US4048035A
Expired / Lapsed
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Photopolymerizable composition
Assignee: Mitsubishi Chemical Corp
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Filing: 1975-12-17
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Granted: 1977-09-13
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Expires: 1995-12-17
Abstract
Abstract A photopolymerizable composition for image formation, which comprises 30 - 95 wt. % of an unsaturated polyester having an acid value of 5 - 100 which is the condensation product of a carboxylic acid component containing more than 40 mole % of a carboxylic acid compound having the formula [I] <IMAGE> wherein R1 represents hydrogen or a C1-4 lower alkyl with a polyol component containing more than 30 mole % of a polyol having the formula [II] HO(R2O)nH wherein R2 represents C2-4 alkylene or a derivative thereof and n is an integer of 2 - 5 and 70 - 5 wt. % of a photopolymerizable unsaturated monomer and a photosensitizer.
Inventors
- 👤 Fumio Ide
- 👤 Tsuneo Kodama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 14:11
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/676
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
111 words
A photopolymerizable composition for image formation, which comprises: 30 - 95 wt. % of an unsaturated polyester having an acid value of 5 - 100 which is the condensation product of a carboxylic acid component containing more than 40 mole % of a carboxylic acid compound having the formula ##STR9## wherein R 1 represents hydrogen or a C 1-4 lower alkyl with a polyol component containing more than 30 mole % of a polyol having the formula ##STR10## wherein R 2 represents C 2-4 alkylene or a derivative thereof and n is an integer of 2 - 5; and 7- 5 wt. % of a photopolymerizable unsaturated monomer and a photosensitizer.
Claim 2
Dependent Claim
111 words
A photopolymerizable composition for image formation, which comprises: 30 - 95 wt. % of an unsaturated polyester having an acid value of 5 - 100 which is the condensation product of a carboxylic acid component containing more than 40 mole % of a carboxylic acid compound having the formula ##STR9## wherein R 1 represents hydrogen or a C 1-4 lower alkyl with a polyol component containing more than 30 mole % of a polyol having the formula ##STR10## wherein R 2 represents C 2-4 alkylene or a derivative thereof and n is an integer of 2 - 5; and 7- 5 wt. % of a photopolymerizable unsaturated monomer and a photosensitizer.
Claim 3
Dependent Claim
23 words
The photopolymerizable composition of claim 1, wherein said condensation product is modified by the incorporation of a polycarboxylic acid or an anhydride thereof.
Claim 4
Dependent Claim
83 words
The photopolymerizable composition of claim 1, wherein said unsaturated polyester having an acid value of 5 - 100 is produced by polycondensing a carboxylic acid component containing more than 40 mole % of said carboxylic acid compound of formula [I] with a polyol component containing more than 30 mole % of said polyol of formula [II] to obtain an unsaturated polyester having a hydroxyl value of 5 - 200 and then reacting a polycarboxylic acid or an anhydride thereof with said unsaturated polyester.
Claim 5
Dependent Claim
49 words
The photopolymerizable composition of claim 1, wherein said photopolymerizable unsaturated monomer is a combination of 5 - 95 wt. % of at least one monomer selected from the group consisting of acrylic acid, methacrylic acid and hydroxyesters thereof, and 95 - 5 wt.% of a second photopolymerizable unsaturated monomer.
Claim 6
Dependent Claim
24 words
The photopolymerizable composition of claim 4, wherein said second photopolymerizable unsaturated monomer is a photopolymerizable monomer containing more than two acryloyloxy or methacryloyloxy groups.
Claim 7
Dependent Claim
45 words
The photopolymerizable composition of claim 1, wherein said photopolymerizable unsaturated monomer is a mixture of monomers containing more than 30 wt. % of a compound having the formula ##STR11## wherein R 3 represents hydrogen, methyl, ethyl or methylol and R 4 represents hydrogen or methyl.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-12 | 1981-03-14 | 1981-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-12 | 1985-03-14 | 1985-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-12 | 1989-03-14 | 1989-09-13 | $7700.00 | Window Closed / Lapsed |