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US4054707A Expired / Lapsed US ⏱️ 0.0 years remaining

Sulphonated polyaryl-ether-sulphones and membranes thereof

Assignee: Rhone Poulenc Industries SA
•
Filing: 1975-12-23
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Granted: 1977-10-18
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Expires: 1995-12-23
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Abstract

Abstract Novel sulphonated polyaryl-ether-sulphone resins are described which are particularly suitable for producing semi-permeable membranes, in particular for reverse osmosis. These resins consist essentially of a plurality of units of the formula: ##STR1## and, optionally, a plurality of units of the formula: ##STR2## in which A 1 , A 2 , A 3 , A 4 and A 5 each represents a phenylene radical at least one of which is substituted by an optionally salified sulpho (--SO 3 H) radical, the relative proportions of units of formula (I) and (II) and the degree of substitution by sulpho radicals being such that the number of sulpho groups is from about 0.1 to about 5 milliequivalents per gram of dry resin.

Inventors

  • 👤 Jean-Pierre Quentin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 22:27
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/66; B01D71/68; B01D69/00; B01D69/12; C; C08; C08G; C08G65/00; C08G65/34; C08G65/48; C08G75/00; C08G75/20; C08G75/23; C08G2650/00; C08G2650/02; C08G2650/20; C08G2650/62; C08G2650/64; C08L; C08L2312/00; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24992; Y10T428/31504; Y10T428/31533

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 103 words
A sulphonated polyaryl-ether-sulphone resin which consists essentially of a plurality of units of the formula: ##STR6## and, optionally, a plurality of units of the formula: ##STR7## in which A 1 , A 2 , A 3 , A 4 and A 5 each represents a phenylene radical at least one of which is substituted by a sulpho (--SO 3 H) or salified sulpho radical, the relative proportions of units of formula (I) and (II) and the degree of substitution by sulpho radicals being such that the number of sulpho groups is from about 0.1 to about 5 milliequivalents per gram of dry resin.
Claim 2
Dependent Claim 103 words
A sulphonated polyaryl-ether-sulphone resin which consists essentially of a plurality of units of the formula: ##STR6## and, optionally, a plurality of units of the formula: ##STR7## in which A 1 , A 2 , A 3 , A 4 and A 5 each represents a phenylene radical at least one of which is substituted by a sulpho (--SO 3 H) or salified sulpho radical, the relative proportions of units of formula (I) and (II) and the degree of substitution by sulpho radicals being such that the number of sulpho groups is from about 0.1 to about 5 milliequivalents per gram of dry resin.
Claim 3
Dependent Claim 24 words
A sulphonated polysulphone according to claim 1 which contains from about 0.6 to about 2 milliequivalents of sulpho radicals per gram of dry resin.
Claim 4
Dependent Claim 16 words
A sulphonated polysulphone according to claim 1 which is in the form of the free acid.
Claim 5
Dependent Claim 23 words
A sulphonated polysulphone according to claim 1 which is in the form of an ammonium or alkali metal or alkaline earth metal salt.
Claim 6
Dependent Claim 22 words
A sulphonated polysulphone according to claim 1 having a total number of units of formula (I) and (II) from 18 to 30.
Claim 7
Dependent Claim 15 words
A sulphonated polysulphone according to claim 1 which is in the form of a membrane.
Claim 8
Dependent Claim 37 words
A sulphonated polysulphone according to claim 6 which is in the form of an anisotropic membrane possessing a) a thin dense or micro-porous layer and b) a relatively thick layer which is more porous than layer a).
Claim 9
Dependent Claim 34 words
A sulphonated polysulphone according to claim 6 which is in the form of a composite membrane, the resin being in the form of a thin dense or microporous layer deposited on a porous support.

References Cited (Backward Citations)

US3709841A Cited
US3554972A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-17 1981-04-18 1981-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-17 1985-04-18 1985-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-17 1989-04-18 1989-10-18 $7700.00 Window Closed / Lapsed

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