US4039622A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Catalytic process for NOX reduction under lean conditions
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-09-19
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Granted: 1977-08-02
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Expires: 1995-09-19
Abstract
Abstract It has been discovered that supported iridium catalysts will selectively reduce NOX under lean conditions in a critical temperature range.
Inventors
- 👤 Lawrence L. Murrell
- 👤 Samuel J. Tauster
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 09:56
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
165 words
A process for effecting the selective reduction of NO x in lean effluent waste streams containing NO x , CO, O 2 , H 2 , CO 2 and water, wherein the concentration of CO is at least equivalent to the concentration of NO x present in the waste stream, a lean effluent waste stream being defined as one in which the concentration of oxygen is in excess over the concentration of reductants to a level as high as 8%, i.e., about 800% excess oxygen, over the total of reductants present, said reductants being selected from the group comprising CO and H 2 so that when such a waste stream is reacted to completion, the residuum is oxidizing in character, said process comprising the steps of contacting said lean exhaust stream in a reaction zone with an iridium catalyst, said contacting occurring at a temperature between 300° to 750° C. thereby effecting the selective reduction by CO of the oxides of nitrogen to molecular nitrogen.
Claim 2
Dependent Claim
165 words
A process for effecting the selective reduction of NO x in lean effluent waste streams containing NO x , CO, O 2 , H 2 , CO 2 and water, wherein the concentration of CO is at least equivalent to the concentration of NO x present in the waste stream, a lean effluent waste stream being defined as one in which the concentration of oxygen is in excess over the concentration of reductants to a level as high as 8%, i.e., about 800% excess oxygen, over the total of reductants present, said reductants being selected from the group comprising CO and H 2 so that when such a waste stream is reacted to completion, the residuum is oxidizing in character, said process comprising the steps of contacting said lean exhaust stream in a reaction zone with an iridium catalyst, said contacting occurring at a temperature between 300° to 750° C. thereby effecting the selective reduction by CO of the oxides of nitrogen to molecular nitrogen.
Claim 3
Dependent Claim
19 words
A process according to claim 1 wherein the iridium is present at a concentration of from 0.0001 to 5.0%.
Claim 4
Dependent Claim
19 words
A process according to claim 1 wherein the iridium is present at a concentration of from 0.001 to 1.0%.
Claim 5
Dependent Claim
19 words
A process according to claim 1 wherein the iridium is present at a concentration of from 0.01 to 0.1%.
Claim 6
Dependent Claim
16 words
A process according to claim 1 wherein the contact temperature is between 350° to 600° C.
Claim 7
Dependent Claim
18 words
A process according to claim 1 further characterized by having the iridium catalyst deposited on a support medium.
Claim 8
Dependent Claim
21 words
A process according to claim 6 wherein the support material is selected from the group consisting of inert inorganic refractory oxides.
Claim 9
Dependent Claim
19 words
A process according to claim 6 wherein the support material is in the form of pellets, granules or powder.
Claim 10
Dependent Claim
13 words
A process according to claim 6 wherein the preferred support material is alumina.
Claim 11
Dependent Claim
23 words
A process according to claim 1, wherein the lean effluent exhaust waste stream is the waste or stack gases from industrial process plants.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-01 | 1981-01-31 | 1981-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-01 | 1985-01-31 | 1985-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-01 | 1989-01-31 | 1989-08-02 | $7700.00 | Window Closed / Lapsed |