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US4045231A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive resin composition for flexographic printing plates

Assignee: Tokyo Ohka Kogyo Co Ltd
•
Filing: 1976-02-18
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Granted: 1977-08-30
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Expires: 1996-02-18
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Abstract

Abstract A photosensitive resin composition for flexographic printing plates comprising styrene-butadiene block copolymer containing 35 - 50% by weight of styrene, at least one liquid prepolymer having a molecular weight of 1,000 - 5,000 selected from the group consisting of polybutadiene and butadiene-styrene copolymer, at least one photopolymerizable monomer containing at least one vinyl group, such as tetraethyleneglycol diacrylate, a photopolymerization initiator such as benzophenone, and a thermopolymerization inhibitor optionally added. This photosensitive resin composition affords relief images suitable for use in flexographic printing.

Inventors

  • 👤 Hiroyuki Toda
  • 👤 Eiichi Otomegawa
  • 👤 Toshimi Aoyama
  • 👤 Hisashi Nakane

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:55
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/033; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/118

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 56 words
A photosensitive resin composition for flexographic printing plates comprising (a) styrene-butadiene block copolymer containing 35- 50% by weight of styrene, (b) at least one liquid prepolymer having a molecular weight of 1,000- 5,000 selected from the group consisting of polybutadiene and butadiene-styrene copolymer, and (c) at least one photopolymerizable monomer containing one or more vinyl groups.
Claim 2
Dependent Claim 56 words
A photosensitive resin composition for flexographic printing plates comprising (a) styrene-butadiene block copolymer containing 35- 50% by weight of styrene, (b) at least one liquid prepolymer having a molecular weight of 1,000- 5,000 selected from the group consisting of polybutadiene and butadiene-styrene copolymer, and (c) at least one photopolymerizable monomer containing one or more vinyl groups.
Claim 3
Dependent Claim 38 words
The photosensitive resin composition of claim 1 wherein said liquid prepolymer as the component (b) is contained in amount of 1-200 parts by weight per 100 parts by weight of said styrene-butadiene block copolymer as the component (a).
Claim 4
Dependent Claim 51 words
The photosensitive resin composition of claim 1 wherein said photopolymerizable monomer as the component (c) is contained in an amount of 3- 30 parts by weight per 100 parts by weight of a total of said styrene-butadiene block copolymer as the component (a) and said liquid prepolymer as the component (b).
Claim 5
Dependent Claim 44 words
The photosensitive resin composition of claim 1 wherein said photopolymerizable monomer as the component (c) is a polyvinyl ester obtained by reacting a diol or triol having 2- 10 carbon atoms with a monoethylenically unsaturated monocarboxylic or polycarboxylic acid having 3- 5 carbon atoms.
Claim 6
Dependent Claim 34 words
The photosensitive resin composition of claim 1 wherein a thermopoloymerization inhibitor is contained in an amountof 0.05- 1 part by weight per 100 parts by weight of said photopolymerizable monomer as the component (c).
Claim 7
Dependent Claim 17 words
The photosensitive resin composition of claim 1 wherein said composition is shaped into a film or plate.
Claim 8
Dependent Claim 12 words
The photosensitive resin composition of claim 1 which contains a photopolymerization initiator.
Claim 9
Dependent Claim 39 words
The photosensitive resin composition of claim 7 wherein said photopolymerization initiator as the component (d) is contained in an amount of 0.1- 30 parts by weight per 100 parts by weight of said photopolymerizable monomer as the component (c).
Claim 10
Dependent Claim 36 words
The photosensitive resin composition of claim 1 in which said styrene-butadiene block copolymer is a soluble, thermoplastic composed of at least two thermoplastic non-elastomeric polystyrene blocks and an elastomeric polybutadiene block interposed between the polystyrene blocks.
Claim 11
Dependent Claim 81 words
The photosensitive resin composition of claim 9 in which said liquid prepolymer (b) is a polybutadiene which contains in the molecule 1,2 - bonds of at least 90 mol% having the formula ##STR3## wherein n is a positive integer, or polybutadieneor styrene butadiene copolymer which contains in the molecule 1,4-bonds of at least 80 mol % and is shown by the general formula: ##STR4## wherein X stands for --CH═CH 2 or --C 6 H 5 and m for a positive integer.

References Cited (Backward Citations)

US3676386A Cited
US3925076A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-29 1981-02-28 1981-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-29 1985-02-28 1985-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-29 1989-02-28 1989-08-30 $7700.00 Window Closed / Lapsed

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