Photopolymerizable composition for formed-in-place artificial nails

Claim 2

A composition that is readily applicable to human nails for cosmetic, protective and other purposes, and that polymerizes upon exposure to ultraviolet radiation, for the production of artificial nails by direct application to human nail tissue and curing by exposure to a controlled source of radiation, consisting essentially of, in admixture: i. from about 40% to about 90% by weight of the composition of a monofunctional ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with metyl, ethyl, propyl, isopropyl, butyl, isobutyl, furfuryl, tetrahydrofurfuryl and glycidyl alcohols, and mixtures of such esters; ii. from about 3% to about 40% by weight of the composition of an ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with polyhydric alcohols containing 2 to 4 hydroxyl groups and mixtures of such esters; iii. from about 0.1% to about 30% by weight of the composition of an initiator that acts upon exposure to ultraviolet radiation to initiate polymerization, and iv. from about 5% to about 25% by weight of the composition of a modifier that is soluble or swellable in the admixture and is selected from the group consisting of particulate cured elastomers up to 300 microns in particle size, and mixtures of such elastomers with a particulate cellulose ester or a particulate cellulose ether-ester having up to 300 micron particle size in the ratio of at least 4.5 parts by weight of the former to each one party by weight of the latter, said composition being characterized in that the composition after curing exhibits: an in vivo adhesion to natural human nails of at least about 25 pounds per square inch; a flexural modulus of elasticity of at least 50 × 10 3 pounds/square inch; a flexural strength of at least 3000 pounds/square inch, and an elongation to break under flexural stress of at least 3.5% as measured under ambient pressure and temperature conditions.

Claim 3

A photopolymerizable composition according to claim 1 which also exhibits in its cured state a translucency of from about 50% to about 75%.

Claim 4

A composition in accordance with claim 1 that in its uncured state, ready for application to nails, is characterized by a consistency of from 5 to 3000 seconds as measured by a sphere immersion test in which the time is observed that is required for a smooth glass sphere having a diameter of 0.875 inches and a density of 2.14 g/cm 3 to submerge completely in the composition, following release from a position in which the sphere just touches the surface of the composition.

Claim 5

A composition in accordance with claim 1 that also contains from about 2% to 10% by weight of a filler that is selected from the group consisting of colloidal silica and particulate mineral fillers having an average particle size of not more than about 60 microns.

Claim 6

A composition that is readily applicable to human nails for cosmetic, protective and other purposes, and that polymerizes upon exposure to ultraviolet light, for the production of artificial nails by direct application to human nail tissue and curing by exposure to a controlled source of ultraviolet light, consisting essentially of, in admixture: i. from about 70% to about 80% by weight of the composition of a monofunctional ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with methyl, ethyl, propyl, isopropyl, butyl, isobutyl, furfuryl, tetrahydrofurfuryl and glycidyl alcohols, and mixtures of such esters; ii. from about 3% to about 10% by weight of the composition of an ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with polyhydric alcohols containing 2 to 4 hydroxyl groups and mixtures of such esters; iii. from about 0.2% to about 5% by weight of the composition of an initiator that acts upon exposure to ultraviolet light to initiate polymerization, and iv. from about 12% to about 18% by weight of the composition of a modifier that is soluble or swellable in the admixture and is selected from the group consisting of particulate cured elastomers up to 300 microns in particle size, and mixtures of such elastomers with a particulate cellulose ester or a particulate cellulose ether-ester having up to 300 micron particle size in the ratio of at least 4.5 parts by weight of the former to each one part by weight of the latter, said composition being characterized in that the composition after curing exhibits a flexural modulus of elasticity of from about 150 × 10 3 to about 300 × 10 3 psi, a flexural strength of from about 5000 to about 10,000 psi, an elongation to break under flexural stress of from about 5% to 7% as measured under ambient pressure and temperature conditions, an in vivo adhesion to natural human nails of at least about 30 pounds per square inch, and a translucency of from about 75% to about 75%.

Claim 7

A composition that is readily applicable to human nails for cosmetic, protective and other purposes, and that polymerizes upon exposure to ultraviolet light, for the production of artificial nails by direct application to human nail tissue and curing by exposure to a controlled source of ultraviolet light, consisting essentially of, in admixture: i. from about 70% to about 80% by weight of the composition of a monofunctional ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with methyl, ethyl, propyl, isopropyl, butyl, isobutyl, furfuryl, tetrahydrofurfuryl and glycidyl alcohols, and mixtures of such esters; ii. from about 3% to about 10% by weight of the composition of an ester monomer selected from the group consisting of esters of acrylic acid and 1-4 carbon alkyl-substituted acrylic acids with polyhydric alcohols containing 2 to 4 hydroxyl groups and mixtures of such esters; iii. from about 0.2% to about 5% by weight of the composition of an initiator that acts upon exposure to ultraviolet light to initiate polymerization, and iv. from about 12% to about 18% by weight of the composition of a modifier that is soluble or swellable in the admixture and is selected from the group consisting of particulate cured elastomers up to 300 microns in particle size, and mixtures of such elastomers with a particulate cellulose ester or a particulate cellulose ether-ester having up to 300 micron particle size in the ratio of at least 4.5 parts by weight of the former to each one part by weight of the latter, said composition being characterized in that the composition after curing exhibits a flexural modulus of elasticity of from about 150 × 10 3 to about 300 × 10 3 psi, a flexural strength of from about 5000 to about 10,000 psi, an elongation to break under flexural stress of from about 5% to 7% as measured under ambient pressure and temperature conditions, an in vivo adhesion to natural human nails of at least about 30 pounds per square inch, and a translucency of from about 75% to about 75%.

Claim 8

A composition in accordance with claim 5 that in its uncured state, ready for application to nails, is characterized by a consistency of from 1000 to 25000 seconds as measured by a sphere immersion test in which the time is observed that is required for a smooth glass sphere having a diameter of 0.875 inches and a density of 2.15 g/cm 3 to submerge completely in the composition, following release from a position in which the sphere just touches the surface of the composition.

Claim 9

A composition in accordance with claim 5 in which component (iv) comprises at least 5 parts by weight of particulate methacrylate/butadiene/styrene block copolymer of generally 1:1:1 monomer ratio and not more than 1 part by weight of particulate cellulose acetate butyrate.

Claim 10

A composition in accordance with claim 5 comprising about 73% by weight tetrahydrofurfuryl methacrylate, about 8% by weight diethylene glycol dimethacrylate, and 0.4% by weight 3-benzoyl-1, 3-diephenyl dioxolane, about 14% by weight particulate block copolymer of methacrylate/styrene/butadiene in 1:1:1 monomer ratio, and about 2% by weight cellulose acetate butyrate.

Claim 11

A photopolymerizable composition according to claim 5 in which component (i) is tetrahydrofurfuryl methacrylate.

Claim 12

A photopolymerizable composition according to claim 5 in which component (ii) is diethylene glycol dimethacrylate.

Claim 13

A photopolymerizable composition according to claim 5 in which component (iii) is a compound of the formula ##STR4## wherein R 1 and R 2 are selected from H and organic radicals having a molecular weight of not more than 210 and Ar 1 and Ar 2 are selected from the group consisting of phenyl, naphthyl and non-sterically hindered substituted phenyl and naphthyl rings wherein each substitutent has a molecular weight of not more than 210.

Claim 14

A photopolymerizable composition according to claim 11 in which Ar 1 and Ar 2 , R 1 are each phenyl and R 2 is methyl.

Claim 15

A photopolymerizable composition according to clam 11 in which Ar 1 , Ar 2 and R 2 are phenyl and R 1 is H.

Claim 16

A photopolymerizable composition according to clam 11 in which Ar 1 , Ar 2 and R 2 are phenyl and R 1 is H.

Claim 17

A photopolymerizable composition according to claim 11 in which Ar 1 , Ar 2 and R 2 are phenyl and R 1 is methyl.

Claim 18

A composition that is readily applicable to human nails for cosmetic, protective and other purposes, and that polymerizes upon exposure to actinic light, for the production of artificial nails by direct application to human nail tissue and curing by exposure to a controlled source of actinic light, consisting essentially of, in admixture: i. from about 70% to about 80% by weight of the composition of the monofunctional ester monomer, tetrahydrofurfuryl methacrylate; ii. from about 3% to about 10% by weight of the composition of the ester monomer, diethylene glycol dimethacrylate; iii. from about 0.2% to about 5% by weight of the composition of an initiator that acts upon exposure to ultraviolet light to initiate polymerization, and iv. from about 12% to about 18% by weight of the composition of a particulate cured elastomer that is soluble or swellable in the composition, the particles of which are up to 300 microns in particle size, said composition after curing exhibiting a flexural modulus of elasticity of from about 150 × 10 3 to about 300 × 10 3 psi, a flexural strength of from about 5000 to about 10,000 psi, an elongation to break under flexural stress of from about 5% to 7%, an in vivo adhesion to natural human nails of from about 3 psi to about 200 psi, and a translucency of from about 50% to about 75%; said composition in its uncured state, ready for application to nails, being characterized by a consistency of from 1000 to 2500 seconds as measured by a sphere immersion test in which the time is observed that is required for a smooth glass sphere having a diameter of 0.875 inches and a density of 2.14 g/cm 3 to submerge completely in the composition, following release from a position in which the sphere just touches the surface of the composition.

Claim 19

A composition that is readily applicable to human nails for cosmetic, protective and other purposes, and that polymerizes upon exposure to actinic light, for the production of artificial nails by direct application to human nail tissue and curing by exposure to a controlled source of actinic light, consisting essentially of, in admixture: i. from about 70% to about 80% by weight of the composition of the monofunctional ester monomer, tetrahydrofurfuryl methacrylate; ii. from about 3% to about 10% by weight of the composition of the ester monomer, diethylene glycol dimethacrylate; iii. from about 0.2% to about 5% by weight of the composition of an initiator that acts upon exposure to ultraviolet light to initiate polymerization, and iv. from about 12% to about 18% by weight of the composition of a particulate cured elastomer that is soluble or swellable in the composition, the particles of which are up to 300 microns in particle size, said composition after curing exhibiting a flexural modulus of elasticity of from about 150 × 10 3 to about 300 × 10 3 psi, a flexural strength of from about 5000 to about 10,000 psi, an elongation to break under flexural stress of from about 5% to 7%, an in vivo adhesion to natural human nails of from about 3 psi to about 200 psi, and a translucency of from about 50% to about 75%; said composition in its uncured state, ready for application to nails, being characterized by a consistency of from 1000 to 2500 seconds as measured by a sphere immersion test in which the time is observed that is required for a smooth glass sphere having a diameter of 0.875 inches and a density of 2.14 g/cm 3 to submerge completely in the composition, following release from a position in which the sphere just touches the surface of the composition.

Claim 20

A composition in accordance with claim 15 in which component (iii) is a compound of the formula ##STR5## wherein R 1 and R 2 are selected from H and organic radicals having a molecular weight of not more than 210 and Ar 1 and Ar 2 are selected from the group consisting of phenyl, naphthyl, and non-sterically hindered substituted phenyl and naphthyl rings wherein each substituent has a molecular weight of not more than 210; and component (iv) is a particulate methacrylate/butadiene/styrene block copolymer of 1:1:1 monomer ratio.