US4039474A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silica-alumina catalysts
Assignee: CROSFIELD CHEMICALS COMPANY A DIVISION OF INDOPCO Inc A CORP OF DELAWARE
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Filing: 1975-10-20
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Granted: 1977-08-02
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Expires: 1995-10-20
Abstract
Abstract Porous silica-alumina products useful in catalysis are prepared by adding excess alkali to a body of water glass, the excess alkali is responsible for rendering the product extrudable and for increasing the pore diameter.
Inventors
- 👤 Gerald R. Feistel
- 👤 George N. Pessimisis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:08
CPC Classifications
B; B01; B01J; B01J21/00; B01J21/12; B01J37/00; B01J37/0009
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
136 words
In a process where porous microspherical silica-alumina particles useful in catalysis are prepared by initially adding a mineral acid to a body of aqueous sodium silicate starting material initially to precipitate silica in hydrous form, followed by addition of an aluminate salt to precipitate hydrous alumina on the silica, after which the product is filtered, purified and dried: the improvement characterized by said body of aqueous sodium silicate starting material, before acid is added, being treated with Na 2 O so that the alkali, expressed as Na 2 O in the starting material, is substantially in excess of that required to form water glass and in an amount sufficient to produce pores of an appreciably larger diameter compared to pore size distribution when the body of sodium silicate is in water glass proportion without excess alkali.
Claim 2
Dependent Claim
136 words
In a process where porous microspherical silica-alumina particles useful in catalysis are prepared by initially adding a mineral acid to a body of aqueous sodium silicate starting material initially to precipitate silica in hydrous form, followed by addition of an aluminate salt to precipitate hydrous alumina on the silica, after which the product is filtered, purified and dried: the improvement characterized by said body of aqueous sodium silicate starting material, before acid is added, being treated with Na 2 O so that the alkali, expressed as Na 2 O in the starting material, is substantially in excess of that required to form water glass and in an amount sufficient to produce pores of an appreciably larger diameter compared to pore size distribution when the body of sodium silicate is in water glass proportion without excess alkali.
Claim 3
Dependent Claim
38 words
A process according to claim 1 further characterized by the steps of adding water to the purified, dried particles to obtain an extrudable mixture; and afterwards extruding and calcining the mixture to afford the desired catalyst support bodies.
Claim 4
Dependent Claim
23 words
A process according to claim 1 in which excess alkalinity is achieved by addition of sodium hydroxide or sodium carbonate to water glass.
References Cited (Backward Citations)
US2462236A
Cited
US2477373A
Cited
US2933456A
Cited
US2839475A
Cited
US3079234A
Cited
US3403109A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-01 | 1981-01-31 | 1981-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-01 | 1985-01-31 | 1985-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-01 | 1989-01-31 | 1989-08-02 | $7700.00 | Window Closed / Lapsed |