Abstract An ophthalmic glass lens having a compressively-stressed surface zone after ion exchanging which is at least 120 microns in depth, formed from an alkali metal oxide silicate glass comprising by weight about 4 to about 15 percent sodium oxide and about 3 to about 15 percent potassium oxide. There is a compressively-stressed surface layer having a strength of at least 25,000 psi. The total amount of sodium, potassium and other alkali metal oxides is up to about 20 percent. The total amount of zinc oxide, lanthanum oxide, magnesium oxide, and calcium oxide is about 8 to 15 percent, and there is about 3 to about 15 percent phosphorus pentoxide. An ion exchange process takes place at a temperature either above or below the strain point of conventional ophthalmic crown glass to produce satisfactory physical properties in the ophthalmic glass lens.
A chemically-strengthened ophthalmic glass lens made from a phospho-silicate glass having the following chemical analysis: ______________________________________
Ingredient Percent by Weight
______________________________________
sodium oxide about 4 to about 15
potassium oxide about 3 to about 15
Other Alkali Metal Oxides:
lithium oxide up to about 5
rubidium oxide up to about 5
cesium oxide up to about 5
lanthanum oxide up to about 15
aluminum oxide up to about 5
zirconium oxide up to about 5
zinc oxide up to about 15
calcium oxide up to about 10
titanium oxide up to about 5
magnesium oxide up to about 4
boron oxide up to about 2
phosphorus pentoxide
about 3 to about 15
Total Na.sub.2 O + K.sub.2 O and
other alkali metal oxides
about 12 to about 20
Total ZnO + La.sub.2 O.sub.3 +
CaO + MgO about 8 to about 15
Total MgO + Al.sub.2 O.sub.3
about 0.2 to about 5
Fining Agents
(antimony oxide, cerium
oxide, arsenic oxide
and mixtures thereof)
up to about 2
silica balance
______________________________________ said lens characterized by an index of refraction in the range of about 1.50 to 1.52 having a minimum depth of penetration of potassium ions of 120 microns and a compressively-stressed surface layer having a strength of at least 25,000 psi.
Claim 2
Dependent Claim
211 words
A chemically-strengthened ophthalmic glass lens made from a phospho-silicate glass having the following chemical analysis: ______________________________________
Ingredient Percent by Weight
______________________________________
sodium oxide about 4 to about 15
potassium oxide about 3 to about 15
Other Alkali Metal Oxides:
lithium oxide up to about 5
rubidium oxide up to about 5
cesium oxide up to about 5
lanthanum oxide up to about 15
aluminum oxide up to about 5
zirconium oxide up to about 5
zinc oxide up to about 15
calcium oxide up to about 10
titanium oxide up to about 5
magnesium oxide up to about 4
boron oxide up to about 2
phosphorus pentoxide
about 3 to about 15
Total Na.sub.2 O + K.sub.2 O and
other alkali metal oxides
about 12 to about 20
Total ZnO + La.sub.2 O.sub.3 +
CaO + MgO about 8 to about 15
Total MgO + Al.sub.2 O.sub.3
about 0.2 to about 5
Fining Agents
(antimony oxide, cerium
oxide, arsenic oxide
and mixtures thereof)
up to about 2
silica balance
______________________________________ said lens characterized by an index of refraction in the range of about 1.50 to 1.52 having a minimum depth of penetration of potassium ions of 120 microns and a compressively-stressed surface layer having a strength of at least 25,000 psi.
Claim 3
Dependent Claim
114 words
A chemically-strengthened ophthalmic glass lens according to claim 1 made from a glass containing the following chemical analysis: ______________________________________
Ingredient Percent by Weight
______________________________________
sodium oxide about 7 to about 10
potassium oxide about 7 to about 11
zinc oxide up to about 15
aluminum oxide about 0.2 to about 4
phosphorus pentoxide
about 3 to about 15
lanthanum oxide up to about 15
Calcium oxide up to about 10
titanium oxide up to about 5
magnesium oxide up to about 4
Total ZnO + CaO + about 8 to about 15
La.sub.2 O.sub.3 + MgO
Fining Agents
(antimony oxide, cerium
oxide, arsenic oxide
and mixtures thereof)
up to about 2
silica balance
______________________________________
Claim 4
Dependent Claim
40 words
The lens of claim 1 wherein said glass comprises by weight 8.8 percent sodium oxide, 9.9 percent potassium oxide, 3.3 percent magnesium oxide, 2.5 percent aluminum oxide, 10.9 percent zinc oxide, and about 3 to about 15 percent phosphorus pentoxide.