US4042529A
Expired / Lapsed
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Composition and method for enhancing dispersibility of water soluble polymers
Assignee: Dow Chemical Co
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Filing: 1974-07-11
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Granted: 1977-08-16
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Expires: 1994-07-11
Abstract
Abstract A water dispersible particulate organic polymer is coated with a polyvinyl lactam-containing polymeric material to provide a particulate material which is readily dispersible in aqueous solutions with a minimum of agglomeration of the water soluble polymer.
Inventors
- 👤 Kenneth H. Nimerick
- 👤 Benny E. Simpson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:23
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; Y; Y10; Y10S; Y10S507/00; Y10S507/904; Y10S507/922; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2998
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
214 words
A water soluble polymeric composition comprising: a particulate mass of a water soluble organic polymer, said water soluble organic polymer being a natural gum, a derivative of a natural gum, a cellulosic derivative, a starch derivative, or a polyacrylamide, of the type which tends to agglomerate when wetted with water but which, once dissolved in an aqueous liquid in an effective amount, thickens said aqueous liquid, the individual particles of which are coated with a water-dispersibility and water-solubility affecting amount of a water soluble copolymer having a molecular weight ranging from about 300 to 2,000,000 containing a. at least about 20 percent by weight polyvinyl lactam units selected from the group consisting of units corresponding to the formula ##STR3## wherein R is an alkylene group containing a sufficient number of carbon atoms to form a heterocyclic ring containing from 5 to 7 members, and R 1 is hydrogen or a lower alkyl group, and b. units of at least one other organic monomer, the polyvinyl lactam units being present in an amount sufficient to increase the dispersibility of the water soluble organic polymer in water, and the nature and proportion of the other organic monomer units being selected so as to modify the rate at which said dispersed organic polymer is dissolved in water.
Claim 2
Dependent Claim
214 words
A water soluble polymeric composition comprising: a particulate mass of a water soluble organic polymer, said water soluble organic polymer being a natural gum, a derivative of a natural gum, a cellulosic derivative, a starch derivative, or a polyacrylamide, of the type which tends to agglomerate when wetted with water but which, once dissolved in an aqueous liquid in an effective amount, thickens said aqueous liquid, the individual particles of which are coated with a water-dispersibility and water-solubility affecting amount of a water soluble copolymer having a molecular weight ranging from about 300 to 2,000,000 containing a. at least about 20 percent by weight polyvinyl lactam units selected from the group consisting of units corresponding to the formula ##STR3## wherein R is an alkylene group containing a sufficient number of carbon atoms to form a heterocyclic ring containing from 5 to 7 members, and R 1 is hydrogen or a lower alkyl group, and b. units of at least one other organic monomer, the polyvinyl lactam units being present in an amount sufficient to increase the dispersibility of the water soluble organic polymer in water, and the nature and proportion of the other organic monomer units being selected so as to modify the rate at which said dispersed organic polymer is dissolved in water.
Claim 3
Dependent Claim
16 words
The composition of claim 1 wherein said molecular weight ranges from about 400 to about 70,000.
Claim 4
Dependent Claim
29 words
The composition of claim 1 wherein the polyvinyl lactam units of the comonomer are selected from the group consisting of polyvinyl pyrrolidone, poly-N-vinyl-5-methyl-2-pyrrolidone, poly-N-vinyl-4-methyl-2-pyrrolidone, poly-N-vinyl-3-methyl-2-pyrrolidone, poly-N-vinyl-ε-caprolactam, poly-N-vinyl-hexahydrophthalamidine, and poly-N-vinyl-3,3-dimethyl-2-pyrrolidone.
Claim 5
Dependent Claim
63 words
The composition of claim 1 wherein the other organic monomer units in the copolymer are selected from the group consisting of acrylonitrile, allyl alcohol, allyl acetate, ethylene, maleic anhydride, methyl methacrylate, vinyl acetate, vinyl chloride, vinyl carbonate, vinyl cyclohexyl ether, vinyl phenyl ether, vinyl stearate, acrylic acid, vinyl laurate, methyl vinyl ether, ethyl vinyl ether, isobutyl vinyl ether, diallyl phthalate and vinyl bromide.
Claim 6
Independent Claim
224 words
A method for rendering particulate water soluble polymers which tend to agglomerate when wetted with water more readily dispersible and controllably soluble in water, said water soluble organic polymer being a natural gum, a derivative of a natural gum, a cellulosic derivative, a starch derivative, or a polyacrylamide, of the type which tends to agglomerate when wetted with water but which, once dissolved in an aqueous liquid in an effective amount, thickens said aqueous liquid, which comprises: coating the individual particles of said water soluble polymer with an effective quantity of a water soluble copolymer having a molecular weight ranging from about 300 to 2,000,000 containing a. at least about 20 percent by weight polyvinyl lactam units selected from the group consisting of units corresponding to the formula ##STR4## wherein R is an alkylene group containing a sufficient number of carbon atoms to form a heterocyclic ring containing from 5 to 7 members, and R 1 is hydrogen or a lower alkyl group, and b. units of at least one other organic monomer, the polyvinyl lactam units being present in an amount sufficient to increase the dispersibility of the water soluble organic polymer in water, and the nature and proportion of the other organic monomer units being selected so as to modify the rate at which said dispersed organic polymer is dissolved in water.
Claim 7
Independent Claim
224 words
A method for rendering particulate water soluble polymers which tend to agglomerate when wetted with water more readily dispersible and controllably soluble in water, said water soluble organic polymer being a natural gum, a derivative of a natural gum, a cellulosic derivative, a starch derivative, or a polyacrylamide, of the type which tends to agglomerate when wetted with water but which, once dissolved in an aqueous liquid in an effective amount, thickens said aqueous liquid, which comprises: coating the individual particles of said water soluble polymer with an effective quantity of a water soluble copolymer having a molecular weight ranging from about 300 to 2,000,000 containing a. at least about 20 percent by weight polyvinyl lactam units selected from the group consisting of units corresponding to the formula ##STR4## wherein R is an alkylene group containing a sufficient number of carbon atoms to form a heterocyclic ring containing from 5 to 7 members, and R 1 is hydrogen or a lower alkyl group, and b. units of at least one other organic monomer, the polyvinyl lactam units being present in an amount sufficient to increase the dispersibility of the water soluble organic polymer in water, and the nature and proportion of the other organic monomer units being selected so as to modify the rate at which said dispersed organic polymer is dissolved in water.
Claim 8
Dependent Claim
16 words
The method of claim 5 wherein said molecular weight ranges from about 400 to about 70,000.
Claim 9
Dependent Claim
29 words
The method of claim 5 wherein the polyvinyl lactam units of the comonomer are selected from the group consisting of polyvinyl pyrrolidone, poly-N-vinyl-5-methyl-2-pyrrolidone, poly-N-vinyl-4-methyl-2-pyrrolidone, poly-N-vinyl-3-methyl-2-pyrrolidone, poly-N-vinyl-ε-caprolactam, poly-N-vinyl-hexahydrophthalamidine, and poly-N-vinyl-3,3-dimethyl-2-pyrrolidone.
Claim 10
Dependent Claim
63 words
The method of claim 5, wherein the other organic monomer units in the copolymer are selected from the group consisting of acrylonitrile, allyl alcohol, allyl acetate, ethylene, maleic anhydride, methyl methacrylate, vinyl acetate, vinyl chloride, vinyl carbonate, vinyl cyclohexyl ether, vinyl phenyl ether, vinyl stearate, acrylic acid, vinyl laurate, methyl vinyl ether, ethyl vinyl ether, isobutyl vinyl ether, diallyl phthalate and vinyl bromide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-15 | 1981-02-14 | 1981-08-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-15 | 1985-02-14 | 1985-08-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-15 | 1989-02-14 | 1989-08-16 | $7700.00 | Window Closed / Lapsed |