US4049735A
Expired / Lapsed
US
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Use of elemental oxygen to inhibit elution of antimony from an antimony-ZSM-5 catalyst
Assignee: Mobil Oil AS
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Filing: 1976-12-09
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Granted: 1977-09-20
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Expires: 1996-12-09
Abstract
Abstract The lower monohydric alcohols and their ethers, especially methanol and dimethyl ether, are converted to a hydrocarbon mixture mostly ethylene, propylene and mononuclear aromatics, by co-feeding elemental oxygen and said alcohol and/or ether to a catalytic reactor that contains as catalyst a composite of antimony oxide and a crystalline aluminosilicate zeolite such as ZSM-5. Co-feeding elemental oxygen effectively inhibits the elution of antimony from the catalytic reactor.
Inventors
- 👤 Nai Yuen Chen
- 👤 William Joseph Reagan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 10:05
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; C; C07; C07C; C07C1/00; C07C1/20; B01J2229/00; B01J2229/30; B01J2229/36; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; Y; Y10; Y10S; Y10S585/00; Y10S585/949; Y10S585/954
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
147 words
An improved process for producing hydrocarbons, which comprises: passing to a catalytic conversion zone, under conversion conditions, a feed comprising oxygenated compounds and a co-feed of elemental oxygen, said oxygenated compounds consisting essentially of one or more lower monohydric alcohol having up to four carbon atoms, the ethers derived therefrom, or mixtures of said alcohols and ethers, said co-feed being passed in an amount equal to from 0.1 mol percent to 10 mol percent of said feed, and said catalytic conversion zone containing a catalyst comprising an intimate admixture of an oxide of antimony and a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index from 1 to 12, said antimony oxide constituting at least 1% by weight of said admixture, and recovering from said catalytic conversion zone a mixture comprising light olefins, monocyclic aromatic hydrocarbons and steam.
Claim 2
Dependent Claim
147 words
An improved process for producing hydrocarbons, which comprises: passing to a catalytic conversion zone, under conversion conditions, a feed comprising oxygenated compounds and a co-feed of elemental oxygen, said oxygenated compounds consisting essentially of one or more lower monohydric alcohol having up to four carbon atoms, the ethers derived therefrom, or mixtures of said alcohols and ethers, said co-feed being passed in an amount equal to from 0.1 mol percent to 10 mol percent of said feed, and said catalytic conversion zone containing a catalyst comprising an intimate admixture of an oxide of antimony and a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index from 1 to 12, said antimony oxide constituting at least 1% by weight of said admixture, and recovering from said catalytic conversion zone a mixture comprising light olefins, monocyclic aromatic hydrocarbons and steam.
Claim 3
Dependent Claim
38 words
The improved process of claim 1 wherein said conversion conditions include a space velocity of about 0.5 to 50 WHSV, a temperature of about 300° to about 550° C, and a pressure of about 0.2 to 30 atmospheres.
Claim 4
Dependent Claim
16 words
The improved process of claim 2 wherein said feed is methanol, dimethyl ether or mixtures thereof.
Claim 5
Dependent Claim
13 words
The improved process of claim 1 wherein said crystalline aluminosilicate zeolite is HZSM-5.
Claim 6
Dependent Claim
23 words
The improved process of claim 1 wherein the ratio of antimony oxide to crystalline aluminosilicate zeolite is from about 0.01 to about 0.50.
Claim 7
Dependent Claim
22 words
The improved process of claim 1 wherein the ratio of antimony oxide to crystalline aluminosilicate zeolite is from about 0.03 to 0.30.
Claim 8
Dependent Claim
30 words
The improved process of claim 2 wherein said co-feed of elemental oxygen is passed in an amount equal to from 0.3 mol percent to 3.0 mol percent of said feed.
Claim 9
Dependent Claim
23 words
The improved process of claim 7 wherein said feed is methanol, dimethyl ether or mixtures thereof and said crystalline aluminosilicate zeolite is HZSM-5.
Claim 10
Dependent Claim
19 words
The improved process of claim 7 wherein said catalyst contained in said catalytic conversion zone is a fluidized catalyst.
Claim 11
Independent Claim
46 words
A method for suppressing the elution of antimony during catalytic conversion of a feed with a catalyst comprising an intimate admixture of an oxide of antimony and a crystalline aluminosilicate zeolite, which comprises: co-feeding an amount of elemental oxygen effective to suppress said elution of antimony.
Claim 12
Independent Claim
46 words
A method for suppressing the elution of antimony during catalytic conversion of a feed with a catalyst comprising an intimate admixture of an oxide of antimony and a crystalline aluminosilicate zeolite, which comprises: co-feeding an amount of elemental oxygen effective to suppress said elution of antimony.
Claim 13
Dependent Claim
28 words
The method described in claim 10 wherein said elemental oxygen is co-fed at a rate equal to from 0.1 mol percent to 10 mol percent of said feed.
Claim 14
Dependent Claim
28 words
The method described in claim 10 wherein said elemental oxygen is co-fed at a rate equal to from 0.3 mol percent to 3 mol percent of said feed.
References Cited (Backward Citations)
US3686138A
Cited
US3979472A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-19 | 1981-03-21 | 1981-09-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-19 | 1985-03-21 | 1985-09-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-19 | 1989-03-21 | 1989-09-20 | $7700.00 | Window Closed / Lapsed |