Light-sensitive photographic material

Claim 2

Light-sensitive photographic material having at least one silver halide emulsion layer containing a thioether compound which on reaction with the oxidation product of a color developer substance containing primary aromatic amino groups releases a diffusible mercaptan which inhibits development of the silver halide, wherein the improvement comprises the thioether compound is an oxazolinone-2 compound of the following formula or its tautomeric form: ##STR9## in which X represents an alkyl group with 1 to 10 carbon atoms, which may be substituted by carboxyl and/or amino groups, a phenyl group or a 5- or 6-membered heteroaromatic group having at least one nitrogen atom, R represents an alkyl group having from 1 to 18 carbon atoms which may be straight or branched chain or cyclic, and may be substituted by alkoxy, aroxy, aryl, halogen, carboxy or sulpho group, or phenyl or naphthyl groups which may be substituted by one or more substituents selected from the group consisting of alkyl, alkoxy, alkylamino or alkylthio groups, in any of which groups the alkyl portion may contain from 1 to 20 carbon atoms; nitro groups; halogen; carboxyl or sulpho groups; acyl or acylamino groups in either of which the acyl portion may be derived from carboxylic or sulphonic acids such as heptadecyl carbonamido; dimethylaminosulphonylphenyl; octadecylaminosulphonyl; methyloctadecylaminocarbonyl; phenylaminocarbonyl; benzoylaminophenoxycarbonyl or ethoxycarbonyl; or a 5- or 6-membered heterocyclic group having at least one nitrogen atom whereby a mercapto group is splittable from the 5-position of the oxazolinone-2 compound.

Claim 3

Photographic material according to claim 1, wherein the group in its 4-position is an alkyl group having from 3 to 18 carbon atoms and the carbon atom which is linked to the 4-position of the oxazolinone-2 ring is a branched carbon atom.

Claim 4

Photographic material according to claim 1, wherein R is attached to the 4-position of the oxazolinone-2 ring via a saturated or aromatic carbon atom of the aliphatic, aromatic or heterocyclic group.

Claim 5

Photographic material according to claim 1, wherein X is a 1-phenyl tetrazolyl group.

Claim 6

Material according to claim 1, wherein the photographic material is a multilayered color photographic material and contains a thioether compound in at least one silver halide emulsion layer or in a light-insensitive layer of binder associated with it.

Claim 7

Process for the development of an imagewise exposed light-sensitive photographic material containing at least one silver halide emulsion layer including in an element of the material or in a processing bath a thioether compound which on reaction with the oxidation product of a color developer substance containing primary aromatic amino groups releases a diffusible mercaptan which inhibits development of the silver halide, the improvement according to which the thioether compound is an oxazolinone-2 compound from which a mercapto group can be split off from its 5-position said thioether compound is of the following formula or its tautomeric form: ##STR10## in which X represents an alkyl group with 1 to 10 carbon atoms, which may be substituted by carboxyl and/or amino groups, a phenyl or a 5- or 6-membered heteroaromatic group having at least one nitrogen atom, R represents an alkyl group having from 1 to 18 carbon atoms which may be straight or branched chain or cyclic, and may be substituted by alkoxy, aroxy, aryl, halogen, carboxy or sulpho group, or phenyl or naphthyl groups which may be substituted by one or more substituents selected from the group consisting of alkyl, alkoxy, alkylamino or alkylthio groups, in any of which groups the alkyl portion may contain from 1 to 20 carbon atoms; nitro groups; halogen; carboxyl or sulpho groups; acyl or acylamino groups in either of which the acyl portion may be derived from carboxylic or sulphonic acids such as heptadecyl carbon amido; dimethylaminosulphonylphenyl; octadecylaminosulphonyl; methyloctadecylaminocarbonyl; phenylaminocarbonyl; benzoylaminophenoxycarbonyl or ethoxycarbonyl; or a 5- or 6- membered heterocyclic group having at least one nitrogen atom.

Claim 8

Process for the development of an imagewise exposed light-sensitive photographic material containing at least one silver halide emulsion layer including in an element of the material or in a processing bath a thioether compound which on reaction with the oxidation product of a color developer substance containing primary aromatic amino groups releases a diffusible mercaptan which inhibits development of the silver halide, the improvement according to which the thioether compound is an oxazolinone-2 compound from which a mercapto group can be split off from its 5-position said thioether compound is of the following formula or its tautomeric form: ##STR10## in which X represents an alkyl group with 1 to 10 carbon atoms, which may be substituted by carboxyl and/or amino groups, a phenyl or a 5- or 6-membered heteroaromatic group having at least one nitrogen atom, R represents an alkyl group having from 1 to 18 carbon atoms which may be straight or branched chain or cyclic, and may be substituted by alkoxy, aroxy, aryl, halogen, carboxy or sulpho group, or phenyl or naphthyl groups which may be substituted by one or more substituents selected from the group consisting of alkyl, alkoxy, alkylamino or alkylthio groups, in any of which groups the alkyl portion may contain from 1 to 20 carbon atoms; nitro groups; halogen; carboxyl or sulpho groups; acyl or acylamino groups in either of which the acyl portion may be derived from carboxylic or sulphonic acids such as heptadecyl carbon amido; dimethylaminosulphonylphenyl; octadecylaminosulphonyl; methyloctadecylaminocarbonyl; phenylaminocarbonyl; benzoylaminophenoxycarbonyl or ethoxycarbonyl; or a 5- or 6- membered heterocyclic group having at least one nitrogen atom.

Claim 9

Process according to claim 6 wherein the oxazolinone-2 compound is added to the developer or to a processing bath used before development.