US4045377A
Expired / Lapsed
US
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Cationic polymer prepared from dicyandiamide, a polyamide, a dialkylamine, and an epoxide
Assignee: Hercules LLC
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Filing: 1975-10-20
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Granted: 1977-08-30
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Expires: 1995-10-20
Abstract
Abstract Cationic polymers which are useful as flocculants are prepared by reacting (a) a condensation polymer prepared from dicyandiamide and a polyalkylenepolyamine, (b) a dialkylamine, and (c) a difunctional epoxide.
Inventors
- 👤 Stephen C. Pearson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:34
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/02; C08G73/0206; C08G73/0213; C08G73/022; B; B01; B01D; B01D21/00; B01D21/01; C08L; C08L63/00
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
258 words
A process for the preparation of a water-soluble cationic polymer comprising: a. reacting and polyalkylenepolyamine having the formula ##STR4## wherein R 1 is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl; R 2 is independent of the other R 2 and is an alkylene radical having from 2 to 6 carbon atoms and x is an integer of 1 to 5 and dicyandiamide in a mole ratio of polyalkylenepolyamine to dicyandiamide of from about 1.2/1 to about 1/1.2 until reaction is substantially complete whereby a condensation polymer is produced, b. forming an aqueous solution of the condensation polymer of step (a), c. admixing dialkylamine having the formula ##STR5## wherein R 3 is independent of the other R 3 and is a C 1 -C 3 alkly, and the aqueous solution of condensate polymer of step (b) in a mole ratio of dialkylamine to the equivalent molecular weight of the repeating unit of the condensation polymer of from about 20/1 to about 2/1, d. admixing the mixture of step (c) with difunctional epoxide, the mole ratio of difunctional epoxide to dialkylamine being from about 2/1 to about 1/1, e. reacting the resulting admixture at a temperature of from about 50° C. to about 80° C., said reaction being continued until the viscosity of the resultant cationic polymer is in the range of from about 40 centipoises to about 250 centipoises, viscosity of the cationic polymer being measured in water as a 40% by weight solution at 25° C., and f. terminating the reaction of step (e).
Claim 2
Dependent Claim
258 words
A process for the preparation of a water-soluble cationic polymer comprising: a. reacting and polyalkylenepolyamine having the formula ##STR4## wherein R 1 is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl; R 2 is independent of the other R 2 and is an alkylene radical having from 2 to 6 carbon atoms and x is an integer of 1 to 5 and dicyandiamide in a mole ratio of polyalkylenepolyamine to dicyandiamide of from about 1.2/1 to about 1/1.2 until reaction is substantially complete whereby a condensation polymer is produced, b. forming an aqueous solution of the condensation polymer of step (a), c. admixing dialkylamine having the formula ##STR5## wherein R 3 is independent of the other R 3 and is a C 1 -C 3 alkly, and the aqueous solution of condensate polymer of step (b) in a mole ratio of dialkylamine to the equivalent molecular weight of the repeating unit of the condensation polymer of from about 20/1 to about 2/1, d. admixing the mixture of step (c) with difunctional epoxide, the mole ratio of difunctional epoxide to dialkylamine being from about 2/1 to about 1/1, e. reacting the resulting admixture at a temperature of from about 50° C. to about 80° C., said reaction being continued until the viscosity of the resultant cationic polymer is in the range of from about 40 centipoises to about 250 centipoises, viscosity of the cationic polymer being measured in water as a 40% by weight solution at 25° C., and f. terminating the reaction of step (e).
Claim 3
Dependent Claim
16 words
The process of claim 1 in which the polyalkylenepolyamine is diethylenetriamine and the dialkylamine is dimethylamine.
Claim 4
Dependent Claim
12 words
The process of claim 2 in which the difunctional epoxide is epichlorohydrin.
Claim 5
Dependent Claim
32 words
The process of claim 1 in which the mole ratio of dialkylamine to the equivalent molecular weight of the repeating unit of the condensate polymer is from about 8/1 to about 3/1.
Claim 6
Dependent Claim
17 words
The process of claim 4 in which the mole ratio of polyalkylenepolyamine to dicyandiamide is about 1.1/1.
Claim 7
Dependent Claim
13 words
The process of claim 1 in which the difunctional epoxide is an epihalohydrin.
Claim 8
Dependent Claim
24 words
The process of claim 6 in which polyalkylenepolyamine and dicyandiamide are reacted at a temperature of from about 120° C. to about 170° C.
Claim 9
Dependent Claim
22 words
The process of claim 7 in which the difunctional epoxide is selected from the group consisting of epichlorohydrin, epibromohydrin, epiiodohydrin and epifluorohydrin.
Claim 10
Dependent Claim
25 words
The process of claim 8 in which the polyalkylenepolyamine is selected from the group consisting of diethylenetriamine, triethylenetetriamine, tetraethylenepentamine, dipropylenetriamine, dihexamethylenetriamine, pentaethylenehexamine, and mixtures thereof.
Claim 11
Dependent Claim
22 words
The process of claim 9 in which the dialkylamine is selected from the group consisting of dimethylamine, diethylamine, methylethylamine and mixtures thereof.
Claim 12
Dependent Claim
13 words
The water-soluble cationic polymer prepared in accordance with the process of claim 1.
Claim 13
Dependent Claim
13 words
The water-soluble cationic polymer prepared in accordance with the process of claim 3.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-29 | 1981-02-28 | 1981-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-29 | 1985-02-28 | 1985-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-29 | 1989-02-28 | 1989-08-30 | $7700.00 | Window Closed / Lapsed |