US4045390A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silicone rubber compositions
Assignee: Shin-Etsu Chemical Co Ltd
•
Filing: 1975-12-23
•
Granted: 1977-08-30
•
Expires: 1995-12-23
Abstract
Abstract The organopolysiloxane compositions comprising (a) a linear diorganopolysiloxane having a block structure composed of alternately linked two kinds of blocks of dimethylsiloxane units on one hand and of dimethylsiloxane units and methylvinylsiloxane units on the other hand, (b) a silica filler, (c) a methylhydrogenpolysiloxane as a crosslinking agent, and (d) a platinum catalyst for accelerating crosslinking by addition reaction. Cured silicone rubber elastomers obtained from the composition have very excellent mechanical properties, especially tear strength.
Inventors
- 👤 Kunio Itoh
- 👤 Takeshi Fukuda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 11:36
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/10; C08K; C08K3/00; C08K3/34; C08K3/36; C08L83/04; Y; Y10; Y10S; Y10S528/00; Y10S528/901
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
249 words
An organopolysiloxane composition comprising (a) 100 parts by weight of a linear diorganopolysiloxane with a polymerization degree higher than 3,000 terminated at both chain ends with hydroxy groups directly bonded to the silicon atoms and composed of alternately linked portions of two kinds of blocks, (i) one of which is a vinyl-containing diorganopolysiloxane block composed of randomly linked methylvinylsiloxane units (CH 3 ) (CH 2 =CH)SiO and diorganosiloxane units R 2 SiO, where R is the same or different substituted or unsubstituted monovalent hydrocarbon group having no aliphatic unsaturation, the total number of said methylvinylsiloxane units and said diorganosiloxane units being from 10 to 400 and the number of said methylvinylsiloxane units in each of the vinyl-containing blocks being at least 3, and (ii) the other of which is a vinyl-free diorganopolysiloxane block composed of at least 400 of diorganosiloxane units R 2 'SiO where R' has the same meaning as R above, (b) from about 20 to about 200 parts by weight of a silica filler with a specific surface area at least 150 m.sup. 2 /g, (c) an organohydrogenpolysiloxane having at least two hydrogen atoms directly bonded to the silicon atoms in a molecule in an amount such that the total number of the hydrogen atoms directly bonded to the silicon atoms is equal to from about 40% to about 400% of the total number of the vinyl groups in the said component (a) defined above, and (d) a catalytic amount of platinum or a platinum compound.
Claim 2
Dependent Claim
249 words
An organopolysiloxane composition comprising (a) 100 parts by weight of a linear diorganopolysiloxane with a polymerization degree higher than 3,000 terminated at both chain ends with hydroxy groups directly bonded to the silicon atoms and composed of alternately linked portions of two kinds of blocks, (i) one of which is a vinyl-containing diorganopolysiloxane block composed of randomly linked methylvinylsiloxane units (CH 3 ) (CH 2 =CH)SiO and diorganosiloxane units R 2 SiO, where R is the same or different substituted or unsubstituted monovalent hydrocarbon group having no aliphatic unsaturation, the total number of said methylvinylsiloxane units and said diorganosiloxane units being from 10 to 400 and the number of said methylvinylsiloxane units in each of the vinyl-containing blocks being at least 3, and (ii) the other of which is a vinyl-free diorganopolysiloxane block composed of at least 400 of diorganosiloxane units R 2 'SiO where R' has the same meaning as R above, (b) from about 20 to about 200 parts by weight of a silica filler with a specific surface area at least 150 m.sup. 2 /g, (c) an organohydrogenpolysiloxane having at least two hydrogen atoms directly bonded to the silicon atoms in a molecule in an amount such that the total number of the hydrogen atoms directly bonded to the silicon atoms is equal to from about 40% to about 400% of the total number of the vinyl groups in the said component (a) defined above, and (d) a catalytic amount of platinum or a platinum compound.
Claim 3
Dependent Claim
30 words
The organopolysiloxane composition according to claim 1, wherein said monovalent hydrocarbon group R and R' are each selected from the class consisting of methyl, ethyl, propyl, butyl, and phenyl groups.
Claim 4
Dependent Claim
25 words
The organopolysiloxane composition according to claim 1, wherein from 0.05 to 5 mole % of the siloxane units in said component (a) are methylvinylsiloxane units.
Claim 5
Dependent Claim
15 words
The organopolysiloxane composition according to claim 1, wherein said silica filler is a fumed silica.
Claim 6
Dependent Claim
31 words
The organopolysiloxane composition according to claim 1, wherein the organic groups bonded to the silicon atoms in said component (c) to which the hydrogen atoms are directly bonded are methyl groups.
Claim 7
Dependent Claim
14 words
The organopolysiloxane composition according to claim 1, wherein said platinum compound is chloroplatinic acid.
Claim 8
Dependent Claim
38 words
The organopolysiloxane composition according to claim 1, wherein said component (d) is present in an amount ranging from 0.5 p.p.m. to 20 p.p.m. by weight as platinum based on the total amount of said components (a) and (c).
Claim 9
Dependent Claim
56 words
The organopolysiloxane composition according to claim 1, wherein at least one additional component is added to said composition, said component being selected from the class consisting of an organophosphorous compound or an organic amine stabilizing agent, an ester silane or silanol dispersing agent, an iron or ceric oxide, or iron octoate heat stability improver, and pigments.
References Cited (Backward Citations)
US3844992A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-29 | 1981-02-28 | 1981-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-29 | 1985-02-28 | 1985-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-29 | 1989-02-28 | 1989-08-30 | $7700.00 | Window Closed / Lapsed |