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US4038280A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydroxyaryl-tetramethyl-piperidines

Assignee: Novartis Corp
•
Filing: 1972-11-28
•
Granted: 1977-07-26
•
Expires: 1992-11-28
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Abstract

Abstract New 4-(4'-hydroxyaryl)-2,2,6,6-tetramethyl-piperidines are used as stabilisers for organic materials, especially for polymers.

Inventors

  • 👤 Donald Richard Randell
  • 👤 Malcolm John Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 04:27
CPC Classifications
C; C07; C07D; C07D211/00; C07D211/92; C07D211/94; C07D211/02; C07D211/04; C07D211/06; C07D211/08; C07D211/18; C07D211/20; C07D211/22; C07D211/68; C07D211/70; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C09; C09K; C09K15/00; C09K15/04; C09K15/30

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 270 words
A compound of the formula I ##STR20## or a salt thereof, wherein the substituent X has one of the formulae ##STR21## wherein R 1 , R 2 , R 3 and R 4 are the same or different and each is hydrogen, a straight- or branched-chain alkyl residue having from 1 to 9 carbon atoms, a cycloalkyl residue having from 5 to 14 carbon atoms, an aralkyl residue having from 7 to 14 carbon atoms or an aryl or alkaryl residue having from 6 to 14 carbon atoms, Y is hydrogen, O, a straight- or branched-chain alkyl residue having from 1 to 12 carbon atoms, an alkenyl or alkynyl residue having from 3 to 12 carbon atoms or an aralkyl residue having from 7 to 12 carbon atoms. Z is hydrogen, an alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 2 to 20 carbon atoms, a cycloaliphatic residue having from 5 to 12 carbon atoms, an araliphatic residue having from 7 to 12 carbon atoms, an aromatic residue having from 6 to 12 carbon atoms or a β-hydroxyethyl, β-cyanoethyl, furan or thiophene residue or the group --COZ 1 wherein Z 1 has the same significance as Z, or Z 1 is a group having the formula --NR 5 R 6 wherein R 5 is hydrogen or an alkyl residue having from 1 to 4 carbon atoms, and R 6 is hydrogen, an aliphatic residue having from 1 to 20 carbon atoms, a cycloaliphatic residue having from 5 to 12 carbon atoms or an aromatic residue having from 6 to 12 carbon atoms.
Claim 2
Dependent Claim 270 words
A compound of the formula I ##STR20## or a salt thereof, wherein the substituent X has one of the formulae ##STR21## wherein R 1 , R 2 , R 3 and R 4 are the same or different and each is hydrogen, a straight- or branched-chain alkyl residue having from 1 to 9 carbon atoms, a cycloalkyl residue having from 5 to 14 carbon atoms, an aralkyl residue having from 7 to 14 carbon atoms or an aryl or alkaryl residue having from 6 to 14 carbon atoms, Y is hydrogen, O, a straight- or branched-chain alkyl residue having from 1 to 12 carbon atoms, an alkenyl or alkynyl residue having from 3 to 12 carbon atoms or an aralkyl residue having from 7 to 12 carbon atoms. Z is hydrogen, an alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 2 to 20 carbon atoms, a cycloaliphatic residue having from 5 to 12 carbon atoms, an araliphatic residue having from 7 to 12 carbon atoms, an aromatic residue having from 6 to 12 carbon atoms or a β-hydroxyethyl, β-cyanoethyl, furan or thiophene residue or the group --COZ 1 wherein Z 1 has the same significance as Z, or Z 1 is a group having the formula --NR 5 R 6 wherein R 5 is hydrogen or an alkyl residue having from 1 to 4 carbon atoms, and R 6 is hydrogen, an aliphatic residue having from 1 to 20 carbon atoms, a cycloaliphatic residue having from 5 to 12 carbon atoms or an aromatic residue having from 6 to 12 carbon atoms.
Claim 3
Dependent Claim 59 words
A compound according to claim 1 wherein X has the formula II and Z is hydrogen, an alkyl residue having from 1 to 12 carbon atoms, an allyl or methallyl residue a cyclopentyl or cyclohexyl residue, a benzyl α,α-dimethylbenzyl or α-methyl benzyl residue, a phenyl, tolyl, naphthyl or p-t-butyl phenyl residue, or a furan β-hydroxyethyl, β-cyanoethyl, or thiophene residue.
Claim 4
Dependent Claim 54 words
A compound according to claim 1 having the formula ##STR22## wherein R 1 and R 4 are selected from hydrogen, methyl, ethyl, n-propyl, isopropyl, sec-butyl, t-butyl, 1,1-dimethylpropyl, 1,1-dimethylbutyl, 2-octyl, cyclohexyl, 1-methylcyclohexyl, benzyl, α,α-dimethylbenzyl and phenyl residues, R 2 and R 3 are hydrogen, methyl or ethyl groups and Y is hydrogen, O or methyl.
Claim 5
Dependent Claim 9 words
A compound according to claim 1 which is 4-(4'-hydroxyphenyl-2,2,6,6-tetramethylpiperidine.
Claim 6
Dependent Claim 9 words
A compound according to claim 1 which is 4-(3'-methyl-4'-hydroxyphenyl)-2,2,6,6-tetramethylpiperidine.
Claim 7
Dependent Claim 9 words
A compound according to claim 1 which is 4-(3'-t-butyl-4'-hydroxyphenyl)-2,2,2,6-tetramethyl-piperidine.
Claim 8
Dependent Claim 9 words
A compound according to claim 1 which is 4-(3',5'-di-isopropyl-4'-hydroxyphenyl)-2,2,6,6-tetramethylpiperidine.
Claim 9
Dependent Claim 9 words
A compound according to claim 1 which is 4-(3',5'-dimethyl-4'-hydroxyphenyl)-2,2,6,6-tetramethylpiperidine.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-25 1981-01-24 1981-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-25 1985-01-24 1985-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-25 1989-01-24 1989-07-26 $7700.00 Window Closed / Lapsed

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