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US4045225A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a photographic image

Assignee: Fujifilm Holdings Corp
•
Filing: 1976-07-23
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Granted: 1977-08-30
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Expires: 1996-07-23
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Abstract

Abstract A method of forming an image which comprises subjecting a photographic element comprising a support and at least one photographic layer in which there is image-wise distributed a substance having a catalytic effect to image-wise intensification in the presence of a reducing agent using a solution containing: (1) at least one of hydrogen peroxide and compounds capable of releasing hydrogen peroxide or a halogenite, and (2) at least one nitro-substituted nitrogen-containing heterocyclic compound represented by the following General Formulae (I) and (II); ##STR1## in which R 1 represents hydrogen atom, an alkyl group, SO 3 M or COOM, wherein M represents a hydrogen atom, an alkali metal or ammonium group, X represents nitrogen atom or CR', wherein R' represents a hydrogen atom or a lower alkyl group, and ##STR2## in which R 2 represents hydrogen atom, an alkyl group, SO 3 M or COOM, wherein M represents a hydrogen atom, an alkali metal or an ammonium group and Y represents a hydrogen atom, an alkyl group or CH 2 --S--(CH 2 ) n --Y' wherein n represents 1 to 3 and Y' represents a hydrogen atom or SO 3 M.

Inventors

  • 👤 Isao Shimamura
  • 👤 Koichi Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:11
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3017; G03C7/392; G03C7/39208; G03C7/3924; G03C7/39244; Y; Y10; Y10S; Y10S430/00; Y10S430/144; Y10S430/156

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 247 words
A method of forming an image which comprises subjecting an image-wise exposed and developed photographic element comprising a support and at least one photographic layer in which there is image-wise distributed a metallic silver having a catalytic effect to image-wise intensification in the presence of a reducing agent which diffuses into the layer of photographic element from the developer solution or the intensifier solution, or is previously incorporated into the layer, using a solution consisting essentially of at least one of a halogenite, hydrogen peroxide and one or more compounds capable of releasing hydrogen peroxide as an oxidation agent; and containing at least one nitro-substituted nitrogen-containing heterocyclic compound represented by the following General formulae (I) and (II); ##STR5## in which R 1 represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms, SO 3 M or COOM wherein M represents hydrogen atom, an alkali metal or an ammonium group, X represents nitrogen atom or CR' wherein R' represents a hydrogen atom or a lower alkyl group of 1 to 5 carbon atoms, and ##STR6## in which R 2 represents hydrogen atom, an alkyl group of 1 to 5 carbon atoms, SO 3 M or COOM wherein M represents hydrogen atom, an alkali metal or ammonium group and Y represents hydrogen atom, an alkyl group of 1 to 5 carbon atoms or CH 2 --S--(CH 2 ) n --Y' wherein n represents 1 to 3 and Y' represents a hydrogen atom or SO 3 M.
Claim 2
Independent Claim 247 words
A method of forming an image which comprises subjecting an image-wise exposed and developed photographic element comprising a support and at least one photographic layer in which there is image-wise distributed a metallic silver having a catalytic effect to image-wise intensification in the presence of a reducing agent which diffuses into the layer of photographic element from the developer solution or the intensifier solution, or is previously incorporated into the layer, using a solution consisting essentially of at least one of a halogenite, hydrogen peroxide and one or more compounds capable of releasing hydrogen peroxide as an oxidation agent; and containing at least one nitro-substituted nitrogen-containing heterocyclic compound represented by the following General formulae (I) and (II); ##STR5## in which R 1 represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms, SO 3 M or COOM wherein M represents hydrogen atom, an alkali metal or an ammonium group, X represents nitrogen atom or CR' wherein R' represents a hydrogen atom or a lower alkyl group of 1 to 5 carbon atoms, and ##STR6## in which R 2 represents hydrogen atom, an alkyl group of 1 to 5 carbon atoms, SO 3 M or COOM wherein M represents hydrogen atom, an alkali metal or ammonium group and Y represents hydrogen atom, an alkyl group of 1 to 5 carbon atoms or CH 2 --S--(CH 2 ) n --Y' wherein n represents 1 to 3 and Y' represents a hydrogen atom or SO 3 M.
Claim 3
Dependent Claim 15 words
The method of claim 1, which comprises the steps of development, intensification, bleaching and fixing.
Claim 4
Dependent Claim 14 words
The method of claim 1, which comprises the steps of development, intensification and blixing.
Claim 5
Dependent Claim 11 words
The method of claim 1, where material (1) is hydrogen peroxide.
Claim 6
Dependent Claim 11 words
The method of claim 1, where material (1) is a halogenite.
Claim 7
Dependent Claim 11 words
The method of claim 5, where the halogenite is sodium chlorite.
Claim 8
Dependent Claim 17 words
The method of claim 1, where material (1) is one or more compounds capable releasing hydrogen peroxide.

References Cited (Backward Citations)

US3820997A Cited
US3765891A Cited
US3841873A Cited
US3846130A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-29 1981-02-28 1981-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-29 1985-02-28 1985-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-29 1989-02-28 1989-08-30 $7700.00 Window Closed / Lapsed

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