Direct gaseous reduction of oxidic metal ores with dual temperature cooling of the reduced product

Claim 2

In a process for the batchwise reduction of a metal oxide to sponge metal by contact with a hot reducing gas in a multiple unit reactor system of the type in which separate fixed beds of metal-bearing material are simultaneously treated in a plurality of reactors including at least one cooling reactor and at least one reduction reactor and a cool carbon-containing reducing gas is passed through a cooling reactor of said system, heated to a temperature of 950° to 1100° C. and then passed through a reduction reactor of said system, the method of cooling and carburizing a bed of metal-bearing material in said cooling reactor which comprises pre-heating a stream of said cool reducing gas to a temperature of 250° to 800° C. before it comes in contact with said metal bearing material, passing said preheated stream of reducing gas through said bed of metal-bearing material in said cooling reactor for a first period of time to carburize the metal thereof and reduce metal oxide present therein and thereafter passing a stream of said cool but not pre-heated reducing gas through said bed of metal-bearing material in said cooling reactor for a second period of time to complete the cooling of said material.

Claim 3

A process according to claim 1 wherein said reducing gas is generated by catalytically reforming a mixture of steam and hydrocarbon.

Claim 4

A process according to claim 1 wherein said stream of reducing gas is heated to a temperature of 400° to 700° C. before being passed through said bed of metal-bearing material in said cooling reactor.

Claim 5

A process according to claim 1 wherein during said first time period a portion of the effluent cooling gas from said bed of metal-bearing material is cooled and recycled through said bed.

Claim 6

A process according to claim 1 wherein during said second time period a portion of the reducing gas flowing through said bed of metal-bearing material is cooled and recycled to said bed.

Claim 7

A method according to claim 5 wherein the volumetric proportion of recycled gas is progressively increased during said second time period.

Claim 8

In a process for the batchwise reduction of metal oxide to sponge metal by contact with a hot reducing gas in a multiple unit reactor system of the type in which separate fixed beds of metal-bearing material are simultaneously treated in a plurality of reactors including at least one cooling reactor and at least one reduction and a cool carbon-containing reducing gas is passed through a cooling reactor of said system, heated to a temperature of 950° to 1100° C. and then passed through a reduction reactor of said system, the method of cooling and carburizing the bed of metal-bearing material in said cooling reactor which comprises pre-heating a stream of said cool reducing gas to a temperature of 250° to 800° C. before it comes in contact with said metal bearing material, passing said preheated stream of reducing gas through the bed of metal-bearing material in said cooling reactor for a first period of time to carburize the metal thereof and reduce metal oxide present therein, then passing a stream of said cool but not pre-heated reducing gas through said bed of metal-bearing material for a second period of time to further cool said material, cooling and recirculating a relatively small proportion of the gas passing through said bed during said second time period, thereafter during a third time period passing a stream of said cooled reducing gas through said bed of metal-bearing material and cooling and recycling a relatively large proportion of the gas passing through said bed during said third period to rapidly complete the cooling of said material.

Claim 9

In a process for the batchwise reduction of metal oxide to sponge metal by contact with a hot reducing gas in a multiple unit reactor system of the type in which separate fixed beds of metal-bearing material are simultaneously treated in a plurality of reactors including at least one cooling reactor and at least one reduction and a cool carbon-containing reducing gas is passed through a cooling reactor of said system, heated to a temperature of 950° to 1100° C. and then passed through a reduction reactor of said system, the method of cooling and carburizing the bed of metal-bearing material in said cooling reactor which comprises pre-heating a stream of said cool reducing gas to a temperature of 250° to 800° C. before it comes in contact with said metal bearing material, passing said preheated stream of reducing gas through the bed of metal-bearing material in said cooling reactor for a first period of time to carburize the metal thereof and reduce metal oxide present therein, then passing a stream of said cool but not pre-heated reducing gas through said bed of metal-bearing material for a second period of time to further cool said material, cooling and recirculating a relatively small proportion of the gas passing through said bed during said second time period, thereafter during a third time period passing a stream of said cooled reducing gas through said bed of metal-bearing material and cooling and recycling a relatively large proportion of the gas passing through said bed during said third period to rapidly complete the cooling of said material.

Claim 10

A process according to claim 7 and in which said metal oxide is iron ore and said sponge metal is sponge iron.

Claim 11

A method according to claim 8 wherein said reducing gas is generated by catalytically reforming a mixture of steam and hydrocarbon.

Claim 12

A process according to claim 8 wherein during said second time period the volumetric ratio of recycled cooling gas to fresh reducing gas from said reformer is from 0.3 to 1.5.

Claim 13

A process according to claim 8 wherein the volumetric ratio of recycled gas to fresh reducing gas from said reformer during said third time period is from 0.8 to 3.0.