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US4049599A Expired / Lapsed US ⏱️ 0.0 years remaining

High solids polyesters capable of dissolving in an organic solvent

Assignee: NOF Corp
•
Filing: 1976-01-09
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Granted: 1977-09-20
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Expires: 1996-01-09
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Abstract

Abstract A composition of matter comprising a polyester capable of dissolving in an organic solvent, having a solids content of at least 75% by weight, at a viscosity of X-Z on the Garner scale, prepared by reacting an aromatic polycarboxylic acid, anhydride, or a functionally acid esterifiable derivative thereof, an aliphatic polycarboxylic acid, anhydride or a functionally acid esterifiable derivative thereof, an aliphatic polyol and a monofunctional fatty acid to an acid number less than about 10, and then reacting the product of that reaction with an aromatic or aliphatic polycarboxylic acid, anhydride or a functional acid esterifiable derivative thereof to an acid number greater than 10 and less than about 60, wherein the total reactants have a hydroxyl/carboxyl ratio of greater than 1; the amount of monofunctional fatty acid employed ranges from about 20 to about 50% of the total number of acid equivalents of the reactants and the amount of aromatic polycarboxylic acid reacted in the first step ranges from about 20% to about 50% of the total number of acid equivalents of the reactants. Also described is a coating composition employing the above described polyester in conjunction with a nitrogenous composition, preferably for coating metallic substrates.

Inventors

  • 👤 Joseph C. Lott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 00:44
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/46; C08G63/48; C08G63/16; C08G63/20; C09; C09D; C09D167/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 183 words
A composition of matter comprising a polyester capable of dissolving in an organic solvent, having a solids content of at least 75% by weight, (on a pigment, filler and catalyst-free basis), at a viscosity of X-Z on the Garner scale, prepared by reacting an aromatic polycarboxylic acid, anhydride, or a functionally acid esterifiable derivative thereof, an aliphatic polycarboxylic acid, anhydride or a functionally acid esterifiable derivative thereof, an aliphatic polyol and a monofunctional fatty acid to an acid number less than about 10, and then reacting the product of that reaction with an aromatic or aliphatic polycarboxylic acid, anhydride or a functional acid esterifiable derivative thereof to an acid number greater than 10 and less than about 60, wherein the total reactants have a hydroxyl/carboxyl ratio of greater than 1; the amount of monofunctional fatty acid employed ranges from about 20 to about 50% of the total number of acid equivalents of the reactants, and the amount of aromatic polycarboxylic acid reacted in the first step ranges from about 20% to about 50% of the total number of acid equivalents of the reactants.
Claim 2
Dependent Claim 183 words
A composition of matter comprising a polyester capable of dissolving in an organic solvent, having a solids content of at least 75% by weight, (on a pigment, filler and catalyst-free basis), at a viscosity of X-Z on the Garner scale, prepared by reacting an aromatic polycarboxylic acid, anhydride, or a functionally acid esterifiable derivative thereof, an aliphatic polycarboxylic acid, anhydride or a functionally acid esterifiable derivative thereof, an aliphatic polyol and a monofunctional fatty acid to an acid number less than about 10, and then reacting the product of that reaction with an aromatic or aliphatic polycarboxylic acid, anhydride or a functional acid esterifiable derivative thereof to an acid number greater than 10 and less than about 60, wherein the total reactants have a hydroxyl/carboxyl ratio of greater than 1; the amount of monofunctional fatty acid employed ranges from about 20 to about 50% of the total number of acid equivalents of the reactants, and the amount of aromatic polycarboxylic acid reacted in the first step ranges from about 20% to about 50% of the total number of acid equivalents of the reactants.
Claim 3
Dependent Claim 24 words
The composition of claim 1 wherein the hydroxyl/carboxyl ratio in the first step of preparing the polyester ranges from about 1.3 to about 2.3.
Claim 4
Dependent Claim 45 words
The composition of claim 2 wherein the ratio of the number of acid equivalents in Step 1 of preparing the polyester for the aromatic polycarboxylic acid, anhydride or acid esterifiable derivative thereof and the aliphatic polycarboxylic acid, anhydride or acid esterifiable derivative thereof is one.
Claim 5
Dependent Claim 28 words
The composition of claim 1 wherein the aliphatic polyol is comprised of diols and triols present in a ratio of the number of hydroxyl equivalents of 1.5:1, triol:diol.
Claim 6
Dependent Claim 29 words
The composition of claim 1 further comprising an organic solvent soluble cross-linkable nitrogenous composition wherein the components are present on a weight basis as: 0.5 - 5:1 Polyester:Nitrogenous Composition
Claim 7
Dependent Claim 13 words
The composition of claim 5 wherein the nitrogenous composition is an amine-aldehyde condensate.
Claim 8
Dependent Claim 13 words
The composition of claim 6 wherein the nitrogenous composition is a melaminealdehyde condensate.

References Cited (Backward Citations)

US2973331A Cited
US3379548A Cited
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US3714091A Cited
US3994851A Cited
US3883454A Cited
US3920595A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-19 1981-03-21 1981-09-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-19 1985-03-21 1985-09-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-19 1989-03-21 1989-09-20 $7700.00 Window Closed / Lapsed

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