US4049426A
Expired / Lapsed
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Copper-base alloys containing chromium, niobium and zirconium
Assignee: Olin Corp
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Filing: 1976-10-04
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Granted: 1977-09-20
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Expires: 1996-10-04
Abstract
Abstract Copper base alloys containing chromium, zirconium and niobium are disclosed as well as a process of heat treating and mechanically working said alloys. The combination of alloying elements, hot and cold working, annealing and aging steps increases both the strength and electrical conductivity properties of the alloy without excessive cold working.
Inventors
- 👤 W. Gary Watson
- 👤 John F. Breedis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 03:59
CPC Classifications
C; C22; C22F; C22F1/00; C22F1/08; C22C; C22C9/00
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
40 words
A copper base alloy which exhibits a combination of high strength and high electrical conductivity, said alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper.
Claim 2
Dependent Claim
40 words
A copper base alloy which exhibits a combination of high strength and high electrical conductivity, said alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper.
Claim 3
Dependent Claim
109 words
A process for improving both the strength and electrical conductivity properties of copper base alloys, which comprises: a. casting a copper base alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper; b. hot working the alloy at a starting temperature of 950°-1000° C to effect the maximum solid solution of all alloying elements; c. rapidly cooling the alloy to maintain said maximum solid solution of all alloying elements; d. cold working the alloy to a total reduction of at least 60%; and e. aging said alloy at 400°-500° C for one to 24 hours.
Claim 4
Dependent Claim
109 words
A process for improving both the strength and electrical conductivity properties of copper base alloys, which comprises: a. casting a copper base alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper; b. hot working the alloy at a starting temperature of 950°-1000° C to effect the maximum solid solution of all alloying elements; c. rapidly cooling the alloy to maintain said maximum solid solution of all alloying elements; d. cold working the alloy to a total reduction of at least 60%; and e. aging said alloy at 400°-500° C for one to 24 hours.
Claim 5
Dependent Claim
127 words
A process for improving both the strength and electrical conductivity properties of copper base alloys, which comprises: a. casting a copper base alloy consisting essentially 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper; b. hot working the alloy at a starting temperature of 850°-950° C; c. solution annealing the worked alloy at a solutionizing temperature of 950°-1000° C, for a period of time sufficient to insure the maximum solid solution of all alloying elements; d. rapidly cooling the alloy to maintain said maximum solid solution of all alloying elements; e. cold working the alloy to a total reduction of at least 60%; and f. aging said alloy at 400°-500° C for one to 24 hours.
Claim 6
Dependent Claim
127 words
A process for improving both the strength and electrical conductivity properties of copper base alloys, which comprises: a. casting a copper base alloy consisting essentially 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper; b. hot working the alloy at a starting temperature of 850°-950° C; c. solution annealing the worked alloy at a solutionizing temperature of 950°-1000° C, for a period of time sufficient to insure the maximum solid solution of all alloying elements; d. rapidly cooling the alloy to maintain said maximum solid solution of all alloying elements; e. cold working the alloy to a total reduction of at least 60%; and f. aging said alloy at 400°-500° C for one to 24 hours.
Claim 7
Dependent Claim
31 words
A process as in claim 2 wherein said aging step is accomplished in cycles with said cold working, where the cycles end with either an aging or a cold working step.
Claim 8
Dependent Claim
30 words
A process as in claim 2 wherein the alloy is cast at a temperature which ranges between 25° C above the melting point of the alloy up to 1300° C.
Claim 9
Dependent Claim
21 words
A process as in claim 2 wherein said rapid cooling is sufficient to cool the alloy to at least 350° C.
Claim 10
Dependent Claim
31 words
A process as in claim 3 wherein said aging step is accomplished in cycles with said cold working, where the cycles end with either an aging or a cold working step.
Claim 11
Dependent Claim
17 words
A process as in claim 2 wherein the hot working occurs at a temperature of 975°-1000° C.
Claim 12
Dependent Claim
13 words
A process as in claim 3 wherein the solutionizing temperature is 975°-1000° C.
Claim 13
Dependent Claim
30 words
A process as in claim 3 wherein the alloy is cast at a temperature which ranges between 25° C above the melting point of the alloy up to 1300° C.
Claim 14
Dependent Claim
21 words
A process as in claim 3 wherein said rapid cooling is sufficient to cool the alloy to at least 350° C.
Claim 15
Dependent Claim
45 words
A wrought copper base alloy in the worked and aged condition having high strength and high electrical conductivity properties, said wrought alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper.
Claim 16
Dependent Claim
45 words
A wrought copper base alloy in the worked and aged condition having high strength and high electrical conductivity properties, said wrought alloy consisting essentially of 0.05 to 1.25% by weight chromium, 0.05 to 1.0% by weight zirconium, 0.05 to 1.5% by weight niobium, balance copper.
Claim 17
Dependent Claim
32 words
An alloy as in claim 1 wherein said alloy consists essentially of 0.5 to 1.0% by weight chromium, 0.1 to 0.4% by weight zirconium, 0.1 to 0.4% by weight niobium, balance copper.
Claim 18
Dependent Claim
34 words
An alloy as in claim 1 wherein a small but effective amount of an element selected from the group consisting of arsenic, magnesium, cobalt, boron, calcium, cadmium and mischmetal is added to said alloy.
Claim 19
Dependent Claim
32 words
A process as in claim 2 wherein said alloy consists essentially of 0.5 to 1.0% by weight chromium, 0.1 to 0.4% by weight zirconium, 0.1 to 0.4% by weight niobium, balance copper.
Claim 20
Dependent Claim
37 words
A process as in claim 2 wherein a small but effective amount of an element selected from the group consisting of arsenic, magnesium, cobalt, boron, calcium, cadmium and mischmetal is added to said alloy of step (a).
Claim 21
Dependent Claim
33 words
A wrought alloy as in claim 12 wherein said alloy consists essentially of 0.5 to 1.0% by weight chromium, 0.1 to 0.4% by weight zirconium, 0.1 to 0.4% by weight niobium, balance copper.
Claim 22
Dependent Claim
35 words
A wrought alloy as in claim 12 wherein a small but effective amount of an element selected from the group consisting of arsenic, magnesium, cobalt, boron, calcium, cadmium and mischmetal is added to said alloy.
Claim 23
Dependent Claim
31 words
A process as in claim 3 wherein said alloy consists essentially of 0.5 to 1.0% by weight chromium, 0.1to 0.4% by weight zirconium, 0.1 to 0.4% by weight niobium, balance copper.
Claim 24
Dependent Claim
37 words
A process as in claim 3 wherein a small but effective amount of an element selected from the group consisting of arsenic, magnesium, cobalt, boron, calcium, cadmium and mischmetal is added to said alloy of step (a).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-19 | 1981-03-21 | 1981-09-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-19 | 1985-03-21 | 1985-09-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-19 | 1989-03-21 | 1989-09-20 | $7700.00 | Window Closed / Lapsed |