Separation of bi-alkyl substituted monocyclic aromatic isomers

Claim 2

A process for separating the para-isomer from a feed stream comprising at least two bi-alkyl monosubstituted aromatic isomers, including the para-isomer, said isomers having more than eight and less than about eighteen carbon atoms per molecule which process employs an adsorbent comprising a X or a Y zeolite containing at exchangeable cationic sites a cation pair selected from the group consisting of barium and potassium, potassium and beryllium, potassium and magnesium, rubidium and barium, cesium and barium, potassium and rubidium and potassium and cesium and which process comprises the steps of: a. maintaining net fluid flow through a column of said adsorbent in a single direction, which column contains at least three zones having separate operational functions occurring therein and being serially interconnected with terminal zones of said column connected to provide a continuous connection of said zones; b. maintaining an adsorption zone in said column, said zone defined by the adsorbent located between a feed input stream at an upstream boundary of said zone and a raffinate output stream at a downstream boundary of said zone; c. maintaining a purification zone immediately upstream from said adsorption zone, said purification zone defined by the adsorbent located between an extract output stream at an upstream boundary of said purification zone and said feed input stream at a downstream boundary of said purification zone; d. maintaining a desorption zone immediately upstream from said purification zone, said desorption zone defined by the adsorbent located between a desorbent input stream at an upstream boundary of said zone and said extract output stream at a downstream boundary of said zone; e. passing said feed stream into said adsorption zone at adsorption conditions to effect the selective adsorption of said para-isomer by said adsorbent in said adsorption zone and withdrawing a raffinate output stream from said adsorption zone; f. passing a desorbent material into said desorption zone at desorption conditions to effect the displacement of said para-isomer from the adsorbent in said desorption zone; g. withdrawing an extract stream comprising said para-isomer and desorbent material from said desorption zone; h. passing at least a portion of said extract output stream to a separation means and therein separating at separation conditions at least a portion of said desorbent material to produce a para-isomer product; and i. periodically advancing through said column of adsorbent in a downstream direction with respect to fluid flow in said adsorption zone the feed input stream, raffinate output stream, desorbent input stream, and extract output stream to effect the shifting of zones through said adsorbent and the production of extract output and raffinate output streams.

Claim 3

The process as described in claim 1 wherein said para-isomer is para-diethylbenzene and said feed mixture comprises para-diethylbenzene and at least one other diethylbenzene isomer.

Claim 4

The process as described in claim 1 wherein said para-isomer is para-cymene and said feed mixture comprises para-cymene and at least one other cymene isomer.

Claim 5

The process as described in claim 1 wherein said zeolite is a X zeolite.

Claim 6

The process as described in claim 1 wherein said zeolite is essentially completely exchanged with said cation pair.

Claim 7

The process as described in claim 1 wherein said cation pair is potassium and barium.

Claim 8

The process as described in claim 1 wherein said desorbent material comprises toluene.

Claim 9

The process of claim 1 wherein said raffinate output stream contains desorbent material.

Claim 10

The process as described in claim 8 wherein it includes the step of passing at least a portion of said raffinate output stream to a separation means and therein separating at separation conditions at least a portion of said desorbent material to produce a raffinate product.

Claim 11

The process of claim 1 further characterized in that it includes the step of maintaining a buffer zone immediately upstream from said desorption zone, said buffer zone defined as the adsorbent located between the desorbent input stream at a downstream boundary of said buffer zone and a raffinate output stream at an upstream boundary of said buffer zone.

Claim 12

The process of claim 1 further characterized in that said adsorption conditions and desorption conditions include a temperature within the range of from about 20° to about 250° C. and a pressure within the range of from about atmospheric to about 500 psig to insure liquid phase.

Claim 13

A process for separating the para-isomer from a feed stream comprising at least two bi-alkyl monosubstituted aromatic isomers, including the para-isomer, said isomers having more than eight and less than about eighteen carbon atoms per molecule which process employs an adsorbent comprising a X zeolite containing barium and potassium at exchangeable cationic sites and which process comprises the steps of: a. maintaining net fluid flow through a column of said adsorbent in a single direction, which column contains at least four zones having separate operational functions occurring therein and being serially interconnected with the terminal zones of said column connected to provide a continuous connection of said zones; b. maintaining an adsorption zone in said column, said zone defined by the adsorbent located between a feed input stream at an upstream boundary of said zone and a raffinate output stream at a downstream boundary of said zone; c. maintaining a purification zone immediately upstream from said adsorption zone, said purification zone defined by the adsorbent located between an extract output stream at an upstream boundary of said purification zone and said feed input stream at a downstream boundary of said purification zone; d. maintaining a desorption zone immediately upstream from said purification zone, said desorption zone defined by the adsorbent located between a desorbent input stream at an upstream boundary of said zone and said extract output stream at a downstream boundary of said zone; e. maintaining a buffer zone immediately upstream from said desorption zone, said buffer zone defined as the adsorbent located between the desorbent input stream at a downstream boundary of said buffer zone and a raffinate output stream at an upstream boundary of said buffer zone; f. passing said feed stream into said adsorption zone at adsorption conditions to effect the selective adsorption of said para-isomer by said adsorbent in said adsorption zone and withdrawing a raffinate output stream comprising a bi-alkyl monosubstituted aromatic isomer and a hereinafter described desorbent material from said adsorption zone; g. passing a desorbent material comprising toluene into said desorption zone at desorption conditions to effect the displacement of said para-isomer from the adsorbent in said desorption zone; h. withdrawing an extract stream comprising said para-isomer and desorbent material from said desorption zone; i. passing at least a portion of said extract output stream to a first separation means and therein separating at first separation conditions at least a portion of said desorbent material to produce a para-isomer product; j. passing at least a portion of said raffinate output stream to a second separation means and therein separating at second separation conditions at least a portion of said desorbent material to produce a raffinate product; and k. periodically advancing through said column of adsorbent in a downstream direction with respect to fluid flow in said adsorption zone the feed input stream, raffinate output stream, desorbent input stream, and extract output stream to effect the shifting of zones through said adsorbent and the continuous production of extract output and raffinate output streams.

Claim 14

A process for separating the para-isomer from a feed stream comprising at least two bi-alkyl monosubstituted aromatic isomers, including the para-isomer, said isomers having more than eight and less than about eighteen carbon atoms per molecule which process employs an adsorbent comprising a X zeolite containing barium and potassium at exchangeable cationic sites and which process comprises the steps of: a. maintaining net fluid flow through a column of said adsorbent in a single direction, which column contains at least four zones having separate operational functions occurring therein and being serially interconnected with the terminal zones of said column connected to provide a continuous connection of said zones; b. maintaining an adsorption zone in said column, said zone defined by the adsorbent located between a feed input stream at an upstream boundary of said zone and a raffinate output stream at a downstream boundary of said zone; c. maintaining a purification zone immediately upstream from said adsorption zone, said purification zone defined by the adsorbent located between an extract output stream at an upstream boundary of said purification zone and said feed input stream at a downstream boundary of said purification zone; d. maintaining a desorption zone immediately upstream from said purification zone, said desorption zone defined by the adsorbent located between a desorbent input stream at an upstream boundary of said zone and said extract output stream at a downstream boundary of said zone; e. maintaining a buffer zone immediately upstream from said desorption zone, said buffer zone defined as the adsorbent located between the desorbent input stream at a downstream boundary of said buffer zone and a raffinate output stream at an upstream boundary of said buffer zone; f. passing said feed stream into said adsorption zone at adsorption conditions to effect the selective adsorption of said para-isomer by said adsorbent in said adsorption zone and withdrawing a raffinate output stream comprising a bi-alkyl monosubstituted aromatic isomer and a hereinafter described desorbent material from said adsorption zone; g. passing a desorbent material comprising toluene into said desorption zone at desorption conditions to effect the displacement of said para-isomer from the adsorbent in said desorption zone; h. withdrawing an extract stream comprising said para-isomer and desorbent material from said desorption zone; i. passing at least a portion of said extract output stream to a first separation means and therein separating at first separation conditions at least a portion of said desorbent material to produce a para-isomer product; j. passing at least a portion of said raffinate output stream to a second separation means and therein separating at second separation conditions at least a portion of said desorbent material to produce a raffinate product; and k. periodically advancing through said column of adsorbent in a downstream direction with respect to fluid flow in said adsorption zone the feed input stream, raffinate output stream, desorbent input stream, and extract output stream to effect the shifting of zones through said adsorbent and the continuous production of extract output and raffinate output streams.

Claim 15

The process as described in claim 12 wherein said para-isomer is para-diethylbenzene and said feed mixture comprises para-diethylbenzene and at least one other diethylbenzene isomer.

Claim 16

The process as described in claim 12 wherein said para-isomer is para-cymene and said feed mixture comprises para-cymene and at least one other cymene isomer.

Claim 17

The process as described in claim 12 wherein said zeolite is essentially completely exchanged with barium and potassium.

Claim 18

The process as described in claim 12 wherein said adsorption conditions and desorption conditions include a temperature within the range of from about 20° to about 250° C. and a pressure within the range of from about atmospheric to about 500 psig to insure liquid phase.