US4039467A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Visibly opaque infrared transmitting optical filter containing a combination of copper and vanadyl phthalocyanine sulfonamides
Assignee: Honeywell Safety Products Sweden AB
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Filing: 1975-06-16
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Granted: 1977-08-02
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Expires: 1995-06-16
Abstract
Abstract Optical filters comprised of a plastic film having incorporated therein a mixture of dyes including defined amounts of a copper phthalocyanine sulfonamide compound and a vanadyl phthalocyanine sulfonamide compound are substantially opaque to visible light but permit a high transmission of radiation in the near infrared region.
Inventors
- 👤 Robert Jerome Tucker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 00:24
CPC Classifications
F; F21; F21V; F21V9/00; F21V9/04; G; G02; G02B; G02B5/00; G02B5/20; G02B5/22; G02B5/223
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
288 words
An optical filter which is substantially opaque to visible light but which is transparent to light in the near infrared region comprising a plastic substrate having substantially uniformly dispersed therein, a copper phthalocyanine sulfonamide compound having the formula: ##STR3## wherein Pc is the phthalocyanine moiety, R 1 and R 2 are alkyl groups containing from 1 to 4 carbon atoms or R 1 is hydrogen and R 2 is an alkyl group containing from 4 to 20 carbon atoms; X is a number from 1 to 4, provided that not more than 1 sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; a vanadyl phthalocyanine sulfonamide compound having the formula: ##STR4## wherein Pc is the phthalocyanine moiety and R 3 and R 4 are alkyl groups containing from 1 to 4 carbon atoms or R 3 is hydrogen and R 4 is an alkyl group containing from 4 to 20 carbon atoms and X is a number from 1 to 4, provided that not more than one sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; and an auxiliary organic dye compound capable of absorbing visible light but which does not absorb in the near infrared; said copper phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.02 to about 6.13 and said vanadyl phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.01 to 0.3.
Claim 2
Dependent Claim
288 words
An optical filter which is substantially opaque to visible light but which is transparent to light in the near infrared region comprising a plastic substrate having substantially uniformly dispersed therein, a copper phthalocyanine sulfonamide compound having the formula: ##STR3## wherein Pc is the phthalocyanine moiety, R 1 and R 2 are alkyl groups containing from 1 to 4 carbon atoms or R 1 is hydrogen and R 2 is an alkyl group containing from 4 to 20 carbon atoms; X is a number from 1 to 4, provided that not more than 1 sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; a vanadyl phthalocyanine sulfonamide compound having the formula: ##STR4## wherein Pc is the phthalocyanine moiety and R 3 and R 4 are alkyl groups containing from 1 to 4 carbon atoms or R 3 is hydrogen and R 4 is an alkyl group containing from 4 to 20 carbon atoms and X is a number from 1 to 4, provided that not more than one sulfonamide group is present on any single phenyl ring of the phthalocyanine moiety; and an auxiliary organic dye compound capable of absorbing visible light but which does not absorb in the near infrared; said copper phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.02 to about 6.13 and said vanadyl phthalocyanine sulfonamide compound being present in the substrate in a weight percent concentration such that said concentration multiplied by the thickness of the substrate in mils is a constant falling within the range of from about 0.01 to 0.3.
Claim 3
Dependent Claim
23 words
An optical filter according to claim 1 wherein in R 1 , R 2 and R 3 and R 4 are each n-butyl.
Claim 4
Dependent Claim
21 words
An optical filter according to claim 1 wherein R 2 is n-octadecyl and R 3 and R 4 are each n-butyl.
Claim 5
Dependent Claim
16 words
An optical filter according to claim 1 wherein R 2 and R 4 are each n-octadecyl.
Claim 6
Dependent Claim
22 words
An optical filter according to claim 1 wherein the plastic substrate is a copolymer of 97% vinyl chloride and 3% vinyl acetate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-01 | 1981-01-31 | 1981-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-01 | 1985-01-31 | 1985-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-01 | 1989-01-31 | 1989-08-02 | $7700.00 | Window Closed / Lapsed |