US4048094A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reactivation of hydrotreating catalyst by operating at a temperature in excess of normal operating temperature
Assignee: BP Corp North America Inc
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Filing: 1976-08-23
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Granted: 1977-09-13
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Expires: 1996-08-23
Abstract
Abstract A method for reactivating the catalyst used in the mild hydrotreating of petroleum crude scale wax comprises contacting the catalyst with the feedstream at a temperature in excess of the normal operating temperature for the particular feedstream for a time sufficient to reactivate the catalyst and produce effluent having satisfactory color and stability characteristics. Operation at a temperature in excess of the normal operating temperature may follow conventional air-stream catalyst regeneration.
Inventors
- 👤 Roland L. Menzl
- 👤 P. Donald Hopkins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 08:32
CPC Classifications
C; C10; C10G; C10G73/00; C10G73/42; C10G73/44; B; B01; B01J; B01J23/00; B01J23/90; B01J23/94
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
180 words
A process for the reactivation of deactivated catalyst used in the hydrotreating of a hydrocarbon feedstream, which hydrotreating is conducted within a temperature range from about 500° F. to about 800° F. and a hydrogen partial pressure within the range from about 500 to about 2500 psia, wherein the catalyst comprises a Group VIa and Group VIII metal on a solid porous refractory oxide support of alumina having a pore diameter greater than about 80 A. and up to about 250 A, and wherein said feedstream comprises unfinished petroleum crude scale wax, which process comprises first contacting said catalyst with a mixture of steam containing about 0.2 to about 4 volume percent oxygen at a temperature of about 750° F. to about 1050° F. in a conventional air-steam catalyst regeneration, and then contacting said catalyst with said hydrogen and feedstream at a temperature from about 25° F. to about 200° F. in excess of the normal operating temperature that would be used for said hydrotreating stream, said contacting being conducted for a time that is sufficient to reactivate said catalyst.
Claim 2
Dependent Claim
180 words
A process for the reactivation of deactivated catalyst used in the hydrotreating of a hydrocarbon feedstream, which hydrotreating is conducted within a temperature range from about 500° F. to about 800° F. and a hydrogen partial pressure within the range from about 500 to about 2500 psia, wherein the catalyst comprises a Group VIa and Group VIII metal on a solid porous refractory oxide support of alumina having a pore diameter greater than about 80 A. and up to about 250 A, and wherein said feedstream comprises unfinished petroleum crude scale wax, which process comprises first contacting said catalyst with a mixture of steam containing about 0.2 to about 4 volume percent oxygen at a temperature of about 750° F. to about 1050° F. in a conventional air-steam catalyst regeneration, and then contacting said catalyst with said hydrogen and feedstream at a temperature from about 25° F. to about 200° F. in excess of the normal operating temperature that would be used for said hydrotreating stream, said contacting being conducted for a time that is sufficient to reactivate said catalyst.
Claim 3
Dependent Claim
26 words
The process of claim 1 wherein the feedstream contacting temperature is about 25° F. to about 100° F. above the normal operating temperature for said feedstream.
Claim 4
Dependent Claim
35 words
The process of claim 1 wherein the catalyst consists essentially from about 2 to about 4 weight percent cobalt oxide and from about 10 to about 15 weight percent molybdenum oxide on said alumina base.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-12 | 1981-03-14 | 1981-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-12 | 1985-03-14 | 1985-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-12 | 1989-03-14 | 1989-09-13 | $7700.00 | Window Closed / Lapsed |