← Back to Patent Explorer
US4048099A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocarbon conversion with an acidic trimetallic catalytic composite

Assignee: Honeywell UOP LLC
•
Filing: 1975-09-22
•
Granted: 1977-09-13
•
Expires: 1995-09-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic trimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IV-A metallic component, a Group VI-B transition metal component and a halogen component with a porous carrier material. The platinum group component, Group IV-A metallic component, and halogen component are present in the trimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IV-A metal and about 0.1 to about 3.5 wt. % halogen. The Group VI-B component is present in an amount of about 0.01 to about 3 wt. % and the atomic ratio of Group VI-B metal to platinum group metal is about 0.05:1 to about 4:1. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state; while substantially all of the Group IV-A metallic component and all of the Group VI-B component are present therein in an oxidation state above that of the corresponding metal.

Inventors

  • 👤 John C. Hayes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 06:26
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/56; B01J23/64; B01J23/652; B01J23/6527; B01J37/00; B01J37/22; C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/085; C10G35/09; C07; C07C; C07C2523/00; C07C2523/02; C07C2523/04; C07C2523/14; C07C2523/16; C07C2523/24; C07C2523/30; C07C2523/38; C07C2523/40; C07C2523/42; C07C2523/54; C07C2523/56; C07C2523/64; C07C2523/652

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 141 words
An acidic catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IV-A metal, about 0.01 to about 3 wt. % Group VI-B transition metal and about 0.1 to about 3.5 wt. % halogen; wherein the platinum group metal, Group IV-A metal and Group VI-B transition metal are uniformly dispersed throughout the porous carrier material; wherein substantially all of the platinum group metal is present in the elemental metallic state; wherein substantially all of the Group IV-A metal and the Group VI-B transition metal are present in oxide form; wherein the halogen component is present in the form of combined halide, and wherein the atomic ratio of Group VI-B transition metal to platinum group metal is about 0.05:1 to about 4:1.
Claim 2
Dependent Claim 141 words
An acidic catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IV-A metal, about 0.01 to about 3 wt. % Group VI-B transition metal and about 0.1 to about 3.5 wt. % halogen; wherein the platinum group metal, Group IV-A metal and Group VI-B transition metal are uniformly dispersed throughout the porous carrier material; wherein substantially all of the platinum group metal is present in the elemental metallic state; wherein substantially all of the Group IV-A metal and the Group VI-B transition metal are present in oxide form; wherein the halogen component is present in the form of combined halide, and wherein the atomic ratio of Group VI-B transition metal to platinum group metal is about 0.05:1 to about 4:1.
Claim 3
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the platinum group metal is platinum.
Claim 4
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the platinum group metal is palladium.
Claim 5
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the platinum group metal is iridium.
Claim 6
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the halogen component is combined chloride.
Claim 7
Dependent Claim 19 words
An acidic catalytic composite as defined in claim 1 wherein the porous carrier material is a refractory inorganic oxide.
Claim 8
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 6 wherein the refractory inorganic oxide is alumina.
Claim 9
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the Group IV-A metal is germanium.
Claim 10
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the Group IV-A metal is lead.
Claim 11
Dependent Claim 16 words
An acidic catalytic composite as defined in claim 1 wherein the Group IV-A metal is tin.
Claim 12
Dependent Claim 17 words
An acidic catalytic composite as defined in claim 1 wherein the Group VI-B transition metal is tungsten.
Claim 13
Dependent Claim 17 words
An acidic catalytic composite as defined in claim 1 wherein the Group VI-B transition metal is molybdenum.
Claim 14
Dependent Claim 17 words
An acidic catalytic composite as defined in claim 1 wherein the Group VI-B transition metal is chromium.
Claim 15
Dependent Claim 25 words
An acidic catalytic composite as defined in claim 1 wherein the Group IV-A metal to platinum metal atomic ratio is about 0.05:1 to about 10:1.
Claim 16
Dependent Claim 54 words
An acidic catalytic composite as defined in claim 1 wherein the catalytic composite contains about 0.05 to about 1 wt. % platinum group metal, about 0.05 to about 2 wt. % Group IV-A metal, about 0.05 to about 1 wt. % Group VI-B transition metal and about 0.5 to about 1.5 wt. % halogen.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-12 1981-03-14 1981-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-12 1985-03-14 1985-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-12 1989-03-14 1989-09-13 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag