US4054705A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for decorating coatings produced by heat-stable polymer compositions
Assignee: EIDP Inc
•
Filing: 1976-04-19
•
Granted: 1977-10-18
•
Expires: 1996-04-19
Abstract
Abstract The appearance of a heat-stable polymer coating is enhanced by a process which produces a decorative pattern within a coating produced by a heat-stable polymer coating composition. The process consists of applying a heat-stable polymer composition as a subsequent coat over or directly under an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns and which diffuse into the heat-stable polymer coating composition and render the patterns visible, upon baking, within the baked coat produced by the coating composition.
Inventors
- 👤 Eustathios Vassiliou
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 04:41
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/06; C; C09; C09D; C09D5/00; C09D5/28; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24901; Y10T428/24917; Y10T428/31504; Y10T428/31533; Y10T428/31536; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31623; Y10T428/31678; Y10T428/31681; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31757
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
210 words
A process for decorating a heat-stable polymer coating on a substrate, the process consisting essentially of applying a heat-stable polymer composition which is stable at temperatures above 300° C either as a subsequent coat over or directly under or between an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns on a substrate and then baking the coating wherein the antioxidant or its decomposition product and the oxidation catalyst or its decomposition products diffuse into the coating and either by reacting with components of the coating, by catalyzing or hindering reactions within the coating or by themself render, upon baking, the decorative pattern visible within the heat-stable polymer coatings wherein the heat-stable polymer composition comprising: a. a heat-stable polymer, said polymer being silicone, polysulfide, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbons, or mixtures of the above, b. a liquid carrier, c. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2): ______________________________________
(1) Metals
Cobalt Bismuth
Cerium Nickel
Manganese Lead
Iron
(2) Salts
Acetate Octoate
Caprate Oleate
Caprylate Palmintate
Isodecanoate Ricinoleate
Linoleate Soyate
Naphthenate Stearate
Nitrate Tallate.
______________________________________
Claim 2
Dependent Claim
210 words
A process for decorating a heat-stable polymer coating on a substrate, the process consisting essentially of applying a heat-stable polymer composition which is stable at temperatures above 300° C either as a subsequent coat over or directly under or between an antioxidant composition and an oxidation catalyst composition which are both arranged in decorative patterns on a substrate and then baking the coating wherein the antioxidant or its decomposition product and the oxidation catalyst or its decomposition products diffuse into the coating and either by reacting with components of the coating, by catalyzing or hindering reactions within the coating or by themself render, upon baking, the decorative pattern visible within the heat-stable polymer coatings wherein the heat-stable polymer composition comprising: a. a heat-stable polymer, said polymer being silicone, polysulfide, polymerized parahydroxy benzoic acid, polysulfone, polyimide, polyamide, polysulfonate, polysulfonamide, fluorocarbons, or mixtures of the above, b. a liquid carrier, c. optionally a colorant; wherein the oxidation catalyst is a compound or mixture of compounds produced by reaction of a metal from list (1) with an acid to form a salt compound of list (2): ______________________________________
(1) Metals
Cobalt Bismuth
Cerium Nickel
Manganese Lead
Iron
(2) Salts
Acetate Octoate
Caprate Oleate
Caprylate Palmintate
Isodecanoate Ricinoleate
Linoleate Soyate
Naphthenate Stearate
Nitrate Tallate.
______________________________________
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the antioxidant composition contains a compound or mixture of compounds containing phosphorus, sulfur, boron or mixtures thereof.
Claim 4
Dependent Claim
41 words
The process of claim 1 wherein the antioxidant is phosphoric acid, its decomposable salts containing ammonia or amines, 2-ethylhexyl diphenyl phosphate, magnesium glycerophosphate, calcium glycerophosphate, iron glycerophosphate or mixtures thereof; and the heat-stable polymer composition is further comprised of a colorant.
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein the heat-stable polymer is a fluorocarbon.
Claim 6
Dependent Claim
27 words
The process of claim 1 wherein the heat-stable polymer is a hydrocarbon monomer completely sbustituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms.
Claim 7
Dependent Claim
20 words
The process of claim 1 wherein the heat-stable polymer is polytetrafluoroethylene, a copolymer of tetrafluoroethylene and hexafluoropropylene or mixtures thereof.
Claim 8
Dependent Claim
13 words
The process of claim 1 wherein the heat-stable polymer composition contains a colorant.
Claim 9
Dependent Claim
36 words
The process of claim 7 wherein the colorant is carbon black, a carbonaceous residue, a carbonaceous residue precursor or mixture thereof, in concentrations up to 40% based on the weight of total solids of the composition.
Claim 10
Dependent Claim
23 words
The process of claim 1 wherein the oxidation catalyst composition contains a mixture of a compound containing cerium and a compound containing cobalt.
Claim 11
Dependent Claim
25 words
The process of claim 1 wherein the oxidation catalyst is: Cobalt octoate Cerium octoate Manganese octoate Iron octoate Bismuth octoate Nickel octoate or Lead octoate.
Claim 12
Dependent Claim
25 words
The process of claim 1 wherein the heat-stable polymer composition is applied as a subsequent coat over the antioxidant composition and the oxidation catalyst composition.
Claim 13
Dependent Claim
22 words
The process of claim 1 wherein the heat-stable polymer composition is applied directly under the antioxidant composition and the oxidation catalyst composition.
Claim 14
Dependent Claim
21 words
The process of claim 1 wherein the heat-stable polymer composition is applied between the antioxidant composition and the oxidation catalyst composition.
Claim 15
Dependent Claim
33 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration of at least 25% by weight of the total solids of the composition.
Claim 16
Dependent Claim
34 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration in the range of 25% to 95% of the total solids of the composition.
Claim 17
Dependent Claim
34 words
The process of claim 1 in which the heat-stable polymer is present in the heat-stable polymer composition at a concentration in the range of 70% to 90% of the total solids of the composition.
Claim 18
Dependent Claim
14 words
An article bearing a decorative pattern coating produced by the process of claim 1.
References Cited (Backward Citations)
US2681324A
Cited
US2866765A
Cited
US2979418A
Cited
US2961341A
Cited
US3293203A
Cited
US3473949A
Cited
US3489595A
Cited
US3493418A
Cited
US3692558A
Cited
US3577257A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-17 | 1981-04-18 | 1981-10-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-17 | 1985-04-18 | 1985-10-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-17 | 1989-04-18 | 1989-10-18 | $7700.00 | Window Closed / Lapsed |