US4054542A
Expired / Lapsed
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Amine-epichlorohydrin polymeric compositions
Assignee: Buckman Laboratories International Inc
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Filing: 1976-03-10
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Granted: 1977-10-18
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Expires: 1996-03-10
Abstract
Abstract Cationic, water-soluble, amine-epichlorohydrin polymeric compositions formed by reacting polymeric bis(3-chloro-2-hydroxypropyl) amines with tertiary amines are useful in papermaking processes, in water purification processes, textile manufacturing processes, and for the control of pests such as algae, bacteria and fungi.
Inventors
- 👤 John D. Buckman
- 👤 Stanley J. Buckman
- 👤 Gerald D. Mercer
- 👤 John D. Pera
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 08:16
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/02; C08G73/0206; C08G73/0213; C08G73/0226; A; A01; A01N; A01N33/00; A01N33/02; A01N33/12; C02; C02F; C02F1/00; C02F1/50; C02F1/52; C02F1/54; D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/55; D06M16/00; D21; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/46; D21H17/54; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
256 words
A cationic, water-soluble, amine-epichlorohydrin polymer prepared using a two-stage reaction process wherein about one mole of ammonia is reacted with about three moles of epichlorohydrin or about one mole of a primary amine having the formula RNH 2 is reacted with about two moles of epichlorohydrin in the presence of a polar solvent comprising an alkyl alcohol containing from 1 to 3 carbon atoms and water, thus forming a polymeric precursor and subsequently reacting said precursor with a tertiary amine having the formula: ##STR6## wherein R represents a straight or branched chain alkyl group containing 1 to 20 carbon atoms and 0 to 2 carbon to carbon double bonds, a straight or branched chain alkyl group containing 1 to 6 carbon atoms and one or more hydroxyl or chloro substituents, a saturated aryl group or a benzyl group; and wherein each of the R' groups independently represents a straight or branched chain alkyl group containing 1 to 20 carbon atoms and 0 to 2 carbon to carbon double bonds, a straight or branched chain alkyl group containing 1 to 6 carbon atoms and one or more hydroxyl or chloro substituents, a saturated aryl group, or a benzyl group; R" represents a straight chain alkyl group containing 1 to 6 carbon atoms; X represents a polymethylene group containing 1 to 12 carbon atoms, ##STR7## -- CH 2 -- CH 2 -- O -- CH 2 -- CH 2 --; or -- CH 2 -- CH═CH -- CH 2 ; and salts of polymers, having tertiary amine groups.
Claim 2
Dependent Claim
256 words
A cationic, water-soluble, amine-epichlorohydrin polymer prepared using a two-stage reaction process wherein about one mole of ammonia is reacted with about three moles of epichlorohydrin or about one mole of a primary amine having the formula RNH 2 is reacted with about two moles of epichlorohydrin in the presence of a polar solvent comprising an alkyl alcohol containing from 1 to 3 carbon atoms and water, thus forming a polymeric precursor and subsequently reacting said precursor with a tertiary amine having the formula: ##STR6## wherein R represents a straight or branched chain alkyl group containing 1 to 20 carbon atoms and 0 to 2 carbon to carbon double bonds, a straight or branched chain alkyl group containing 1 to 6 carbon atoms and one or more hydroxyl or chloro substituents, a saturated aryl group or a benzyl group; and wherein each of the R' groups independently represents a straight or branched chain alkyl group containing 1 to 20 carbon atoms and 0 to 2 carbon to carbon double bonds, a straight or branched chain alkyl group containing 1 to 6 carbon atoms and one or more hydroxyl or chloro substituents, a saturated aryl group, or a benzyl group; R" represents a straight chain alkyl group containing 1 to 6 carbon atoms; X represents a polymethylene group containing 1 to 12 carbon atoms, ##STR7## -- CH 2 -- CH 2 -- O -- CH 2 -- CH 2 --; or -- CH 2 -- CH═CH -- CH 2 ; and salts of polymers, having tertiary amine groups.
Claim 3
Dependent Claim
22 words
The product according to claim 1 wherein R is a straight or branched chain alkyl group containing 1 to 20 carbon atoms.
Claim 4
Dependent Claim
30 words
The product according to claim 1 wherein R is a straight or branched chain alkyl group containing 1 to 6 carbon atoms and one or more hydroxyl or chloro substituents.
Claim 5
Dependent Claim
12 words
The product according to claim 1 wherein the primary amine is monomethylamine.
Claim 6
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is ethyl amine.
Claim 7
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is n-propyl amine.
Claim 8
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is iso-propyl amine.
Claim 9
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is n-butyl amine.
Claim 10
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is t-butyl amine.
Claim 11
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is 3-chloro-2-hydroxypropyl amine.
Claim 12
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is stearyl amine.
Claim 13
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is benzyl amine.
Claim 14
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is cyclohexyl amine.
Claim 15
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is 3-hydroxy-2-methylpropyl amine.
Claim 16
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is tris(hydroxymethyl)methyl amine.
Claim 17
Dependent Claim
13 words
The product according to claim 1 wherein the primary amine is 2-hydroxyethyl amine.
Claim 18
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'-tetramethyl-1,2-diaminoethane.
Claim 19
Dependent Claim
14 words
The product according to claim 1 wherein the tertiary amine is bis (beta-dimethylaminoethyl) ether.
Claim 20
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'-tetramethyl-1,3-diaminobutane.
Claim 21
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'-tetramethyl-1,4-diaminobutane.
Claim 22
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'-tetramethyl-1,6-diaminohexane.
Claim 23
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'tetramethylmethylenediamine.
Claim 24
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is 1,3-bis(dimethylamino)-2-propanol.
Claim 25
Dependent Claim
12 words
The product according to claim 1 wherein the tertiary amine is N,N,N',N'-tetramethyl-1,3-diaminopropane.
Claim 26
Dependent Claim
18 words
The product according to claim 1 wherein the primary amine is methylamine and the tertiary amine is ##STR8##
Claim 27
Dependent Claim
18 words
The product according to claim 1 wherein the primary amine is methylamine and the tertiary amine is ##STR9##
Claim 28
Dependent Claim
21 words
The product according to claim 1 wherein the primary amine is a C 16 alkylamine and the tertiary amine is ##STR10##
Claim 29
Dependent Claim
21 words
The product accordig to claim 1 wherein the primary amine is a C 16 alkylamine and the tertiary amine is ##STR11##
Claim 30
Dependent Claim
21 words
The product according to claim 1 wherein the primary amine is a C 18 alkylamine and the tertiary amine is ##STR12##
Claim 31
Dependent Claim
21 words
The product according to claim 1 wherein the primary amine is a C 18 alkylamine and the tertiary amine is ##STR13##
Claim 32
Dependent Claim
21 words
The product according to claim 1 wherein the primary amine is a C 18 oleylamine and the tertiary amine is ##STR14##
Claim 33
Dependent Claim
21 words
The product according to claim 1 wherein the primary amine is a C 18 oleylamine and the tertiary amine is ##STR15##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-17 | 1981-04-18 | 1981-10-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-17 | 1985-04-18 | 1985-10-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-17 | 1989-04-18 | 1989-10-18 | $7700.00 | Window Closed / Lapsed |