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US4054495A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrodeposition of nickel

Assignee: MANGRA Ltd 24 WADSWORTH ROAD PERIVALE MIDDLESEX UR6 7JD
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Filing: 1976-03-05
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Granted: 1977-10-18
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Expires: 1996-03-05
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Abstract

Abstract The invention relates to aqueous solutions for bright and semi-bright nickel electroplating. The bath contains known ingredients such as nickel salts, boric acid ions together with three acetylenic compounds viz acetylenic alcohol, separated mono and/or di-alkoxylated derivative of acetylenic alcohol produced by reaction of acetylenic alcohol with ethylene oxide, propylene oxide or butylene oxide and N-di-substituted amino-propyne or its hydrochloride.

Inventors

  • 👤 Malcolm John Law
  • 👤 Peter James Hutchinson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 23:48
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/12; C25D3/14; C25D3/16

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 75 words
An acidic aqueous solution for nickel electroplating comprising nickel sulphate, chloride and/or bromide, boric acid, at least 0.005 gms/liter of acetylene alcohol, at least 0.005 gms/liter of separated mono and/or di-alkoxylated derivative of an acetylenic alcohol produced by reaction of acetylenic alcohol with ethylene oxide, propylene oxide or butylene oxide, and at least 0.0005 gms/liter of N-di-substituted amino-propyne or its hydrochloride derivative, the total concentration of acetylenic materials being 0.01 to 0.5 grams per liter.
Claim 2
Dependent Claim 75 words
An acidic aqueous solution for nickel electroplating comprising nickel sulphate, chloride and/or bromide, boric acid, at least 0.005 gms/liter of acetylene alcohol, at least 0.005 gms/liter of separated mono and/or di-alkoxylated derivative of an acetylenic alcohol produced by reaction of acetylenic alcohol with ethylene oxide, propylene oxide or butylene oxide, and at least 0.0005 gms/liter of N-di-substituted amino-propyne or its hydrochloride derivative, the total concentration of acetylenic materials being 0.01 to 0.5 grams per liter.
Claim 3
Dependent Claim 22 words
A solution as claimed in claim 1 wherein the alcohol is butyne 1:4 diol, butyne 1-3 ol, propargyl alcohol or methyl pentynol.
Claim 4
Dependent Claim 21 words
A solution as claimed in claim 1 in which the separated derivative is mono-or di-ethoxylated butyne diol or ethoxylated propargyl alcohol.
Claim 5
Dependent Claim 39 words
A solution as claimed in claim 1 which includes naphthalene tri sulphonic acid up to 5 grams/liter or saccharin 0.5 to 5.0 grams/liter, and sodium allyl sulphonate up to 4 grams/liter or sodium vinyl sulphonate up to 4 grams/liter.

References Cited (Backward Citations)

US3546081A Cited
US3804727A Cited
US3711384A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-17 1981-04-18 1981-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-17 1985-04-18 1985-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-17 1989-04-18 1989-10-18 $7700.00 Window Closed / Lapsed

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