US4041220A
Expired / Lapsed
US
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Mixed conductors of graphite, processes for their preparation and their use, notably for the production of electrodes for electrochemical generators, and new electrochemical generators
Assignee: Bpifrance Financement SA
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Filing: 1976-01-28
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Granted: 1977-08-09
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Expires: 1996-01-28
Abstract
Abstract New mixed conductors resulting from the insertion of an alkali element in the lattice of an intercalation compound of graphite and of a product M' y X z : M' is a transition metal such as Ti, V, Cr, Mn, Fe, Mo; X is a non-metallic electronegative atom such as O, S, F, Cl or Br; y and z have the values of the indices in said product M' y X z . These mixed compounds are useful for the manufacture of positive electrodes of electrochemical generators.
Inventors
- 👤 Michel B. Armand
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 16:28
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/36; C; C01; C01B; C01B32/00; C01B32/20; C01B32/21; C01B32/22; H01M4/00; H01M4/02; H01M4/36; H01M4/58; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
209 words
Electrochemical generator comprising a negative electrode containing an alkali metal such as Li, Na, K, Rb or Cs either in the metallic state or in the form of an alloy with another metal, and an electrolyte permitting conduction of ions of said alkali metal, wherein the positive electrode contains a compound M x .sbsb.1 C n (M' y X z ) in which M is the same alkali metal as that of the negative electrode; x 1 is zero or comprised between zero and a value depending on the affinity of the selected alkali metal for the corresponding compound of formula C n (M' y X z ); y and z have values corresponding to the indices defining the relative proportions of the metal and non-metallic atoms respectively in the formula of the corresponding product M' y X z ; n has a value equal to or higher than a minimum value which is a function of the initial binding energy between graphite and the corresponding compound M' y X z , this value not exceeding however that corresponding to the formation of continuous monomolecular graphite layers interposed between the layers of the compound M' y X z in the corresponding compound C n (M' y X z ).
Claim 2
Dependent Claim
209 words
Electrochemical generator comprising a negative electrode containing an alkali metal such as Li, Na, K, Rb or Cs either in the metallic state or in the form of an alloy with another metal, and an electrolyte permitting conduction of ions of said alkali metal, wherein the positive electrode contains a compound M x .sbsb.1 C n (M' y X z ) in which M is the same alkali metal as that of the negative electrode; x 1 is zero or comprised between zero and a value depending on the affinity of the selected alkali metal for the corresponding compound of formula C n (M' y X z ); y and z have values corresponding to the indices defining the relative proportions of the metal and non-metallic atoms respectively in the formula of the corresponding product M' y X z ; n has a value equal to or higher than a minimum value which is a function of the initial binding energy between graphite and the corresponding compound M' y X z , this value not exceeding however that corresponding to the formation of continuous monomolecular graphite layers interposed between the layers of the compound M' y X z in the corresponding compound C n (M' y X z ).
Claim 3
Dependent Claim
37 words
Electrochemical generator according to claim 1, wherein the positive electrode thereof consists of the compound of formula Na x .sbsb.1 C 8 CrO 3 in which x 1 is 0 or a number between 0 and 3.
Claim 4
Dependent Claim
16 words
Electrochemical generator according to claim 2, wherein the electrolyte is solid and formed of beta alumina.
Claim 5
Dependent Claim
21 words
Electrochemical generator according to claim 3, wherein a sodium-mercury amalgam film is interposed between the positive electrode and the solid electrolyte.
Claim 6
Dependent Claim
22 words
Electrochemical generator according to claim 2, wherein a film of polar solvent is interposed between the positive electrode and the solid electrolyte.
Claim 7
Dependent Claim
34 words
Electrochemical generator according to claim 1, wherein the alkali metal used in the electrodes is lithium and the electrolyte is formed of beta alumina containing lithium or of lithium iodide doped with calcium iodide.
Claim 8
Dependent Claim
43 words
Electrochemical generator according to claim 1 wherein the electrolyte is liquid, is not attacked by the alkali metal and contains a salt or complex of said alkali metal capable of liberating it at the interface of the electrolyte and of the positive electrode.
Claim 9
Dependent Claim
29 words
Electrochemical generator according to claim 7 wherein the alkali metal in said electrodes is sodium and the electrolyte is formed of a solution of sodium perchlorate in propylene carbonate.
Claim 10
Dependent Claim
33 words
Electrochemical generator according to claim 7 wherein the alkali metal in said electrodes is lithium and the electrolyte is formed of a solution of lithium-perchlorate in propylene carbonate, dimethylformamide, gamma-butyrolactone, tetramethylenesulfone or dimethylsulfoxide.
Claim 11
Dependent Claim
22 words
Electrochemical generator according to claim 9 wherein the positive electrode makes use of the intercalation compound of graphite and of ferric chloride.
Claim 12
Dependent Claim
53 words
Electrochemical generator according to claim 1 wherein the product M' y X z in the intercalation compound of said positive electrode is selected from the group consisting of FeCl 3 , CuCl 2 , CoCl 3 , CoF 3 , CrO 3 , Sb 2 O 5 , V 2 O 5 .
Claim 13
Dependent Claim
48 words
Electrochemical generator according to claim 1, wherein the product M' y X z of the graphite compound in the positive electrode is formed by a product selected from the group consisting of CrO 2 F 2 , CrF 6 , MnO 3 F, Mn 2 O 7 .
Claim 14
Dependent Claim
30 words
Electrochemical generator according to claim 1 wherein the product M' y X z of the graphite intercalation compound in said positive electrode is formed of the product FeO 4 .
References Cited (Backward Citations)
US3852113A
Cited
US3864167A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-08 | 1981-02-07 | 1981-08-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-08 | 1985-02-07 | 1985-08-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-08 | 1989-02-07 | 1989-08-09 | $7700.00 | Window Closed / Lapsed |