US4052368A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Water-dispellable hot melt polyester adhesives
Assignee: 3M Co
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Filing: 1976-06-21
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Granted: 1977-10-04
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Expires: 1996-06-21
Abstract
Abstract Water-dispellable, optionally pressure-sensitive hot melt resins having superior heat-aging properties are made by reacting (1) diols, of which at least 90% are polycaprolactonediol and/or monoalkylene diols, with (2) dicarboxylic acids, of which up to 95% are aliphatic, 5-25% are aromatic and have a magnesium or alkali metal sulfonate group attached to the ring, and the balance are non-sulfonated aromatic. These resins, which find use as hot melt adhesives for book binding and other purposes, can be readily dissolved or dispersed in a paper beater during a repulping operation. The product can be wound upon itself and supplied in roll form, optionally reinforced by a fibrous membrane.
Inventors
- 👤 Wayne K. Larson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:56
CPC Classifications
C; C09; C09J; C09J167/00; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C09J7/00; C09J7/10; C09J7/30; C09J7/38; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/3179
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
198 words
A water-dispellable strong hot melt adhesive, resistant to degradation upon continued exposure to high temperatures and functional at high humidities, consisting essentially of a polyester resin which is normally solid at 20° C., has a ball-and-ring softening point greater than 35° C., fuses at a temperature between 35° C. and 200° C., has an intrinsic viscosity in the range of 0.1 - 1.0 and contains substantially equimolar amounts of the residue of a. 100 mole percent dicarboxylic acid molecules consisting essentially of 1. 0-95 mole percent aliphatic dicarboxylic acid having at least two carbon atoms between carboxyl groups and having an average of 4-10 carbon atoms, 2. 0-95 mole percent aromatic dicarboxylic acid, no more than 85 mole percent being terephthalic acid, and 3. 5-25 mole percent aromatic dicarboxylic acid in which magnesium sulfonate or an alkali metal sulfonate is attached to an aromatic ring; and b. 100 mole percent diol molecules consisting essentially of 1. 0-100 mole percent of a monoalkylene glycol containing 2 to 10 carbon atoms, 2. 0-100 mole percent polycaprolactonediol, and 3. 0-10 mole percent polyoxyalkylene glycol, the sum of the mole percentages of monoalkylene glycol residues and polycaprolactonediol residues being at least 90.
Claim 2
Dependent Claim
198 words
A water-dispellable strong hot melt adhesive, resistant to degradation upon continued exposure to high temperatures and functional at high humidities, consisting essentially of a polyester resin which is normally solid at 20° C., has a ball-and-ring softening point greater than 35° C., fuses at a temperature between 35° C. and 200° C., has an intrinsic viscosity in the range of 0.1 - 1.0 and contains substantially equimolar amounts of the residue of a. 100 mole percent dicarboxylic acid molecules consisting essentially of 1. 0-95 mole percent aliphatic dicarboxylic acid having at least two carbon atoms between carboxyl groups and having an average of 4-10 carbon atoms, 2. 0-95 mole percent aromatic dicarboxylic acid, no more than 85 mole percent being terephthalic acid, and 3. 5-25 mole percent aromatic dicarboxylic acid in which magnesium sulfonate or an alkali metal sulfonate is attached to an aromatic ring; and b. 100 mole percent diol molecules consisting essentially of 1. 0-100 mole percent of a monoalkylene glycol containing 2 to 10 carbon atoms, 2. 0-100 mole percent polycaprolactonediol, and 3. 0-10 mole percent polyoxyalkylene glycol, the sum of the mole percentages of monoalkylene glycol residues and polycaprolactonediol residues being at least 90.
Claim 3
Dependent Claim
14 words
The hot melt adhesive of claim 1 wherein said monoalkylene glycol comprises ethylene glycol.
Claim 4
Dependent Claim
21 words
The hot melt adhesive of claim 1 wherein at least about 95 mole percent of the diol molecules are ethylene glycol.
Claim 5
Dependent Claim
17 words
The hot melt adhesive of claim 1 wherein the aliphatic dicarboxylic acid consists essentially of adipic acid.
Claim 6
Dependent Claim
24 words
The hot melt adhesive of claim 1 wherein the aromatic dicarboxylic acid having a sulfonate attached to the aromatic ring is sodium sulfoisophthalic acid.
Claim 7
Dependent Claim
32 words
The hot melt adhesive of claim 3 wherein the dicarboxylic acid molecules consist essentially of 40-75 mole percent adipic acid, 5-10 mole percent sodium sulfoisophthalic acid, and 5-55 mole percent terephthalic acid.
Claim 8
Dependent Claim
14 words
A sheet material consisting essentially of a layer of the adhesive of claim 1.
Claim 9
Dependent Claim
14 words
The sheet material of claim 7 wherein the adhesive layer is a self-supporting film.
Claim 10
Dependent Claim
15 words
The sheet material of claim 7 wherein the adhesive layer is reinforced by a membrane.
Claim 11
Dependent Claim
13 words
The sheet material of claim 9 wherein the membrane is fibrous and water-disintegrable.
Claim 12
Dependent Claim
16 words
The sheet material of claim 7 wherein the adhesive layer is coated on water-insoluble sheet material.
Claim 13
Dependent Claim
16 words
The sheet material of claim 7 in which the adhesive layer is normally tacky and pressure-sensitive.
Claim 14
Dependent Claim
12 words
The sheet material of claim 12 wound upon itself in roll form.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-03 | 1981-04-04 | 1981-10-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-03 | 1985-04-04 | 1985-10-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-03 | 1989-04-04 | 1989-10-04 | $7700.00 | Window Closed / Lapsed |