US4039636A
Expired / Lapsed
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Magnesium dialkyl phosphates and their preparation
Assignee: Dow Chemical Co
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Filing: 1973-06-28
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Granted: 1977-08-02
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Expires: 1993-06-28
Abstract
Abstract Magnesium dialkyl phosphates capable of thickening or gelling nonpolar organic solvents are prepared by reacting a dialkyl acid phosphate with a magnesium oxide, hydroxide, or carbonate in organic solvent solution in the presence of a small amount of water within defined limits of time, temperature, mole ratios of reactants, and size of alkyl groups. The products are useful as thickening agents and vapor pressure depressants for nonpolar solvents.
Inventors
- 👤 Kenneth G. Claus
- 👤 Jack A. Rogers
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 07:11
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/08; C07F9/09; C07F9/11
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
96 words
A process for making a magnesium salt of a dialkyl acid phosphate of the formula ##STR2## wherein R is an alkyl radical of about 1-6 carbon atoms, R' is an alkyl radical of about 10-20 carbon atoms, and R and R' together contain about 12-24 carbon atoms, which process comprises reacting magnesium in the form of its oxide, hydroxide, or carbonate with a molar excess of said dialkyl acid phosphate in an inert nonpolar organic solvent at about 100°-190° C. for 1-90 minutes in the presence of about 2-6 moles of water per mole of magnesium.
Claim 2
Dependent Claim
96 words
A process for making a magnesium salt of a dialkyl acid phosphate of the formula ##STR2## wherein R is an alkyl radical of about 1-6 carbon atoms, R' is an alkyl radical of about 10-20 carbon atoms, and R and R' together contain about 12-24 carbon atoms, which process comprises reacting magnesium in the form of its oxide, hydroxide, or carbonate with a molar excess of said dialkyl acid phosphate in an inert nonpolar organic solvent at about 100°-190° C. for 1-90 minutes in the presence of about 2-6 moles of water per mole of magnesium.
Claim 3
Dependent Claim
16 words
The process of claim 1 wherein the solvent is a normally liquid hydrocarbon or chlorinated hydrocarbon.
Claim 4
Dependent Claim
18 words
The process of claim 1 wherein the temperature is 120°-150° C. and the reaction time is 5-30 minutes.
Claim 5
Dependent Claim
11 words
The magnesium dialkyl phosphate product of the process of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-01 | 1981-01-31 | 1981-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-01 | 1985-01-31 | 1985-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-01 | 1989-01-31 | 1989-08-02 | $7700.00 | Window Closed / Lapsed |