Hydrocurable oxazolidine polyanhydride compositions

Claim 2

A hydrocurable composition comprising a polyanhydride having two or more pendant anhydride groups and an oxazolidine of the formula: ##STR19## wherein R is an organic radical; R 1 is hydrogen, phenyl, benzyl or C 1 -C 12 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl or R 1 and R 2 are joined together with the carbon atom to which they are attached to form a five- or six-membered saturated carbon ring; Y is a radical of the formula ##STR20## wherein n' is an integer of 2 or 3 and R 3 and R 4 are the same or different radicals selected from hydrogen, C 1 -C 12 alkyl, C 6 -C 10 aryl or C 7 -C 12 aralkyl or alkaryl and n is an integer equal to the valence of R.

Claim 3

The composition of claim 1 wherein the polyanhydride is prepared from maleic anhydride and one or more materials selected from C 1 -C 18 alkyl acrylate or methacrylate, a polyunsaturated fatty acid ester, an α-olefin, a vinyl ether, vinyl acetate, ethylene or styrene.

Claim 4

The composition of claim 2 wherein the polyanhydride is prepared from maleic anhydride and either a polyunsaturated fatty acid ester or a C 3 -C 6 acrylate or methacrylate.

Claim 5

The composition of claim 3 wherein the polyunsaturated fatty acid ester is tung oil and the acrylate is butyl acrylate.

Claim 6

The composition of claim 1 wherein the oxazolidine has the following structural formula: ##STR21## wherein R 1 is hydrogen, phenyl, benzyl or a C 1 -C 12 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl or R 1 and R 2 are joined together with the carbon atom to which they are attached to form a saturated five- or six-membered carbon ring and Y is a radical of the formula: ##STR22## wherein n is 2 or 3 and R 3 and R 4 are the same or different radicals selected from hydrogen, C 1 -C 12 alkyl, C 6 -C 10 aryl or C 7 -C 12 aralkyl or alkaryl groups; R 8 is a saturated or unsaturated alkyl or polyvalent alkylene radical having up to 38 carbon atoms, aralkyl, alkaryl, polyvalent aralkylene or polyvalent alkarylene radical having up to 25 carbon atoms or an aryl or polyvalent arylene radical having up to 18 carbon atoms and Z is an integer equal to the valence of R 8 .

Claim 7

The composition of claim 1 wherein the oxazolidine has the following structural formula: ##STR23## wherein R 1 hydrogen, phenyl, benzyl or C 1 -C 12 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl or R 1 and R 2 are joined with the carbon atom to which they are attached to form a five- or six-membered carbon ring; m is an integer of 2-4; Y is the radical ##STR24## wherein n is 2 or 3 and R 3 and R 4 are the same or different radicals selected from hydrogen, C 1 -C 12 alkyl, C 6 -C 10 aryl or C 7 -C 12 aralkyl or alkaryl; Z is a divalent alkylene, a tri- or tetravelent hydrocarbon radical, a monovalent C 1 -C 18 alkyl, a C 3 -C 12 cycloalkyl, a C 6 -C 12 aryl or a C 7 -C 15 aralkyl or alkaryl; X is the radical ##STR25## wherein m is an integer of 2-4 and R 5 and R 6 are the same or different radicals selected from hydrogen or unsubstituted or substituted C 1 -C 6 alkyl.

Claim 8

The composition of claim 1 wherein the oxazolidine has the following structural formula: ##STR26## wherein R 1 is hydrogen, phenyl, benzyl or C 1 -C 12 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl or R 1 and R 2 are joined together with the carbon atom to which they are attached to form a saturated five- or six-membered carbon ring, and Y is the radical ##STR27## wherein n is 2 or 3 and R 3 and R 4 are the same or different radicals selected from hydrogen, C 1 -C 12 alkyl, (C 6 -C 10 ) aryl or C 7 -C 12 aralkyl or alkaryl; X is the radical ##STR28## wherein q is an integer of 2 to 4 and R 5 and R 6 are the same or different radicals selected from hydrogen or unsubstituted or substituted C 1 -C 6 alkyl; Z' is a saturated, polyvalent alkylene radical having up to 38 carbon atoms, a polyvalent phenylene, a polyvalent halo-substituted phenylene, a C 1 -C 8 alkyl-substituted phenylene, the divalent hydrocarbon residue of 1,1,3-trimethyl-5-carboxy-3-(p-carboxyphenyl)indane, an unsaturated divalent alkenyl radical having 2 or 3 carbon atoms or a O═C<group; A is ##STR29## (the left valence being connected to the Z' radical) or when Z' is ##STR30## then A is --O-- and m' is an integer of at least two and is equal to the valence of Z'.

Claim 9

The composition of claim 1 wherein the oxazolidine is a polymer of an unsaturated oxazolidine of the following structural formula: ##STR31## wherein R 1 is hydrogen, phenyl, benzyl or C 1 -C 12 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl or R 1 and R 2 are joined together with the carbon atom to which they are attached to form a saturated five- or six-membered carbon ring; Y is the radical ##STR32## wherein n is 2 or 3 and R 3 and R 4 are the same or different radicals selected from hydrogen, C 1 -C 12 alkyl, C 6 -C 10 aryl or C 7 -C 12 aralkyl or alkaryl; n' is 1 or 2 and n" is 2 or 3.

Claim 10

The composition of claim 1 wherein the polyanhydride is the reaction product of maleic anhydride and tung oil.

Claim 11

The composition of claim 1 wherein the polyanhydride is the copolymer of maleic anhydride and butyl acrylate.

Claim 12

A process for forming a polymeric material which comprises contacting the composition of claim 1 with water.

Claim 13

A polymeric material formed from the composition of claim 1 and water.

Claim 14

The polymeric material formed from the composition of claim 9 and water.

Claim 15

The polymeric material formed from the composition of claim 10 and water.

Claim 16

An article of manufacture comprising a substrate having a coating of the polymeric material of claim 12.

Claim 17

An article according to claim 15 wherein the substrate is wood, metal, plastic, paper or leather.

Claim 18

A leather having as a topcoat or impregnant the polymeric material of claim 12.

Claim 19

An article of manufacture comprising a substrate having a tacky adhesive layer of the polymeric material of claim 15.