Diaminotrihalopropyl triazines: and their methylol derivatives
Abstract
Abstract 2,4-Diamino-6(3,3,3-tribromo-1-propyl)-1,3,5-triazine and 2,4-diamino-6(3,3,3-trichloro-1-propyl)-1,3,5-triazine were prepared by the reaction of the corresponding methyl or ethyl gamma -tribromo-butyrate or methyl or ethyl gamma -trichlorobutyrate with biguanide. The N-methylol derivatives of the diaminotrihalopropyl triazines were prepared by the reaction of the triazines with aqueous formaldehyde. Two pure tetramethylol derivatives were prepared, namely: 2,4-bis[bis(hydroxymethyl)amino]-6-(3,3,3-tribromo-1-propyl)-1,3,5-tri azine and 2,4-bis[bis(hydroxymethyl)amino]-6-(3,3,3-trichloro-1-propyl)-1,3,5-tr iazine. The tetramethylol derivatives were used to impart durable flame retardancy and wrinkle recovery to cellulosic textiles, particularly to cotton. Flame-retardancy was also imparted to wool and to blends of cotton and polyester.
Inventors
- 👤 Leon H. Chance
- 👤 Judy D. Timpa
Bibliographic Details
Claims Analysis
Total Claims: 8References Cited (Backward Citations)
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