C.S.
Claim 4
Dependent Claim 21 words
The invention defined in claim 1, wherein the manganese in addition is at least approximately 30 parts per million by weight.
Claim 5
Dependent Claim 21 words
The invention defined in claim 2, wherein the manganese in addition is at least approximately 30 parts per million by weight.
Claim 6
Dependent Claim 16 words
The invention defined in claim 1, wherein the copper product has been cold worked and annealed.
Claim 7
Dependent Claim 16 words
The invention defined in claim 2, wherein the copper product has been cold worked and annealed.
Claim 8
Dependent Claim 23 words
The invention defined in claim 5, wherein the grain size of the product is relatively homogeneous and the product has a smooth surface.
Claim 9
Dependent Claim 23 words
The invention defined in claim 6, wherein the grain size of the product is relatively homogeneous and the product has a smooth surface.
Claim 10
Dependent Claim 43 words
A process of providing an improved oxygen-free copper, wherein the copper is processed to be free from oxygen by conventional non-deoxidizing means, and manganese is added during the processing in an amount from approximately 1 to approximately 100 parts per million by weight.
Claim 11
Dependent Claim 43 words
A process of providing an improved oxygen-free copper, wherein the copper is processed to be free from oxygen by conventional non-deoxidizing means, and manganese is added during the processing in an amount from approximately 1 to approximately 100 parts per million by weight.
Claim 12
Dependent Claim 21 words
The invention defined in claim 9, wherein the manganese added is no more than approximately 50 parts per million be weight.
Claim 13
Dependent Claim 20 words
The invention defined in claim 9, wherein the manganese added is at least approximately 30 parts per million by weight.
Claim 14
Dependent Claim 20 words
The invention defined in claim 10, wherein the manganese added is at least approximately 30 parts per million by weight.
Claim 15
Dependent Claim 19 words
The invention defined in claim 9, wherein the oxygen-free copper with added manganese is subsequently cold worked and annealed.
Claim 16
Dependent Claim 19 words
The invention defined in claim 10, wherein the oxygen-free copper with added manganese is subsequently cold worked and annealed.
Claim 17
Dependent Claim 56 words
An improved oxygen-free copper product consisting essentially of non-deoxidized oxygen-free copper containing normal impurities and manganese in addition from approximately 1 to approximately 100 parts per million by weight, further characterized by having been annealed, having a minimum electrical conductivity of at least 100% I.A.C.S., and having a controlled grain structure of relatively homogeneous grain sizes.
Claim 18
Dependent Claim 56 words
An improved oxygen-free copper product consisting essentially of non-deoxidized oxygen-free copper containing normal impurities and manganese in addition from approximately 1 to approximately 100 parts per million by weight, further characterized by having been annealed, having a minimum electrical conductivity of at least 100% I.A.C.S., and having a controlled grain structure of relatively homogeneous grain sizes.
Claim 19
Dependent Claim 32 words
The invention defined in claim 15, wherein the manganese in addition is no more than approximately 50 parts per million by weight, and the minimum electrical conductivity is at least 101% I.A.C.S.
Claim 20
Dependent Claim 21 words
The invention defined in claim 15, wherein the manganese in addition is at least approximately 30 parts per million by weight.
Claim 21
Dependent Claim 21 words
The invention defined in claim 16, wherein the manganese in addition is at least approximately 30 parts per million by weight.
Claim 22
Dependent Claim 53 words
A process of controlling grain size during annealing in oxygen-free copper to obtain relatively homogeneous grain sizes, wherein the copper is processed to be free from oxygen by conventional non-deoxidizing means, manganese is added in an amount from approximately 1 to approximately 100 parts per million by weight, and the copper is annealed.
Claim 23
Dependent Claim 53 words
A process of controlling grain size during annealing in oxygen-free copper to obtain relatively homogeneous grain sizes, wherein the copper is processed to be free from oxygen by conventional non-deoxidizing means, manganese is added in an amount from approximately 1 to approximately 100 parts per million by weight, and the copper is annealed.
Claim 24
Dependent Claim 21 words
The invention defined in claim 19, wherein the manganese added is no more than approximately 50 parts per million by weight.
Claim 25
Dependent Claim 20 words
The invention defined in claim 19, wherein the manganese added is at least approximately 30 parts per million by weight.
Claim 26
Dependent Claim 20 words
The invention defined in claim 20, wherein the manganese added is at least approximately 30 parts per million by weight.

References Cited (Backward Citations)

US1660220A Cited
GB379034A Cited
US2003296A Cited
US2003889A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-21 1981-05-23 1981-11-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-21 1985-05-23 1985-11-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-21 1989-05-23 1989-11-22 $7700.00 Window Closed / Lapsed

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