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US4038078A Expired / Lapsed US ⏱️ 0.0 years remaining

Process using suction to form relief images

Assignee: Nippon Paint Co Ltd
•
Filing: 1975-07-28
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Granted: 1977-07-26
•
Expires: 1995-07-28
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Abstract

Abstract A process for formation of a relief image which comprises exposing a layer of a photosensitive composition in liquid provided on the surface of a support material to light through a negative to make cured the photosensitive composition at the exposed part and eliminating the non-cured photosensitive composition at the non-exposed part by suctioning for development, the photosensitive composition comprising as the essential components only (1) at least one addition polymerizable unsaturated monomer having at least one acryloyl or methacryloyl group per each molecule and a molecular weight of not more than about 1000 per each acryloyl or methacryloyl group and (2) at least one photopolymerization initiator.

Inventors

  • 👤 Kiyomi Sakurai
  • 👤 Yasuyuki Takimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 08:21
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/116

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 201 words
A process for formation of a relief image which comprises exposing a portion of a layer of a photosensitive composition provided on the surface of a support material to light through a negative to cure the exposed portion of the photosensitive composition and thereafter developing the image by eliminating the unexposed uncured photosensitive composition by suction, the photosensitive composition being a liquid composition containing no unsaturated polymeric material and having at least one addition polymerizable unsaturated monomer selected from the group consisting of C 7 -C 20 alkyl acrylates and methacrylates, poly(C 2 -C 3 ) alkylene glycol diacrylates and dimethacrylates having 9 to 14 alkylene glycol units, C 1 -C 3 alkoxypoly(C 2 -C 3 ) alkylene glycol acrylates and methacrylates having 9 to 14 alkylene glycol units, hydroxy (C 2 -C 3 ) alkyl acrylates and methacrylates, monoacryloyloxy (C 2 -C 3 ) alkyl and monomethacryloyloxy(C 2 -C 3 ) alkyl phthalates, and hydroxy(C 2 -C 3 ) alkyl acryloyloxy(C 2 -C 3 ) alkyl and methacryloyloxy(C 2 -C 3 )alkyl phthalates and at least one photopolymerization initiator, the initiator being present in an amount effective to photopolymerize the unsatuated monomer when the photosensitive composition is exposed to light.
Claim 2
Dependent Claim 201 words
A process for formation of a relief image which comprises exposing a portion of a layer of a photosensitive composition provided on the surface of a support material to light through a negative to cure the exposed portion of the photosensitive composition and thereafter developing the image by eliminating the unexposed uncured photosensitive composition by suction, the photosensitive composition being a liquid composition containing no unsaturated polymeric material and having at least one addition polymerizable unsaturated monomer selected from the group consisting of C 7 -C 20 alkyl acrylates and methacrylates, poly(C 2 -C 3 ) alkylene glycol diacrylates and dimethacrylates having 9 to 14 alkylene glycol units, C 1 -C 3 alkoxypoly(C 2 -C 3 ) alkylene glycol acrylates and methacrylates having 9 to 14 alkylene glycol units, hydroxy (C 2 -C 3 ) alkyl acrylates and methacrylates, monoacryloyloxy (C 2 -C 3 ) alkyl and monomethacryloyloxy(C 2 -C 3 ) alkyl phthalates, and hydroxy(C 2 -C 3 ) alkyl acryloyloxy(C 2 -C 3 ) alkyl and methacryloyloxy(C 2 -C 3 )alkyl phthalates and at least one photopolymerization initiator, the initiator being present in an amount effective to photopolymerize the unsatuated monomer when the photosensitive composition is exposed to light.
Claim 3
Dependent Claim 37 words
The process according to claim 1, wherein the amount of the photopolymerization initiator in the photosensitive composition is from about 0.1 to 10 parts by weight per 100 parts by weight of the addition polymerizable unsaturated monomer.
Claim 4
Dependent Claim 37 words
The process according to claim 1, wherein the amount of the photopolymerization initiator in the photosensitive composition is from about 0.5 to 5 parts by weight per 100 parts by weight of the addition polymerizable unsaturated monomer.
Claim 5
Dependent Claim 52 words
The process according to claim 1, wherein the addition polymerizable unsaturated monomer in the photosensitive composition is monoacryloyloxy(C 2 -C 3 )alkyl phthalate, monomethacryloyloxy(C 2 -C 3 )alkyl phthalate, hydroxy(C 2 -C 3 )alkyl acryloyloxy(C 2 -C 3 )alkyl phthalate or hydroxy(C 2 -C 3 )alkyl methacryloyloxy(C 2 -C 3 )alkyl phthalate.
Claim 6
Dependent Claim 20 words
The process according to claim 1, wherein the photopolymerization initiator in the photosensitive composition is benzoins, acetophenones or azo compounds.
Claim 7
Dependent Claim 24 words
The process according to claim 5, wherein the photopolymerization initiator in the photosensitive composition is benzoin or its C 1 -C 10 alkyl ether.
Claim 8
Dependent Claim 45 words
The process according to claim 1, wherein the photosensitive composition also includes a plasticizer in an amount of not more than about 50 parts by weight per 100 parts by weight of the combined amount of the addition polymerizable unsaturated monomer and the photopolymerization initiator.
Claim 9
Dependent Claim 35 words
The process according to claim 1, wherein the photosensitive composition also includes an organic amine in an amount of about 0.1 to 5 parts by weight to 1 part by weight of the photopolymerization initiator.

References Cited (Backward Citations)

US3801328A Cited
US3782961A Cited
US3801638A Cited
US3806365A Cited
US3926640A Cited
US3901705A Cited
US3926643A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-25 1981-01-24 1981-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-25 1985-01-24 1985-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-25 1989-01-24 1989-07-26 $7700.00 Window Closed / Lapsed

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