US4042374A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Micron sized spherical droplets of metals and method
Assignee: Wisconsin Alumni Research Foundation
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Filing: 1975-03-20
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Granted: 1977-08-16
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Expires: 1995-03-20
Abstract
Abstract The preparation of micron sized spherical particles of metals comprising emulsification of the metal in the molten state in a carrier fluid, preferably in the form of an inert liquid, and reacting the molten metal while in the emulsified state in the fluid to form an insoluble reaction product on the surface which stabilizes metal droplets in the emulsion.
Inventors
- 👤 Don H. Rasmussen
- 👤 Carl R. Loper, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 14:04
CPC Classifications
B; B22; B22F; B22F3/00; B22F3/006; B22F1/00; B22F1/06; B22F1/065; B22F9/00; B22F9/002; B22F9/02; B22F9/06
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
55 words
The method of preparing micron sized spherical droplets of metals comprising the steps of emulsifying the metal in a molten state in an inert carrier fluid and reacting the molten metal while in the emulsified state in the fluid to form a reaction product on the surface which stabilizes the metal droplets in the emulsion.
Claim 2
Independent Claim
55 words
The method of preparing micron sized spherical droplets of metals comprising the steps of emulsifying the metal in a molten state in an inert carrier fluid and reacting the molten metal while in the emulsified state in the fluid to form a reaction product on the surface which stabilizes the metal droplets in the emulsion.
Claim 3
Dependent Claim
53 words
The method as claimed in claim 1 in which emulsification of the metal in the molten stage in the carrier fluid is effected by heating the metal and carrier fluid to a temperature above the melting point temperature for the metal but below the temperature for volatilization or instability of the carrier fluid.
Claim 4
Dependent Claim
23 words
The method as claimed in claim 2 in which the metal and fluid are maintained in an inert atmosphere during heating and emulsification.
Claim 5
Dependent Claim
46 words
The method as claimed in claim 1 in which the carrier fluid has a boiling point above the melting point temperature of the metal and which is stable at said temperature and not reactive with the metal or the reaction product formed on the surface thereof.
Claim 6
Dependent Claim
31 words
The method as claimed in claim 1 in which the metal and carrier fluid are heated to a temperature 20° C. -50° C. above the melting point temperature of the metal.
Claim 7
Dependent Claim
31 words
The method as claimd in claim 1 in which the metal and carrier fluid are heated to a temperature 20° C. -25° C. above the melting point temperature of the metal.
Claim 8
Dependent Claim
38 words
The method as claimed in claim 1 in which the molten metal in the emulsified state in the carrier fluid is reacted with an oxidizing agent to form the reaction product on the surfaces of the metal droplets.
Claim 9
Dependent Claim
38 words
The method as claimed in claim 7 in which the oxidizing agent is oxygen, sulphur or sulphuric acid to form the corresponding metal oxide, sulfide or sulfate as a reaction product on the surfaces of the metal droplets.
Claim 10
Dependent Claim
50 words
The method as claimed in claim 7 in which the oxidizing agent is a salt of a metal which is below the metal to be emulsified in the electromotive series whereby the reaction is by substitution or displacement to form the reaction product on the surfaces of the metal droplets.
Claim 11
Dependent Claim
30 words
The method as claimed in claim 9 in which the metal salt is a salt formed of a metal as the cation and an organic acidic group as the anion.
Claim 12
Dependent Claim
25 words
The method as claimed in claim 10 in which the organic acidic group is selected from the group consisting of isophthalic acid and terephthalic acid.
Claim 13
Dependent Claim
18 words
The method as claimed in claim 7 in which the chemical reaction is one providing a peroxidation reaction.
Claim 14
Dependent Claim
20 words
The method as claimed in claim 12 in which the peroxidizing agent has a half-life of 1/2 to 2 seconds.
Claim 15
Dependent Claim
21 words
The method as claimed in claim 12 in which the peroxidizing agent is employed in the presence of an acid catalyst.
Claim 16
Dependent Claim
18 words
The method as claimed in claim 14 in which the acid catalyst is isophthalic acid or terephthalic acid.
Claim 17
Dependent Claim
28 words
The method as claimed in claim 1 in which the micron sized droplets are of spherical shape having a diameter within the range of 1 to 200 micrometers.
Claim 18
Dependent Claim
27 words
The method as claimed in claim 1 in which emulsion is characterized by a high degree of supercool to enable its use as a heat exchange medium.
Claim 19
Dependent Claim
48 words
The method as claimed in claim 1 in which the emulsion of metal droplets can be heated to a temperature as much as 50° C. above the melting point for the metal and supercooled to a temperature more than 100° C. below the melting point of the metal.
Claim 20
Dependent Claim
55 words
A metal emulsion produced by the method of claim 1 characterized by metal droplets suspended in an inert liquid carrier in which the metal droplets are of spherical shape having a diameter within the range of 1 to 200 micrometers and can be supercooled to a temperature below the melting point temperature of the metal.
Claim 21
Dependent Claim
33 words
A metal emulsion as claimed in claim 19 in which the spherical metal droplets are of micron size having a stabilized reaction product on their surfaces which stabilizes the droplets in the emulsion.
Claim 22
Dependent Claim
25 words
A metal emulsion as claimed in claim 20 in which the metal is selected from the group consisting of tin, lead, bismuth and alloys thereof.
Claim 23
Independent Claim
150 words
A method for processing a material formed of at least two components, at least one of which tends to cluster when the material is reduced to micron sized particles from a molten state, comprising heating the material to a molten state, reducing the molten material to micron sized particles in the presence of a reactant which forms a reaction product on the surfaces of the formed molten micron sized particles to inhibit their agglomeration whereby as a result of non-statistical separation, some of the micron sized particles contain a concentration of one component which is higher than the concentration of that component in the original material, while other micron sized particles contain a concentration of the one component which is less than the concentration in the original material, and then separating the particles in response to physical or chemical properties based upon such differences in concentration of the impurity component.
Claim 24
Independent Claim
150 words
A method for processing a material formed of at least two components, at least one of which tends to cluster when the material is reduced to micron sized particles from a molten state, comprising heating the material to a molten state, reducing the molten material to micron sized particles in the presence of a reactant which forms a reaction product on the surfaces of the formed molten micron sized particles to inhibit their agglomeration whereby as a result of non-statistical separation, some of the micron sized particles contain a concentration of one component which is higher than the concentration of that component in the original material, while other micron sized particles contain a concentration of the one component which is less than the concentration in the original material, and then separating the particles in response to physical or chemical properties based upon such differences in concentration of the impurity component.
Claim 25
Dependent Claim
23 words
The method as claimed in claim 22 which includes the step of cooling the micron sized particles from a molten state before separation.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-15 | 1981-02-14 | 1981-08-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-15 | 1985-02-14 | 1985-08-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-15 | 1989-02-14 | 1989-08-16 | $7700.00 | Window Closed / Lapsed |