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US4054705A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for decorating coatings produced by heat-stable polymer compositions

Assignee: EIDP Inc
•
Filing: 1976-04-19
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Granted: 1977-10-18
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Expires: 1996-04-19
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Abstract

Abstract The appearance of a heat-stable polymer coating is enhanced by a process which produces a decorative pattern within a coating produced by a heat-stable polymer coating composition. The process consists of applying a heat-stable polymer composition as a subsequent coat over or directly under an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns and which diffuse into the heat-stable polymer coating composition and render the patterns visible, upon baking, within the baked coat produced by the coating composition.

Inventors

  • 👤 Eustathios Vassiliou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 04:41
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/06; C; C09; C09D; C09D5/00; C09D5/28; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24901; Y10T428/24917; Y10T428/31504; Y10T428/31533; Y10T428/31536; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31623; Y10T428/31678; Y10T428/31681; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31757

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 210 words
A process for decorating a heat-stable polymer coating on a substrate, the process consisting essentially of applying a heat-stable polymer composition which is stable at temperatures above 300° C either as a subsequent coat over or directly under or between an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns on a substrate and then baking the coating wherein the antioxidant or its decomposition product and the oxidation catalyst or its decomposition products diffuse into the coating and either by reacting with components of the coating, by catalyzing or hindering reactions within the coating or by themself render, upon baking, the decorative pattern visible within the heat-stable polymer coatings wherein the heat-stable polymer composition comprising: a. a heat-stable polymer, said polymer being silicone, polysulfide, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbons, or mixtures of the above, b. a liquid carrier, c. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2): ______________________________________ (1) Metals Cobalt Bismuth Cerium Nickel Manganese Lead Iron (2) Salts Acetate Octoate Caprate Oleate Caprylate Palmintate Isodecanoate Ricinoleate Linoleate Soyate Naphthenate Stearate Nitrate Tallate. ______________________________________
Claim 2
Dependent Claim 210 words
A process for decorating a heat-stable polymer coating on a substrate, the process consisting essentially of applying a heat-stable polymer composition which is stable at temperatures above 300° C either as a subsequent coat over or directly under or between an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns on a substrate and then baking the coating wherein the antioxidant or its decomposition product and the oxidation catalyst or its decomposition products diffuse into the coating and either by reacting with components of the coating, by catalyzing or hindering reactions within the coating or by themself render, upon baking, the decorative pattern visible within the heat-stable polymer coatings wherein the heat-stable polymer composition comprising: a. a heat-stable polymer, said polymer being silicone, polysulfide, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbons, or mixtures of the above, b. a liquid carrier, c. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2): ______________________________________ (1) Metals Cobalt Bismuth Cerium Nickel Manganese Lead Iron (2) Salts Acetate Octoate Caprate Oleate Caprylate Palmintate Isodecanoate Ricinoleate Linoleate Soyate Naphthenate Stearate Nitrate Tallate. ______________________________________
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein the antioxidant composition contains a compound or mixture of compounds containing phosphorus, sulfur, boron or mixtures thereof.
Claim 4
Dependent Claim 41 words
The process of claim 1 wherein the antioxidant is phosphoric acid, its decomposable salts containing ammonia or amines, 2-ethylhexyl diphenyl phosphate, magnesium glycerophosphate, calcium glycerophosphate, iron glycerophosphate or mixtures thereof; and the heat-stable polymer composition is further comprised of a colorant.
Claim 5
Dependent Claim 12 words
The process of claim 1 wherein the heat-stable polymer is a fluorocarbon.
Claim 6
Dependent Claim 27 words
The process of claim 1 wherein the heat-stable polymer is a hydrocarbon monomer completely sbustituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms.
Claim 7
Dependent Claim 20 words
The process of claim 1 wherein the heat-stable polymer is polytetrafluoroethylene, a copolymer of tetrafluoroethylene and hexafluoropropylene or mixtures thereof.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the heat-stable polymer composition contains a colorant.
Claim 9
Dependent Claim 36 words
The process of claim 7 wherein the colorant is carbon black, a carbonaceous residue, a carbonaceous residue precursor or mixture thereof, in concentrations up to 40% based on the weight of total solids of the composition.
Claim 10
Dependent Claim 23 words
The process of claim 1 wherein the oxidation catalyst composition contains a mixture of a compound containing cerium and a compound containing cobalt.
Claim 11
Dependent Claim 25 words
The process of claim 1 wherein the oxidation catalyst is: Cobalt octoate Cerium octoate Manganese octoate Iron octoate Bismuth octoate Nickel octoate or Lead octoate.
Claim 12
Dependent Claim 25 words
The process of claim 1 wherein the heat-stable polymer composition is applied as a subsequent coat over the antioxidant composition and the oxidation catalyst composition.
Claim 13
Dependent Claim 22 words
The process of claim 1 wherein the heat-stable polymer composition is applied directly under the antioxidant composition and the oxidation catalyst composition.
Claim 14
Dependent Claim 21 words
The process of claim 1 wherein the heat-stable polymer composition is applied between the antioxidant composition and the oxidation catalyst composition.
Claim 15
Dependent Claim 33 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration of at least 25% by weight of the total solids of the composition.
Claim 16
Dependent Claim 34 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration in the range of 25% to 95% of the total solids of the composition.
Claim 17
Dependent Claim 34 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration in the range of 70% to 90% of the total solids of the composition.
Claim 18
Dependent Claim 14 words
An article bearing a decorative pattern coating produced by the process of claim 1.

References Cited (Backward Citations)

US2681324A Cited
US2866765A Cited
US2979418A Cited
US2961341A Cited
US3293203A Cited
US3473949A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-17 1981-04-18 1981-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-17 1985-04-18 1985-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-17 1989-04-18 1989-10-18 $7700.00 Window Closed / Lapsed

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