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US4037172A Expired / Lapsed US ⏱️ 0.0 years remaining

Plastic laser materials

Assignee: Trane US Inc
•
Filing: 1963-09-17
•
Granted: 1977-07-19
•
Expires: 1983-09-17
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Abstract

Abstract A material exhibiting narrow line fluorescence when excited by high energy radiation, hence suitable for laser applications, is formed by dispersion of rare earth ions bonded to organic molecules in the form of an organometallic chelate, in solid solution in a plastic host.

Inventors

  • 👤 Nicolae Filipescu
  • 👤 Nelson McAvoy
  • 👤 Morton R. Kagan
  • 👤 Francis A. Serafin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 08:16
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/14; H01S3/16; H01S3/168; H01S3/17

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 18 words
An optical maser material comprising a solid polymeric matrix having uniformly distributed therein a rare earth metal chelate.
Claim 2
Dependent Claim 18 words
An optical maser material comprising a solid polymeric matrix having uniformly distributed therein a rare earth metal chelate.
Claim 3
Dependent Claim 23 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate.
Claim 4
Dependent Claim 23 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate.
Claim 5
Dependent Claim 26 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a beta-diketone.
Claim 6
Dependent Claim 26 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a beta-diketone.
Claim 7
Dependent Claim 26 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a hydroxyaldehyde.
Claim 8
Dependent Claim 26 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a hydroxyaldehyde.
Claim 9
Dependent Claim 27 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a hydroxycarboxylic acid.
Claim 10
Dependent Claim 27 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a hydroxycarboxylic acid.
Claim 11
Dependent Claim 40 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a member selected from the group consisting of 8-hydroxyquinoline and its alkyl, aryl, and halo-substituted derivatives.
Claim 12
Dependent Claim 40 words
An optical maser material comprising a solid polymerized ethylenically unsaturated monomer having uniformly distributed therein in solid solution a rare earth metal chelate of a member selected from the group consisting of 8-hydroxyquinoline and its alkyl, aryl, and halo-substituted derivatives.
Claim 13
Dependent Claim 18 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein in solid solution a rare earth metal chelate.
Claim 14
Dependent Claim 18 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein in solid solution a rare earth metal chelate.
Claim 15
Dependent Claim 13 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein a europium chelate.
Claim 16
Dependent Claim 13 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein a europium chelate.
Claim 17
Dependent Claim 13 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein europium tris-(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione chelate.
Claim 18
Dependent Claim 13 words
An optical maser material comprising polymethylmethacrylate having uniformly distributed therein europium tris-(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione chelate.
Claim 19
Dependent Claim 27 words
The maser material of claim 9 in which the concentration of europium ion in the polymer is between about 10 17 and 10 20 ions per cc.
Claim 20
Dependent Claim 21 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate.
Claim 21
Dependent Claim 21 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate.
Claim 22
Dependent Claim 24 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a beta-diketone.
Claim 23
Dependent Claim 24 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a beta-diketone.
Claim 24
Dependent Claim 24 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a hydroxyaldehyde.
Claim 25
Dependent Claim 24 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a hydroxyaldehyde.
Claim 26
Dependent Claim 25 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a hydroxycarboxylic acid.
Claim 27
Dependent Claim 25 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a hydroxycarboxylic acid.
Claim 28
Dependent Claim 38 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a member selected from the group consisting of 8-hydroxyquinoline and its alkyl, aryl, and halo-substituted derivatives.
Claim 29
Dependent Claim 38 words
An optical maser material comprising a polymerized ethylenically unsaturated monomer having distributed therein in solid solution a rare earth metal chelate of a member selected from the group consisting of 8-hydroxyquinoline and its alkyl, aryl, and halo-substituted derivatives.
Claim 30
Dependent Claim 25 words
A material exhibiting narrow-line fluorescence when excited by a high energy light source, comprising an europium chelate dispersed in solid solution in a plastic host.
Claim 31
Dependent Claim 25 words
A material exhibiting narrow-line fluorescence when excited by a high energy light source, comprising an europium chelate dispersed in solid solution in a plastic host.
Claim 32
Dependent Claim 14 words
The invention according to claim 16 wherein said plastic host is a polymeric matrix.
Claim 33
Dependent Claim 13 words
The invention according to claim 17 wherein said polymeric matrix is polymethyl methacrylate.
Claim 34
Dependent Claim 24 words
The invention according to claim 18 wherein said chelate of europium comprises europium ions in an organic complex formed by chelation with a beta-diketone.
Claim 35
Dependent Claim 16 words
The invention according to claim 19 wherein said material is in the form of a rod.
Claim 36
Dependent Claim 35 words
For use in generating coherent radiation by stimulated emission, a member comprising rare earth ions bonded to organic molecules in the form of an organometallic chelate, dispersed in solid solution in a plastic host material.
Claim 37
Dependent Claim 35 words
For use in generating coherent radiation by stimulated emission, a member comprising rare earth ions bonded to organic molecules in the form of an organometallic chelate, dispersed in solid solution in a plastic host material.

References Cited (Backward Citations)

US3225307A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-18 1981-01-17 1981-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-18 1985-01-17 1985-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-18 1989-01-17 1989-07-19 $7700.00 Window Closed / Lapsed

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