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US4054493A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for converting saline water to fresh water

Assignee: Individual
•
Filing: 1976-07-01
•
Granted: 1977-10-18
•
Expires: 1996-07-01
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Abstract

Abstract Preheated saline water, typically sea or brackish water, is further heated by quanta of steam, passed to it at differential temperatures and pressures and condensed in the saline water. Scale compounds are precipitated and scale-forming bicarbonates decomposed, with the evolution of carbon dioxide, which is gathered and expelled by steam accessory to the quanta of steam. Post-thermal saline water, which is formed, is multistage flash vaporized while self-cooling. The flashed vapors are compressed to form said quanta of steam. After being further cooled while preheating saline water, post-thermal saline water is evaporated in a multistage vapor compression evaporator, producing brine at a high concentration factor. Relative to equilibrium in scale-compound precipitation between 302° F and 347° F, the recovery of fresh water is 70% to 80% for sea water, and 80% to 90% for brackish waters over a wide range of salinity.

Inventors

  • 👤 Paul S. Roller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:55
CPC Classifications
B; B01; B01D; B01D3/00; B01D3/06; B01D3/065; B01D1/00; B01D1/28; B01D1/284; B01D1/285; C; C02; C02F; C02F1/00; C02F1/02; C02F1/04; C02F1/042; Y; Y10; Y10S; Y10S159/00; Y10S159/08; Y10S159/13; Y10S203/00; Y10S203/11

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 155 words
A process for the conversion of saline water containing scale-forming compounds to fresh water, which comprises indirectly preheating the saline water; to the preheated saline water, passing quanta of steam which are sequentially increasing temperatures and pressures and condensing the quanta of steam in the saline water at points which are at corresponding lesser temperatures and pressures, thereby further heating the preheated saline water; as a result of the further heating, precipitating scale compounds in the saline water and decomposing scale-forming bicarbonates with the evolution of carbon dioxide; separating the precipitated scale compounds and carbon dioxide, forming post-thermal saline water; flash vaporizing the post-thermal saline water in stages of decreasing temperature and forming cooled, post-thermal saline water; compressing the flashed vapors of each said stage and passing the compressed vapors to the preheated saline water as said quanta of steam; and evaporating said cooled, post-thermal saline water to produce fresh water and saline water residuum.
Claim 2
Dependent Claim 155 words
A process for the conversion of saline water containing scale-forming compounds to fresh water, which comprises indirectly preheating the saline water; to the preheated saline water, passing quanta of steam which are sequentially increasing temperatures and pressures and condensing the quanta of steam in the saline water at points which are at corresponding lesser temperatures and pressures, thereby further heating the preheated saline water; as a result of the further heating, precipitating scale compounds in the saline water and decomposing scale-forming bicarbonates with the evolution of carbon dioxide; separating the precipitated scale compounds and carbon dioxide, forming post-thermal saline water; flash vaporizing the post-thermal saline water in stages of decreasing temperature and forming cooled, post-thermal saline water; compressing the flashed vapors of each said stage and passing the compressed vapors to the preheated saline water as said quanta of steam; and evaporating said cooled, post-thermal saline water to produce fresh water and saline water residuum.
Claim 3
Dependent Claim 16 words
Claim 1, wherein accessory steam in part indirectly preheats saline water before said further heating thereof.
Claim 4
Dependent Claim 40 words
Claim 1, wherein solids, selected from among said precipitate of scale compounds, anhydrite and magnesium hydroxide, are added as seed to the further heating saline water, whereby the precipitation of scale compounds and the decomposition of scale-forming bicarbonates are hastened.
Claim 5
Dependent Claim 25 words
Claim 1, wherein accessory steam is passed through the further heating saline water and excess steam including carbon dioxide is separated from the saline water.
Claim 6
Dependent Claim 20 words
Claim 4, wherein separated, excess steam indirectly preheats saline water, forming hot condensate, and carbon dioxide issues from hot condensate.
Claim 7
Dependent Claim 25 words
Claim 5, wherein a part of the carbon dioxide that issues is passed to saline water, whereby in the preheating thereof alkaline scale is prevented.
Claim 8
Dependent Claim 29 words
Claim 1, wherein cooled, post-thermal saline water is further cooled while indirectly preheating saline water; and the further cooled, post-thermal saline water is evaporated in a vapor compression evaporator.
Claim 9
Dependent Claim 84 words
Claim 7, wherein said vapor compression evaporator is in multistage, each stage comprising an evaporation chamber and a connected vapor compressor; compressed vapor indirectly heats saline water in each said chamber, forming condensate therein and saline water concentrate, the latter passing sequentially through chambers of increasing saline water concentration, and finally issuing as evaporator concentrate; and the condensers of each stage are collected to form issuing evaporator condensate; and evaporator condensate and concentrate are cooled to produce fresh water and saline water residuum respectively.
Claim 10
Dependent Claim 21 words
Claim 8, wherein water is combined with each said compressed vapor, whereby to desupersaturate it before it indirectly heats saline water.
Claim 11
Dependent Claim 59 words
Claim 8, wherein solids, selected from among anhydrite and a precipitate of scale compounds formed according to claim 1, are added as seed to the saline water present in a stage of high saline water concentration, whereby to effect body precipitation on said solids by the anhydrite which may precipitate from solution upon further evaporation of the saline water.
Claim 12
Dependent Claim 31 words
Claim 8, wherein acid is added to the saline water in a stage of high saline water concentration, whereby to prevent the hydrolytic precipitation of magnesium hydroxide from the saline water.
Claim 13
Dependent Claim 58 words
Claim 8, wherein solids, selected from among magnesium hydroxide and a precipitate formed by adding lime to a solution containing magnesium ion, is added to the saline water in a stage of high saline water concentration, whereby to effect body precipitation on said solids of magnesium hydroxide which may hydrolytically precipitate from the saline water upon further evaporation.
Claim 14
Dependent Claim 127 words
A process for the conversion of saline water containing scale-forminng compounds to fresh water, which comprises indirectly preheating the saline water; to the preheated saline water, passing quanta of steam which are at sequentially increasing temperatures and pressures and condensing the quanta of steam in the saline water at points which are at correspondingly lesser temperatures and pressures, thereby further heating the preheated saline water; as a result of the further heating, precipitating scale compounds in the saline water and decomposing scale-forming bicarbonates with the evolution of carbon dioxide; separating the precipitated scale compounds and carbon dioxide, forming post-thermal saline water; flash vaporizing the post-thermal saline water and forming cooled, post-thermal saline water; and evaporating cooled, post-thermal saline water to form fresh water and saline water residuum.
Claim 15
Dependent Claim 127 words
A process for the conversion of saline water containing scale-forminng compounds to fresh water, which comprises indirectly preheating the saline water; to the preheated saline water, passing quanta of steam which are at sequentially increasing temperatures and pressures and condensing the quanta of steam in the saline water at points which are at correspondingly lesser temperatures and pressures, thereby further heating the preheated saline water; as a result of the further heating, precipitating scale compounds in the saline water and decomposing scale-forming bicarbonates with the evolution of carbon dioxide; separating the precipitated scale compounds and carbon dioxide, forming post-thermal saline water; flash vaporizing the post-thermal saline water and forming cooled, post-thermal saline water; and evaporating cooled, post-thermal saline water to form fresh water and saline water residuum.
Claim 16
Dependent Claim 28 words
Claim 13, wherein the post-thermal saline water is flash vaporized in stages of decreasing temperature and the flashed vapors are recovered and employed to form quanta of steam.
Claim 17
Dependent Claim 15 words
Claim 14, wherein the recovered flashed vapors are compressed to form said quanta of steam.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-17 1981-04-18 1981-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-17 1985-04-18 1985-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-17 1989-04-18 1989-10-18 $7700.00 Window Closed / Lapsed

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