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US4044064A Expired / Lapsed US ⏱️ 0.0 years remaining

Conversion of Fischer-Tropsch heavy product to high quality jet fuel

Assignee: Mobil Oil AS
•
Filing: 1976-03-29
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Granted: 1977-08-23
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Expires: 1996-03-29
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Abstract

Abstract Upgrading a fraction of a heavy Fischer-Tropsch oil to jet fuel by hydropretreating a 350° to 850° F boiling fraction; separating the hydrotreated product into a 650° F minus and a 650° F plus fraction, separating the650° F minus fraction to provide a 350° F minus naphtha boiling range fraction and a 350° to 650° F light distillate fraction; distilling the 350° to 650° F hydrotreated fraction to provide a fraction boiling in the range of 350° F to 550° F separate from a 550° to 650° F fraction processing either of the 650° F plus fraction above separated or the 350° to 550° F boiling fraction above obtained over a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12 with hydrogen, at a temperature of about 500° to 800° F, a hydrogen partial pressure of about 100 to 800 psig and a space velocity in the range of about 0.5 to 5 LHSV to produce a converted product comprising lower boiling hydrocarbons than the feed charged and recovering as a product of the process a reduced pour point diesel oil fraction, a 350° to 550° F jet fuel fraction, and a 350° F minus naphtha product fraction.

Inventors

  • 👤 Donald Milstein
  • 👤 Thomas R. Stein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 18:45
CPC Classifications
C; C10; C10G; C10G65/00; C10G65/02; C10G65/04; C10G65/043; C10G45/00; C10G45/58; C10G45/60; C10G45/64; F; F02; F02B; F02B3/00; F02B3/06; Y; Y10; Y10S; Y10S208/00; Y10S208/95

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 248 words
A process of producing high quality gasoline and higher boiling products which comprises hydrotreating a wide boiling range aliphatic hydrocarbon fraction comprising oxygenates boiling in the range of about 350° to 850° F; separating the hydrotreated product to produce a 650° F plus fraction and a 650° F minus fraction, separating said 650° F minus fraction to produce a gasoline boiling fraction and higher boiling light oil fraction, separating said high boiling light oil fraction to produce a kerosine boiling fraction and a higher boiling distillate fraction having a low pour point. separately converting said kerosine boiling fraction and said 650° F plus fraction with a catalyst comprising a special zeolite component having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12, at a temperature in the range of about 500° to 800° F, and at a space velocity of about 0.5 to 5 WHSV, to produce a conversion product of said zeolite catalyst, separating product obtained by converting said 650° F plus distillate fraction with said special zeolite catalyst to produce a C 4 minus gaseous product, a naphtha boiling range product, and a higher boiling distillate product suitable for producing jet fuel boiling range material and diesel fuel; and separating product obtained by converting said kerosine boiling fraction with said special zeolite catalyst to produce a C 4 minus gaseous product, a naphtha boiling range product and a kerosine boiling range product suitable for use as jet fuel.
Claim 2
Dependent Claim 248 words
A process of producing high quality gasoline and higher boiling products which comprises hydrotreating a wide boiling range aliphatic hydrocarbon fraction comprising oxygenates boiling in the range of about 350° to 850° F; separating the hydrotreated product to produce a 650° F plus fraction and a 650° F minus fraction, separating said 650° F minus fraction to produce a gasoline boiling fraction and higher boiling light oil fraction, separating said high boiling light oil fraction to produce a kerosine boiling fraction and a higher boiling distillate fraction having a low pour point. separately converting said kerosine boiling fraction and said 650° F plus fraction with a catalyst comprising a special zeolite component having a silica to alumina ratio of at least 12 and a constraint index of 1 to 12, at a temperature in the range of about 500° to 800° F, and at a space velocity of about 0.5 to 5 WHSV, to produce a conversion product of said zeolite catalyst, separating product obtained by converting said 650° F plus distillate fraction with said special zeolite catalyst to produce a C 4 minus gaseous product, a naphtha boiling range product, and a higher boiling distillate product suitable for producing jet fuel boiling range material and diesel fuel; and separating product obtained by converting said kerosine boiling fraction with said special zeolite catalyst to produce a C 4 minus gaseous product, a naphtha boiling range product and a kerosine boiling range product suitable for use as jet fuel.
Claim 3
Dependent Claim 11 words
The process claimed in claim 1 wherein said zeolite is ZSM-5.
Claim 4
Dependent Claim 31 words
The process of claim 1 wherein said gasoline boiling fraction separated from said 650° F minus fraction has an end boiling point within the range of 350° to about 400° F.
Claim 5
Dependent Claim 23 words
The process of claim 1 wherein said kerosine boiling fraction separated from said 650° F minus fraction boils up to about 550° F.
Claim 6
Dependent Claim 31 words
The process of claim 1 wherein a naphtha boiling product is recovered from said zeolite catalyst conversion operation having an end boiling point within the range of 350° to 400° F.
Claim 7
Dependent Claim 31 words
The process of claim 1 wherein a kerosine product of desired low freeze point boiling within the range of 350° to 450° F is recovered from said zeolite catalyst conversion operation.
Claim 8
Dependent Claim 21 words
The process of claim 1 wherein a diesel fuel is recovered from said zeolite catalyst conversion operation boiling above 400° F.
Claim 9
Dependent Claim 25 words
The process of claim 1 wherein said zeolite conversion catalyst is in admixture with from 0.5 to 5 weight percent of a metal hydrogenation/dehydrogenation component.
Claim 10
Dependent Claim 24 words
The process of claim 8 wherein a hydrogen pressure within the range of 100 to 800 psig is employed in said zeolite conversion operation.

References Cited (Backward Citations)

US3172842A Cited
US2740804A Cited
US2752382A Cited
US3700585A Cited
US3729409A Cited
US3760024A Cited
US3843510A Cited
US3960978A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-22 1981-02-21 1981-08-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-22 1985-02-21 1985-08-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-22 1989-02-21 1989-08-23 $7700.00 Window Closed / Lapsed

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