US4038481A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for treatment of corn hulls
Assignee: Standard Brands Inc
•
Filing: 1976-05-24
•
Granted: 1977-07-26
•
Expires: 1996-05-24
Abstract
Abstract Corn hulls are subjected to a treatment to obtain three fractions therefrom comprising a cellulosic fraction, a hemicellulose fraction and a noncarbohydrate fraction. The noncarbohydrate fraction is characterized as being an organic solvent extract comprising at least about 15 percent of the dry weight of the corn hulls and containing above about 10 percent by weight ferulic acid.
Inventors
- 👤 Richard Lee Antrim
- 👤 Donald Wayne Harris
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 06:24
CPC Classifications
D; D21; D21C; D21C5/00; B; B01; B01D; B01D11/00; B01D11/02; B01D11/0288; C; C08; C08B; C08B1/00; C08B37/00; C08B37/0006; C08B37/0057
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
74 words
A method for treating corn hulls to obtain a cellulose fraction, a hemicellulose fraction and a noncarbohydrate fraction comprising treating corn hulls with a sufficient amount of alkali to hydrolyze the corn hulls to affect liberation of the hemicellulose fraction so that it may be solubilized in water and to solubilize the noncarbohydrate fraction, recovering a hemicellulose fraction, an organic solvent extract of the noncarbohydrate fraction and an insoluble residue comprising the cellulose fraction.
Claim 2
Independent Claim
74 words
A method for treating corn hulls to obtain a cellulose fraction, a hemicellulose fraction and a noncarbohydrate fraction comprising treating corn hulls with a sufficient amount of alkali to hydrolyze the corn hulls to affect liberation of the hemicellulose fraction so that it may be solubilized in water and to solubilize the noncarbohydrate fraction, recovering a hemicellulose fraction, an organic solvent extract of the noncarbohydrate fraction and an insoluble residue comprising the cellulose fraction.
Claim 3
Dependent Claim
53 words
A method for treating corn hulls as defined in claim 1, wherein the treatment is performed under conditions to obtain an amount of the noncarbohydrate fraction comprising at least about 15 percent by weight of the dry weight of the corn hulls, said fraction containing above about 10 percent by weight ferulic acid.
Claim 4
Dependent Claim
59 words
A method for treating corn hulls as defined in claim 2, wherein the treatment is performed under conditions to obtain an amount of the noncarbohydrate fraction comprising at from about 20 percent to 30 percent by weight of the dry weight of the corn hulls, said fraction containing from about 10 to about 20 percent by weight ferulic acid.
Claim 5
Dependent Claim
57 words
A method for treating corn hulls as defined in claim 2, wherein the corn hulls are subjected to an aqueous alkaline hydrolysis treatment to solubilize the noncarbohydrate and hemicellulose fractions, contacting the resulting solution with a sufficient amount of a water miscible organic solvent to precipitate the hemicellulose and recovering the noncarbohydrate fraction from the organic solvent.
Claim 6
Dependent Claim
74 words
A method for treating corn hulls as defined in claim 2, wherein the corn hulls are subjected to an alkaline hydrolysis treatment to dissolve the noncarbohydrate fraction and to liberate the hemicellulose fraction so that it may be solubilized in water, contacting the alkaline hydrolysis reaction product with a water miscible organic solvent to extract the noncarbohydrate fraction and treating the insoluble residue with water to separate the hemicellulose fraction from the cellulose fraction.
Claim 7
Dependent Claim
56 words
A method for treating corn hulls as defined in claim 2, wherein the corn hulls are contacted with an alkaline aqueous-miscible organic solvent system which contains insufficient water to substantially solubilize the hemicellulose fraction and thereby extracting the noncarbohydrate fraction and treating the insoluble residue with water to separate the hemicellulose fraction from the cellulose fraction.
Claim 8
Dependent Claim
29 words
A method for treating corn hulls as defined in claim 6, wherein the alkaline hydrolysis treatment is performed at a temperature of from about ambient to about 140° C.
Claim 9
Dependent Claim
29 words
A method for treating corn hulls as defined in claim 7, wherein the alkaline hydrolysis treatment is performed at a temperature of from about ambient to about 100° C.
Claim 10
Dependent Claim
28 words
A method for treating corn hulls as defined in claim 6, wherein the resulting solution is contacted with a water miscible solvent having a pH below about 4.
Claim 11
Dependent Claim
28 words
A method for treating corn hulls as defined in claim 9, wherein the alkaline aqueous miscible organic solvent containing solubilized noncarbohydrate fraction has a pH below about 3.
References Cited (Backward Citations)
US1856567A
Cited
US1819233A
Cited
US2037001A
Cited
US2166540A
Cited
US2218567A
Cited
US2615883A
Cited
US2526607A
Cited
US2709699A
Cited
US2868778A
Cited
US2801955A
Cited
US3579380A
Cited
US3716526A
Cited
US3879373A
Cited
DE2365457A1
Cited
DE2358472A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-25 | 1981-01-24 | 1981-07-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-25 | 1985-01-24 | 1985-07-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-25 | 1989-01-24 | 1989-07-26 | $7700.00 | Window Closed / Lapsed |