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US4039467A Expired / Lapsed US ⏱️ 0.0 years remaining

Visibly opaque infrared transmitting optical filter containing a combination of copper and vanadyl phthalocyanine sulfonamides

Assignee: Honeywell Safety Products Sweden AB
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Filing: 1975-06-16
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Granted: 1977-08-02
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Expires: 1995-06-16
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Abstract

Abstract Optical filters comprised of a plastic film having incorporated therein a mixture of dyes including defined amounts of a copper phthalocyanine sulfonamide compound and a vanadyl phthalocyanine sulfonamide compound are substantially opaque to visible light but permit a high transmission of radiation in the near infrared region.

Inventors

  • 👤 Robert Jerome Tucker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 00:24
CPC Classifications
F; F21; F21V; F21V9/00; F21V9/04; G; G02; G02B; G02B5/00; G02B5/20; G02B5/22; G02B5/223

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 288 words
An optical filter which is substantially opaque to visible light but which is transparent to light in the near infrared region comprising a plastic substrate having substantially uniformly dispersed therein, a copper phthalocyanine sulfonamide compound having the formula: ##STR3## wherein Pc is the phthalocyanine moiety, R 1 and R 2 are alkyl groups containing from 1 to 4 carbon atoms or R 1 is hydrogen and R 2 is an alkyl group containing from 4 to 20 carbon atoms; X is a number from 1 to 4, provided that not more than 1 sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; a vanadyl phthalocyanine sulfonamide compound having the formula: ##STR4## wherein Pc is the phthalocyanine moiety and R 3 and R 4 are alkyl groups containing from 1 to 4 carbon atoms or R 3 is hydrogen and R 4 is an alkyl group containing from 4 to 20 carbon atoms and X is a number from 1 to 4, provided that not more than one sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; and an auxiliary organic dye compound capable of absorbing visible light but which does not absorb in the near infrared; said copper phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.02 to about 6.13 and said vanadyl phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.01 to 0.3.
Claim 2
Dependent Claim 288 words
An optical filter which is substantially opaque to visible light but which is transparent to light in the near infrared region comprising a plastic substrate having substantially uniformly dispersed therein, a copper phthalocyanine sulfonamide compound having the formula: ##STR3## wherein Pc is the phthalocyanine moiety, R 1 and R 2 are alkyl groups containing from 1 to 4 carbon atoms or R 1 is hydrogen and R 2 is an alkyl group containing from 4 to 20 carbon atoms; X is a number from 1 to 4, provided that not more than 1 sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; a vanadyl phthalocyanine sulfonamide compound having the formula: ##STR4## wherein Pc is the phthalocyanine moiety and R 3 and R 4 are alkyl groups containing from 1 to 4 carbon atoms or R 3 is hydrogen and R 4 is an alkyl group containing from 4 to 20 carbon atoms and X is a number from 1 to 4, provided that not more than one sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; and an auxiliary organic dye compound capable of absorbing visible light but which does not absorb in the near infrared; said copper phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.02 to about 6.13 and said vanadyl phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.01 to 0.3.
Claim 3
Dependent Claim 23 words
An optical filter according to claim 1 wherein in R 1 , R 2 and R 3 and R 4 are each n-butyl.
Claim 4
Dependent Claim 21 words
An optical filter according to claim 1 wherein R 2 is n-octadecyl and R 3 and R 4 are each n-butyl.
Claim 5
Dependent Claim 16 words
An optical filter according to claim 1 wherein R 2 and R 4 are each n-octadecyl.
Claim 6
Dependent Claim 22 words
An optical filter according to claim 1 wherein the plastic substrate is a copolymer of 97% vinyl chloride and 3% vinyl acetate.

References Cited (Backward Citations)

US2300572A Cited
US3291746A Cited
US3853783A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-01 1981-01-31 1981-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-01 1985-01-31 1985-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-01 1989-01-31 1989-08-02 $7700.00 Window Closed / Lapsed

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