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US4051226A Expired / Lapsed US ⏱️ 0.0 years remaining

Prevention of explosive mixtures in the regeneration of sulfur oxide acceptors

Assignee: Shell USA Inc
•
Filing: 1976-05-12
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Granted: 1977-09-27
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Expires: 1996-05-12
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Abstract

Abstract Prevention of the formation of explosive mixtures by hydrogen leaking through valves into ducts normally containing quiescent flue gas containing oxygen is accomplished by maintaining a continuous flow of the flue gas sufficient to dilute the hydrogen.

Inventors

  • 👤 Gernot Staudinger
  • 👤 Jaap E. Naber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:12
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C01B17/60; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/508; Y; Y10; Y10S; Y10S502/00; Y10S502/515; Y10S502/517

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 276 words
In a process wherein (A) a flue gas containing sulfur dioxide and oxygen is passed through a first inlet duct and open valve communicating therewith to a first reactor containing a copper-containing acceptor on a refractory carrier at a temperature of between 200° and 600° C, to remove sulfur dioxide from the flue gas, and then the purified flue gas is passed from the first reactor through an open valve communicating with a first outlet duct, and (B) wherein the valves communicating with the first inlet duct and the first outlet duct of said first reactor are closed, and the flue gas containing the sulfur dioxide and oxygen is then passed through another first inlet duct and open valve communicating therewith to a second reactor containing a copper-containing acceptor on a refractory carrier at a temperature between 200° and 600° C, to remove sulfur dioxide from the flue gas, and then the purified flue gas is passed from the second reactor through an open valve communicating with another first outlet duct, while, (C) concomitantly passing a hydrogen-containing gas through a second inlet duct and open valve communicating therewith to said first reactor at a temperature between 200° and 600° C to regenerate the acceptor and then passing the hydrogen-containing gas from said first reactor through an open valve-communicating with a second outlet duct, the improvement comprising, preventing hydrogen build-up from valve leakage into the first inlet duct of the first reactor during step (C) by passing a quantity of flue gas sufficient to prevent hydrogen build-up through the first inlet duct of the first reactor and then to the first inlet duct of the second reactor.
Claim 2
Dependent Claim 276 words
In a process wherein (A) a flue gas containing sulfur dioxide and oxygen is passed through a first inlet duct and open valve communicating therewith to a first reactor containing a copper-containing acceptor on a refractory carrier at a temperature of between 200° and 600° C, to remove sulfur dioxide from the flue gas, and then the purified flue gas is passed from the first reactor through an open valve communicating with a first outlet duct, and (B) wherein the valves communicating with the first inlet duct and the first outlet duct of said first reactor are closed, and the flue gas containing the sulfur dioxide and oxygen is then passed through another first inlet duct and open valve communicating therewith to a second reactor containing a copper-containing acceptor on a refractory carrier at a temperature between 200° and 600° C, to remove sulfur dioxide from the flue gas, and then the purified flue gas is passed from the second reactor through an open valve communicating with another first outlet duct, while, (C) concomitantly passing a hydrogen-containing gas through a second inlet duct and open valve communicating therewith to said first reactor at a temperature between 200° and 600° C to regenerate the acceptor and then passing the hydrogen-containing gas from said first reactor through an open valve-communicating with a second outlet duct, the improvement comprising, preventing hydrogen build-up from valve leakage into the first inlet duct of the first reactor during step (C) by passing a quantity of flue gas sufficient to prevent hydrogen build-up through the first inlet duct of the first reactor and then to the first inlet duct of the second reactor.
Claim 3
Dependent Claim 47 words
The method of claim 1 wherein hydrogen build-up from valve leakage into the first outlet duct of the first reactor during step (C) is prevented by passing flue gas from the first outlet duct of the second reactor through the first outlet duct of the first reactor.
Claim 4
Dependent Claim 61 words
The method of claim 1 wherein, during step (A), the valves communicating with the first inlet duct and the first outlet duct of the second reactor are closed, and hydrogen-containing gas is passed through the second inlet duct of said second reactor and through the second reactor at a temperature of between 200° and 600° C, to regenerate therefor the acceptor.
Claim 5
Dependent Claim 47 words
The method of claim 3 wherein hydrogen build-up from valve leakage into the first outlet duct of the first reactor during step (C) is prevented by passing flue gas from the first outlet duct of the second reactor through the first outlet duct of the first reactor.

References Cited (Backward Citations)

GB1089716A Cited
US3832445A Cited
US3501897A Cited
US3781407A Cited
US3899099A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-26 1981-03-28 1981-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-26 1985-03-28 1985-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-26 1989-03-28 1989-09-27 $7700.00 Window Closed / Lapsed

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