US4049873A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Surface treating compositions
Assignee: Imperial Chemical Industries Ltd
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Filing: 1975-12-24
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Granted: 1977-09-20
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Expires: 1995-12-24
Abstract
Abstract Organopolysiloxane release composition based on curable linear organopolysiloxanes modified by the incorporation of a copolymer containing a proportion of Me(R1Q)SiO groups in which at least one R1 group has at least 6 carbon atoms and Q is O or S, with or without a proportion of MeRSiO groups in which at least one R group has at least 4 carbon atoms, and substrates treated therewith.
Inventors
- 👤 Norman Geoffrey Creasey
- 👤 Leslie Clark Pike
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 21:44
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/08; C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08G77/18; C08G77/20; C08G77/70; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
262 words
An organopolysiloxane composition suitable for conferring release properties on substrates comprising 100 parts by weight of a linear diorganopolysiloxane in the form of a curable release composition and from 0.5 to 50 parts by weight based on the linear diorganopolysiloxane of a copolymer consisting essentially of the average general formula: ##STR17## where A is selected from the group consisting of R, R 1 Q, alkenyl and hydroxy groups and hydrogen, Q is oxygen or sulphur, R is selected from the group consisting of (a) alkyl, aryl, alkaryl, aralkyl and cycloalkyl groups, (b) groups --R 2 QR 3 where R 2 is a divalent organic group having at least 2 carbon atoms and is joined to silicon by a C-Si linkage and R 3 is a monovalent hydrocarbon group and (c) hydrocarbonoxy groups joined to silicon by a C-Si linkage, R 1 is a hydrocarbon or hydrocarbonoxy group; a and d, which will not normally be the same, are 0 or numbers not greater than 950, b is 0 or a number not greater than 999 and c is a number from 1 to 1000, a + b + c + d is not less than 20 and not greater than 1000, (b + c)/(a + b + c + d) is not less than 0.05, at least one of the groups R and R 1 being an alkyl group of 8 to 30 carbon atoms, the proportion of said copolymer in the composition being sufficient to provide at least one of said alkyl groups for each 2000 silicon atoms in the composition.
Claim 2
Dependent Claim
262 words
An organopolysiloxane composition suitable for conferring release properties on substrates comprising 100 parts by weight of a linear diorganopolysiloxane in the form of a curable release composition and from 0.5 to 50 parts by weight based on the linear diorganopolysiloxane of a copolymer consisting essentially of the average general formula: ##STR17## where A is selected from the group consisting of R, R 1 Q, alkenyl and hydroxy groups and hydrogen, Q is oxygen or sulphur, R is selected from the group consisting of (a) alkyl, aryl, alkaryl, aralkyl and cycloalkyl groups, (b) groups --R 2 QR 3 where R 2 is a divalent organic group having at least 2 carbon atoms and is joined to silicon by a C-Si linkage and R 3 is a monovalent hydrocarbon group and (c) hydrocarbonoxy groups joined to silicon by a C-Si linkage, R 1 is a hydrocarbon or hydrocarbonoxy group; a and d, which will not normally be the same, are 0 or numbers not greater than 950, b is 0 or a number not greater than 999 and c is a number from 1 to 1000, a + b + c + d is not less than 20 and not greater than 1000, (b + c)/(a + b + c + d) is not less than 0.05, at least one of the groups R and R 1 being an alkyl group of 8 to 30 carbon atoms, the proportion of said copolymer in the composition being sufficient to provide at least one of said alkyl groups for each 2000 silicon atoms in the composition.
Claim 3
Dependent Claim
41 words
A composition according to claim 1 wherein the curable release composition comprises a linear polysiloxane containing silicon-bonded hydroxyl groups, a cross-linking agent selected from polysiloxanes containing silicon-bonded hydrogen, alkyl polysilicates, trialkoxyorganosilanes and partial hydrolysates thereof and organotriacyloxysilanes, and a curing catalyst.
Claim 4
Dependent Claim
28 words
A composition according to claim 1 wherein the curable release composition comprises a linear polysiloxane containing silicon-bonded vinyl groups, a polysiloxane containing silicon-bonded hydrogen and a platinum catalyst.
Claim 5
Dependent Claim
23 words
A composition according to claim 1 wherein the curable release composition comprises a linear polysiloxane containing silicon-bonded vinyl groups and a peroxide catalyst.
Claim 6
Dependent Claim
23 words
A composition according to claim 1 wherein the groups A are selected from the group consisting of methyl and vinyl groups and hydrogen.
Claim 7
Dependent Claim
46 words
A composition according to claim 1 wherein (b + c)/(a + b + c + d) is from 0.1:1 to 0.9:1, a/(a + b + c + d) is not less than 0.1:1, and d/(a + b + c + d) is not greater than 0.3:1.
Claim 8
Dependent Claim
46 words
A composition according to claim 6 wherein (b + c)/(a + b + c + d) is from 0.2:1 to 0.7:1, a/(a + b + c + d) is not less than 0.3:1 and d/(a + b + c + d) is not greater than 0.05:1.
Claim 9
Dependent Claim
29 words
A composition according to claim 1 wherein the copolymer is present in amount from 0.5 to 15 parts by weight per 100 parts by weight of the linear diorganopolysiloxane.
Claim 10
Dependent Claim
56 words
A composition according to claim 1 wherein at least some of the R 1 groups have at least 4 carbon atoms and wherein the copolymer is present in amount such that the ratio of R 1 groups having at least 4 carbon atoms to total silicon atoms present in the composition is not less than 1:1000.
Claim 11
Dependent Claim
12 words
Substrates obtained by coating thereon a composition as claimed in claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-19 | 1981-03-21 | 1981-09-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-19 | 1985-03-21 | 1985-09-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-19 | 1989-03-21 | 1989-09-20 | $7700.00 | Window Closed / Lapsed |