S-Triazine prepolymers and a process for their production

Claim 1

A process for producing an s-triazine prepolymer which comprises condensing an aromatic polyhydroxy compound with 0.01 to less than 1/2 mol of a 4,6-dichloro-s-triazine per hydroxy group of said polyhydroxy compound and subsequently reacting the product of said condensation with a halogen cyanide in the presence of a base, the molar ratio of hydroxy groups to cyanogen halide to base being about 1:1:1, said condensation being carried out in the melt at a temperature of 100° to 250° C. or in solution or suspension in the presence of about 1 mol of base per mol of hydrogen chloride to be eliminated at a temperature of from about 0° to 150° C., said reaction of said condensation product with cyanogen halide in the presence of a base being carried out at a temperature of from -40° to 65° C., each of said bases being selected from the group consisting of tertiary amines, alkali metal hydroxides, alkali metal carbonates and alkali metal alcoholates, said polyhydroxy compound being of the formula ##STR11## wherein a is 1, 2 or 3, b is 5 - a; c is 5 - d; d is 1, 2 or 3 with the proviso that a + d is from 2 to 4 if n is 0 and is 2 to 6 if n is 1; n is 0, 1, 2 or 3; R is hydrogen, halogen, alkyl or phenyl; A is --O--, --SO 2 --, --CO--, ##STR12## a CH 2 chain having up to 6 carbon atoms, a CH 2 chain having up to 6 carbon atoms substituted by lower alkyl, a CH 2 chain having up to 6 carbon atoms substituted by phenyl, a divalent cycloaliphatic or aromatic 5- or 6-membered ring or a single bond and R 1 is the same as R or ##STR13## wherein A and R are as defined above, e is 1, 2 or 3 and f is 5-e and said 4,6-dichloro-s-triazine is of the formula ##STR14## wherein n' is 0 or 1; Z is hydrogen, alkyl or aryl; X is --O--, --S--, --NH-- or --NZ'-- and Z and Z' are alkyl, cycloalkyl or aryl.