US4045240A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Amorphous precipitated siliceous pigments and methods for their production
Assignee: JM Huber Corp
•
Filing: 1976-03-24
•
Granted: 1977-08-30
•
Expires: 1996-03-24
Abstract
Abstract A method for producing precipitated silicic acid pigments and silicates having a unique combination of physical and chemical properties is disclosed. The pigments are produced by acidulating a solution of an alkali metal silicate with an acid until precipitation just begins. At this point the reaction mass is aged for a period of time and thereafter the acid addition is continued until the precipitated product is obtained. Pigments produced in accordance with the invention exhibit lower wet cake moisture (or higher percent solids).
Inventors
- 👤 Satish K. Wason
- 👤 Peter VAN DER Heem
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:31
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/28; A; A61; A61K; A61K8/00; A61K8/18; A61K8/19; A61K8/25; A61Q; A61Q11/00; C01; C01B; C01B33/00; C01B33/113; C01B33/12; C01B33/18; C01B33/181; C01B33/187; C01B33/193; C01B33/20; C01B33/26; C01B33/28; C01B33/2807; C01B33/2838; C01B33/36; C01B33/38; C01B33/40; C01B33/42; C01B33/46; C09C1/40; C09D; C09D7/00; C09D7/40; C09D7/42; C01P; C01P2002/00; C01P2002/02; C01P2006/00; C01P2006/10; C01P2006/11; C01P2006/12; C01P2006/19; C01P2006/60; C01P2006/80; C01P2006/82; C01P2006/90
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
223 words
A method for producing amorphous, precipitated silica pigments having an improved combination of chemical and physical properties, said method comprising the steps of: acidulating an aqueous solution of an alkali metal silicate with an acid selected from the group consisting of sulfuric acid, nitric acid, and hydrochloric acid; said alkali metal silicate having a SiO 2 /X 2 O mol ratio in the range of from about 2.0 to 2.7 wherein X is selected from the group consisting of sodium, potassium, and lithium; said aqueous alkali metal silicate solution having a concentration on the order of about 1.0 to 2.5 pounds silicate per gallon, said acid being added as a dilute solution thereof and having a concentration of from about 10 to 25% by weight acid based on the weight of the solution thereof; continuing the addition of said acid until that point at which precipitation of said pigment just begins; interrupting and discontinuing the addition of said acid to said silicate at said point; aging the aqueous reaction mass for a period of time sufficient to obtain an equilibrium condition of the reactants comprising said reaction mass; continuing the addition of said acid to said aqueous silicate solution following said aging period until the precipitation of said pigment is complete; separating the precipitated pigment from the reaction mass and recovering the product.
Claim 2
Independent Claim
223 words
A method for producing amorphous, precipitated silica pigments having an improved combination of chemical and physical properties, said method comprising the steps of: acidulating an aqueous solution of an alkali metal silicate with an acid selected from the group consisting of sulfuric acid, nitric acid, and hydrochloric acid; said alkali metal silicate having a SiO 2 /X 2 O mol ratio in the range of from about 2.0 to 2.7 wherein X is selected from the group consisting of sodium, potassium, and lithium; said aqueous alkali metal silicate solution having a concentration on the order of about 1.0 to 2.5 pounds silicate per gallon, said acid being added as a dilute solution thereof and having a concentration of from about 10 to 25% by weight acid based on the weight of the solution thereof; continuing the addition of said acid until that point at which precipitation of said pigment just begins; interrupting and discontinuing the addition of said acid to said silicate at said point; aging the aqueous reaction mass for a period of time sufficient to obtain an equilibrium condition of the reactants comprising said reaction mass; continuing the addition of said acid to said aqueous silicate solution following said aging period until the precipitation of said pigment is complete; separating the precipitated pigment from the reaction mass and recovering the product.
Claim 3
Dependent Claim
31 words
The method in accordance with claim 1, said method further comprising the steps of separating the precipitated pigment from said aqueous reaction mass and thereafter drying and disintegrating the precipitated material.
Claim 4
Dependent Claim
17 words
The method in accordance with claim 1, wherein X is sodium and the acid is sulfuric acid.
Claim 5
Dependent Claim
26 words
The method in accordance with claim 1, wherein said alkali metal silicate is selected from the group consisting of sodium silicate, potassium silicate and lithium silicate.
Claim 6
Dependent Claim
20 words
The method of claim 1, wherein X is sodium and the SiO 2 /Na 2 O mol ratio is 2.5.
Claim 7
Dependent Claim
23 words
The method in accordance with claim 1, wherein said aging period is in the range of from about 10 minutes to 2 hours.
Claim 8
Dependent Claim
11 words
The product produced in accordance with the method of claim 1.
References Cited (Backward Citations)
US3235331A
Cited
US3503707A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-29 | 1981-02-28 | 1981-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-29 | 1985-02-28 | 1985-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-29 | 1989-02-28 | 1989-08-30 | $7700.00 | Window Closed / Lapsed |